Oxidation MDMS

(2,2,6,6-Tetramethylpiperidin-1-yl)oxyl [TEMPO] C 9 H 18 NO CAS No. PS Color Odor FP BP MP d VP VD Sol 2564-83-2 Solid Red N/A 67 N/A 36 – 38 N/A N/A N/A N/A Types of Hazard/Exposure Acute Hazards/Symptoms Prevention First Aid/Fire Fire Moderate fire hazard. No flames, no sparks, no contact with hot surfaces. Carbon dioxide, dry chemical powder, foam, water. Inhalation May be harmful. Irritating to respiratory tract. Ventilation, local exhaust. Remove from exposure immediately and seek medical advice. Skin Causes severe irritation burns. Protective gloves and clothing. Remove contaminated clothes/jewelry, thoroughly wash skin with soap and water, and seek medical advice. Eyes Causes severe burns and eye damage. Safety goggles. Thoroughly flush eyes with water for several min, removing contact lenses if possible, and seek medical advice. Ingestion May be harmful if swallowed. Do not eat or drink in the laboratory. Wash out mouth with water; do not induce vomiting; if vomiting occurs, keep head lower than hips. Seek medical advice immediately. Call a poison center. Carcinogenicity Not a known carcinogen Mutagenicity Not a known mutagen For more detailed information consult the Material Safety Data Sheet for this compound. Abbreviations: CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point (°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d = density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD = vapor density relative to air (1.0); Sol = solubility in water; N/A = not available or not applicable.

N -Methylimidazole C 4 H 6 N 2 CAS No. PS Color Odor FP BP MP d VP VD Sol 616-47-7 Liquid Colorless N/A 92 198 -6 1.03 0.5 @ 20 N/A N/A Types of Hazard/Exposure Acute Hazards/Symptoms Prevention First Aid/Fire Fire Combustible/flammable liquid. No flames, no sparks, no contact with hot surfaces. Carbon dioxide, dry chemical powder, foam, water. Inhalation May be harmful. Irritating to respiratory tract. Ventilation, local exhaust. Remove from exposure immediately and seek medical advice. Skin Toxic in contact with skin. Causes irritation. Protective gloves and clothing. Remove contaminated clothes/jewelry, thoroughly wash skin with soap and water, and seek medical advice. Eyes Causes serious eye damage. Safety goggles. Thoroughly flush eyes with water for several min, removing contact lenses if possible, and seek medical advice. Ingestion Harmful if swallowed. Do not eat or drink in the laboratory. Wash out mouth with water; do not induce vomiting; if vomiting occurs, keep head lower than hips. Seek medical advice immediately. Call a poison center. Carcinogenicity Not a known carcinogen Mutagenicity Not a known mutagen For more detailed information consult the Material Safety Data Sheet for this compound. Abbreviations: CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point (°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d = density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD = vapor density relative to air (1.0); Sol = solubility in water; N/A = not available or not applicable.

Cuprous Bromide BrCu CAS No. PS Color Odor FP BP MP d VP VD Sol 7787-70-4 Powder N/A N/A N/A N/A 504 4.71 0.5 torr @ 20 o C N/A Insoluble Types of Hazard/Exposure Acute Hazards/Symptoms Prevention First Aid/Fire Fire Not flammable or combustible. No flames, no sparks, no contact with hot surfaces. Carbon dioxide, dry chemical powder, foam, water. Inhalation May be harmful. Irritating to respiratory tract. Ventilation, local exhaust. Remove from exposure immediately and seek medical advice. Skin May be harmful if absorbed through skin. Causes irritation. Protective gloves and clothing. Remove contaminated clothes/jewelry, thoroughly wash skin with soap and water, and seek medical advice. Eyes Causes serious eye irritation. Safety goggles. Thoroughly flush eyes with water for several min, removing contact lenses if possible, and seek medical advice. Ingestion Harmful if swallowed. Do not eat or drink in the laboratory. Wash out mouth with water; do not induce vomiting; if vomiting occurs, keep head lower than hips. Seek medical advice immediately. Call a poison center. Carcinogenicity Not a known carcinogen Mutagenicity Not a known mutagen For more detailed information consult the Material Safety Data Sheet for this compound. Abbreviations: CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point (°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d = density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD = vapor density relative to air (1.0); Sol = solubility in water; N/A = not available or not applicable.

