LOG 0140 KNR

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LOG 0140 Packaging of Hazardous Material Knowledge Review Questions Review each description and use the dropdown menu on the right to select the correct role. Select Check Answer when you have selected all of your answers. Maintains safe operations when preparing/handling hazardous material for transport. Handler Certifies that hazardous materials are properly classified, described, packaged, marked, labeled, and in proper condition for transport, in accordance with applicable regulations. Prepare/Certifier Packages hazardous materials. Packer Ensures hazardous materials are properly prepared and documented before they enter into the military airlift system. Inspector  A handler is tasked with maintaining safe operations when preparing/handling hazardous materials for transport. Handlers include warehouse workers, load planners, load selectors, special handling personnel, and aircraft load teams.  The preparer/certifier signs legally binding documents that certify hazmat is properly classified, described, packaged, marked, labeled, and in proper condition for transport.  A packer packages hazardous materials.  The inspector ensures hazardous materials are properly prepared and documented before they enter into the military airlift system. Match each regulatory document with its description and select check Answer. Regulatory Document Description UN Orange Book Provides recommendations that are adaptable by individual countries into modal regulations 49 CFR U.S. regulations governing the safe domestic transport of hazmat IMDG Code Provides the standards for the international transport of dangerous goods by sea IATA DGR Used in preparation in international commercial air shipments AFMAN 24-204 Governs the transport of hazmat when entered into the Defense Transportation System (DTS) as cargo on military controlled aircraft ICAO TI Provides technical instruction for the safe transport of dangerous goods by international air  UN Orange Book – United Nations Recommendations of the Transport of Dangerous Goods  49 CFR – Title 49 Code of Federal Regulations, Transportation  IMDG Code – International Maritime Dangerous Goods Code  IATA DGR – International Air Transport Association Dangerous Goods Regulations  AFMAN 24-240 – Preparing Hazardous Material for Military Air Shipments  IACO TI – International Civil Aviation Organization Technical Instructions for the Safe Transport of Dangerous Goods by Air

Using 49 CFR §173.102 Special Provisions to look up the code, what is the N34 requirement?  Glass materials of construction are not authorized for any part of a packaging which is normally in contact with the hazardous material.  Aluminum construction materials are not authorized for any part of a packaging which is normally in contact with the hazardous material.  Plastic packagings are not authorized.  This material is not authorized in a combination packaging consisting of a 4G fiberboard box with inner receptacles of glass or earthenware. The excepted quantity limit for Hazard Class 8 liquids is 30 mL for an inner container and 500 mL for an outer package. The limited quantity limit for Hazard Class 8 liquids in PG II is 100 ml (inner) and 500 ml (outer). If we were shipping our 2.5-liter bottle of Sulfuric Acid via military air, would it be eligible to ship as an excepted or limited quantity?  Yes, it could ship as an excepted quantity  Yes, it could ship as an limited quantity  No, it could not ship as either Declaration Requirements for Grandfathered Items  49 CFR, Section 173.7(e) (Shipping Papers)  MIL-STD-129 (Labeling)  IMDG Code 4.1.5.19 (Multimodal Dangerous Goods Form)  AFMAN 24-204, A3.3.1.10 (Shipper’s Declaration for Dangerous Goods) Per 49 CFR, Section 173.7(e), explosive material is declared as “government-owned goods packaged prior to January 1, 1990” on the shipping papers (after the shipping description). Declaration Requirements for Grandfathered Items  49 CFR, Section 173.7(e) (Shipping Papers)  MIL-STD-129 (Labeling)  IMDG Code 4.1.5.19 (Multimodal Dangerous Goods Form)  AFMAN 24-204, A3.3.1.10 (Shipper’s Declaration for Dangerous Goods) MIL-STD-129 requires that a label stating “government-owned goods packaged prior to January 1, 1990” must be placed on the package in a clear location. Declaration Requirements for Grandfathered Items  49 CFR, Section 173.7(e) (Shipping Papers)  MIL-STD-129 (Labeling)  IMDG Code 4.1.5.19 (Multimodal Dangerous Goods Form)  AFMAN 24-204, A3.3.1.10 (Shipper’s Declaration for Dangerous Goods) Per IMDG Code 4.1.5.19, Government-owned military dangerous goods, packaged prior to January 1, 1990 in accordance with the provisions of the IMDG Code in effect at that time, may be transported provided the packagings maintain their integrity and the goods are declared as government-owned goods packaged prior to 1 January 1990 on the Multimodal Dangerous Goods Form.

