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. For N2, fw = e 2360 cm-1, and fwae 14.5 cm-1. Ev %3D

. For N2, fw = e 2360 cm-1, and fwae 14.5 cm-1. Ev %3D

Biochemistry
Biochemistry
9th Edition
ISBN:9781319114671
Author:Lubert Stryer, Jeremy M. Berg, John L. Tymoczko, Gregory J. Gatto Jr.
Publisher:Lubert Stryer, Jeremy M. Berg, John L. Tymoczko, Gregory J. Gatto Jr.
Chapter1: Biochemistry: An Evolving Science
Section: Chapter Questions
Problem 1P
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9. For N2, fiw = 2360 cm-1, and fwxe = 14.5 cm-1. Evaluate the above vibrational partition function at 100, 300, and 1000 K and by adding together as many terms as necessary to give an answer to three decimal places. Do the same for Br2, which has fw = 323 cm-1, and hwre = 1.1 cm-. Compare these values to those computing using the harmonic approximation (setting ae = 0). Comment on the results.
Transcribed Image Text:9. For N2, fiw = 2360 cm-1, and fwxe = 14.5 cm-1. Evaluate the above vibrational partition function at 100, 300, and 1000 K and by adding together as many terms as necessary to give an answer to three decimal places. Do the same for Br2, which has fw = 323 cm-1, and hwre = 1.1 cm-. Compare these values to those computing using the harmonic approximation (setting ae = 0). Comment on the results.
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