.011 .02- Pressure "P" mm Observed boiling point at P Boiling point corrected to 760 mm °C °C 400 700 1.0 600 300 6 500 - 20 30140 60 100 80 200- 300f 400 - 300 200 200 700 1500 100 100 в A Figure 13.2 Pressure-temperature alignment nomograph. How to use the nomograph: Assume a reported boiling point of 100°C (column A) at 1 mm. To determine the boiling point at 18 mm, connect 100°C (column A) to 1 mm (column C) with a transparent plastic rule and observe where this line intersects column B (about 280°C). This value would correspond to the normal boiling point. Next, connect 280°C (column B) with 18 mm (column C) and observe where this intersects column A (151°C). The approximate boiling point will be 151°C at 18 mm. (Reprinted courtesy of EMD Chemicals, Inc.) 4. O 88 +++

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Question

Using the pressure–temperature alignment chart in Figure 13.2, answer the
following questions.
a. What is the normal boiling point (at 760 mm Hg) for a compound that boils
at 150°C at 10 mm Hg pressure?
b. At what temperature would the compound in (a) boil if the pressure were
40 mm Hg?
c. A compound was distilled at atmospheric pressure and had a boiling point
of 285°C. What would be the approximate boiling range for this compound
at 15 mm Hg?

.011
.02-
Pressure
"P" mm
Observed
boiling point
at P
Boiling point
corrected
to 760 mm
°C
°C
400
700
1.0
600
300
6
500 -
20
30140
60
100 80
200-
300f
400 -
300
200
200
700 1500
100
100
в
A
Figure 13.2
Pressure-temperature alignment nomograph. How to use the
nomograph: Assume a reported boiling point of 100°C (column A)
at 1 mm. To determine the boiling point at 18 mm, connect 100°C
(column A) to 1 mm (column C) with a transparent plastic rule
and observe where this line intersects column B (about 280°C).
This value would correspond to the normal boiling point. Next,
connect 280°C (column B) with 18 mm (column C) and observe
where this intersects column A (151°C). The approximate boiling
point will be 151°C at 18 mm. (Reprinted courtesy of EMD
Chemicals, Inc.)
4.
O 88
+++
Transcribed Image Text:.011 .02- Pressure "P" mm Observed boiling point at P Boiling point corrected to 760 mm °C °C 400 700 1.0 600 300 6 500 - 20 30140 60 100 80 200- 300f 400 - 300 200 200 700 1500 100 100 в A Figure 13.2 Pressure-temperature alignment nomograph. How to use the nomograph: Assume a reported boiling point of 100°C (column A) at 1 mm. To determine the boiling point at 18 mm, connect 100°C (column A) to 1 mm (column C) with a transparent plastic rule and observe where this line intersects column B (about 280°C). This value would correspond to the normal boiling point. Next, connect 280°C (column B) with 18 mm (column C) and observe where this intersects column A (151°C). The approximate boiling point will be 151°C at 18 mm. (Reprinted courtesy of EMD Chemicals, Inc.) 4. O 88 +++
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