02. Infrared Spectroscopy (IR). Answer each of the following questions related to infrared (IR) spectroscopy. (16 points) a. Write the letter of the set of key IR frequencies shown below (a-d) in the space beneath each structure that best matches each of the following structures. Abbreviations: w, weak; m, medium; s, strong; br, broad. Use the IR frequency (stretching vibrations) table 2.3, pages 10-11 of the exam to help you (08 pts) OH OH a. 1665 (m), 2890-2990 (s), 3030 (m) cm*1. b. 905 (s), 995 (m), 1040 (m), 1640 (m), 2850-2980 (s), 3090 (m), 3400 (s, br) cm³¹. c. 2840 (s), 2930 (s) cm 1. d. 1040 (m), 2810-2930 (s), 3300 (s, br) cm³¹. a. A compound with the molecular formula C3H5CIO2 has the infrared spectrum shown below. Draw a reasonable structure that is consistent with this data. Show your work for partial credit. Calculate the R value first! (see front page for formula). Hint: This compound has a very common common functional group. Use the IR frequency (stretching vibrations) table 2.3, pages 11-12 of the exam to help you. (08 points) 100 80 60 40 20 2,5 3 WAVELENGTH (MICRONS) 6 7 8 9 10 12 15 مسلسل سلساء 0 4000 3500 3000 2500 2000 1800 1400 1600 FREQUENCY (CM³) 1200 1000 800 600 Structure (show your work):

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02. Infrared Spectroscopy (IR). Answer each of the following questions related to infrared (IR)
spectroscopy. (16 points)
a. Write the letter of the set of key IR frequencies shown below (a-d) in the space beneath each
structure that best matches each of the following structures. Abbreviations: w, weak; m, medium; s,
strong; br, broad. Use the IR frequency (stretching vibrations) table 2.3, pages 10-11 of the exam to
help you (08 pts)
OH
OH
a. 1665 (m), 2890-2990 (s), 3030 (m) cm*1.
b. 905 (s), 995 (m), 1040 (m), 1640 (m), 2850-2980 (s), 3090 (m), 3400 (s, br) cm³¹.
c. 2840 (s), 2930 (s) cm 1.
d. 1040 (m), 2810-2930 (s), 3300 (s, br) cm³¹.
a. A compound with the molecular formula C3H5CIO2 has the infrared spectrum shown below. Draw a
reasonable structure that is consistent with this data. Show your work for partial credit. Calculate the R
value first! (see front page for formula). Hint: This compound has a very common common functional
group. Use the IR frequency (stretching vibrations) table 2.3, pages 11-12 of the exam to help you. (08
points)
100
80
60
40
20
2,5
3
WAVELENGTH (MICRONS)
6
7
8
9 10
12
15
مسلسل سلساء
0
4000
3500
3000
2500
2000
1800
1400
1600
FREQUENCY (CM³)
1200
1000
800
600
Structure (show your work):
Transcribed Image Text:02. Infrared Spectroscopy (IR). Answer each of the following questions related to infrared (IR) spectroscopy. (16 points) a. Write the letter of the set of key IR frequencies shown below (a-d) in the space beneath each structure that best matches each of the following structures. Abbreviations: w, weak; m, medium; s, strong; br, broad. Use the IR frequency (stretching vibrations) table 2.3, pages 10-11 of the exam to help you (08 pts) OH OH a. 1665 (m), 2890-2990 (s), 3030 (m) cm*1. b. 905 (s), 995 (m), 1040 (m), 1640 (m), 2850-2980 (s), 3090 (m), 3400 (s, br) cm³¹. c. 2840 (s), 2930 (s) cm 1. d. 1040 (m), 2810-2930 (s), 3300 (s, br) cm³¹. a. A compound with the molecular formula C3H5CIO2 has the infrared spectrum shown below. Draw a reasonable structure that is consistent with this data. Show your work for partial credit. Calculate the R value first! (see front page for formula). Hint: This compound has a very common common functional group. Use the IR frequency (stretching vibrations) table 2.3, pages 11-12 of the exam to help you. (08 points) 100 80 60 40 20 2,5 3 WAVELENGTH (MICRONS) 6 7 8 9 10 12 15 مسلسل سلساء 0 4000 3500 3000 2500 2000 1800 1400 1600 FREQUENCY (CM³) 1200 1000 800 600 Structure (show your work):
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