4-Chlorobenzyl Alcohol C 7 H 7 ClO CAS No. PS Color Odor FP BP MP d VP VD Sol 873-76-7 Solid White N/A N/A 234 70 – 72 N/A N/A N/A Poor Types of Hazard/Exposure Acute Hazards/Symptoms Prevention First Aid/Fire Fire Moderate fire hazard. No flames, no sparks, no contact with hot surfaces. Carbon dioxide, dry chemical powder, foam, water. Inhalation May be harmful. Ventilation, local exhaust. Remove from exposure immediately and seek medical advice. Skin Irritation; may be harmful if absorbed through skin. Protective gloves and clothing. Remove contaminated clothes/jewelry, thoroughly wash skin with soap and water, and seek medical advice. Eyes Irritation. Safety goggles. Thoroughly flush eyes with water for several min, removing contact lenses if possible, and seek medical advice. Ingestion May be harmful. Do not eat or drink in the laboratory. Wash out mouth with water; if vomiting occurs, keep head lower than hips. Seek medical advice immediately. Carcinogenicity Not a known carcinogen. Mutagenicity Not a known mutagen. For more detailed information, consult the Material Safety Data Sheet for this compound. Abbreviations: CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point (°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d = density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD = vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise stated; N/A = not available or not applicable.

Acetone C 3 H 6 O CAS No. PS Color Odor FP BP MP d VP VD Sol 67-64-1 Liquid Colorless Paint thinner- like -17 56 -94 0.791 180 @ 20 2.0 Soluble Types of Hazard/Exposure Acute Hazards/Symptoms Prevention First Aid/Fire Fire Severe fire hazard; vapors or gases may ignite at distant ignition sources. No flames, no sparks, no contact with hot sources. Alcohol-resistant foam, carbon dioxide, dry chemical powder, water. Inhalation Irritation, dryness of the mouth and throat, central nervous system depression, headache. Ventilation, local exhaust. Remove from exposure immediately and seek medical advice. Skin Irritation, cellular damage to the outer layers of the epithelium with edema and hyperemia, small amounts may be absorbed through intact skin. Protective gloves and clothing. Remove contaminated clothes/jewelry, thoroughly wash skin with soap and water, and seek medical advice. Eyes Irritation, corneal epithelial, conjunctival, stinging sensation, and damage to eyes. Safety goggles. Thoroughly flush eyes with water for several min, removing contact lenses if possible, and seek medical advice. Ingestion Fruity odor of the breath and mucous membrane, gastroenteric irritation, diarrhea, nausea and vomiting. Do not eat or drink in the laboratory. Wash out mouth with water; if vomiting occurs, keep head lower than hips. Seek medical advice immediately. Carcinogenicity Not a known carcinogen. Mutagenicity Possible mutagen. For more detailed information, consult the Material Safety Data Sheet for this compound. Abbreviations: CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point (°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d = density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD = vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise

Pentane C 5 H 12 CAS No. PS Color Odor FP BP MP d VP VD Sol 109-66-0 Liquid Colorless Gasoline- like -49 35 – 36 -130 0.626 434 @ 20 N/A Insoluble Types of Hazard/Exposure Acute Hazards/Symptoms Prevention First Aid/Fire Fire Severe fire hazard; vapor may travel considerable distance to ignition source and flash back. No flames, no sparks, no contact with hot surfaces. Dry chemical powder, carbon dioxide, appropriate foam. Inhalation May be harmful by inhalation. Vapor is irritating to the upper respiratory track. Symptoms may include headache, dizziness, and nausea. Ventilation, local exhaust. Remove from exposure immediately and seek medical advice. Skin May be harmful if absorbed though skin. May cause skin irritation, dermatitis. Protective gloves and clothing. Remove contaminated clothes/jewelry, thoroughly wash skin with soap and water, and seek medical advice. Eyes May cause eye irritation. Symptoms may include redness, blurred vision, tears. Safety goggles. Thoroughly flush eyes with water for several min, removing contact lenses if possible, and seek medical advice. Ingestion May be harmful if swallowed. Symptoms may include headache, dizziness and nausea. Aspiration hazard if swallowed. Do not eat or drink in the laboratory. If swallowed, wash out mouth with water. Seek medical advice. Carcinogenicity Not a known carcinogen. Mutagenicity Not a known mutagen. For more detailed information, consult the Material Safety Data Sheet for this compound. Abbreviations: CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point (°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d = density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD = vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise stated; N/A = not available or not applicable.