Declaration Requirements for Grandfathered Items  49 CFR, Section 173.7(e) (Shipping Papers)  MIL-STD-129 (Labeling)  IMDG Code 4.1.5.19 (Multimodal Dangerous Goods Form)  AFMAN 24-204, A3.3.1.10 (Shipper’s Declaration for Dangerous Goods) AFMAN, paragraph A3.3.1.10, Grandfathered Items, specifies that items are shipped under the packaging requirements in effect at the time of packaging and requires that (Preparers/Certifiers) annotate key 19 (additional handling information) of the Shipper’s Declaration for Dangerous Goods “Government-owned goods packaged before 1 January 1990.” Common Packaging Tests  Drop (UN)  Leakproofness (UN)  Hydrostatic Pressure  Stacking (UN)  Cooperage (UN)  Vibration (USA)  Internal Pressure Differential  Compatibility  Water Resistance Drop (UN): Regulation: 49 CFR §178.603; §173.4(a)(6)(i); §173.4(f)(i). Items to be tested:  All packagings  Non-bulk  Small quantities for highway and rail  Excepted quantities Exceptions: Excepted quantities as stated in 49 CFR §173.4a NOTE: Not all packagings are subject to every test. For example, packagings containing solids are not subject to the hydrostatic pressure test. Common Packaging Tests  Drop (UN)  Leakproofness (UN)  Hydrostatic Pressure  Stacking (UN)  Cooperage (UN)  Vibration (USA)  Internal Pressure Differential  Compatibility  Water Resistance Leakproofness (UN): Regulation: 49 CFR §178.604 Items to be tested: Types of outer packagings intended to contain liquids.

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Exceptions: Inner packagings of combination packagings. NOTE: Not all packagings are subject to every test. For example, packagings containing solids are not subject to the hydrostatic pressure test. Common Packaging Tests  Drop (UN)  Leakproofness (UN)  Hydrostatic Pressure  Stacking (UN)  Cooperage (UN)  Vibration (USA)  Internal Pressure Differential  Compatibility  Water Resistance Hydrostatic Pressure (UN): Regulation: 49 CFR §178.605 Items to be tested: All metal, plastic, and composite design types intended to contain liquids. Exceptions: Inner packagings of combination packagings. Supplemental Packaging for Air Transport – Pack containers holding liquids that do not meet the pressure requirement for air transport into a supplementary packaging that does meet the requirements as defined in IATA 5.0.2.9 (Internal Pressure Standards) and AFMAN A3.1.7 (Air-Eligible Packaging Requirements). NOTE: Not all packagings are subject to every test. For example, packagings containing solids are not subject to the hydrostatic pressure test. Common Packaging Tests  Drop (UN)  Leakproofness (UN)  Hydrostatic Pressure  Stacking (UN)  Cooperage (UN)  Vibration (USA)  Internal Pressure Differential  Compatibility  Water Resistance Stacking (UN): Regulation: 49 CFR §178.606; §173.4(a)(i) Items to be tested:  All packaging design types (tested for a duration of 24 hour)  Excepted quantities Exceptions:  Bags: test not required

 Plastic drums, jerricans, and composite packagins tested at 104°F for 28 days NOTE: Not all packagings are subject to every test. For example, packagings containing solids are not subject to the hydrostatic pressure test. Common Packaging Tests  Drop (UN)  Leakproofness (UN)  Hydrostatic Pressure  Stacking (UN)  Cooperage (UN)  Vibration (USA)  Internal Pressure Differential  Compatibility  Water Resistance Cooperage (UN): Regulation: 49 CFR §178.607 Items to be tested: Bung-type wooden barrels Exceptions: N/A NOTE: Not all packagings are subject to every test. For example, packagings containing solids are not subject to the hydrostatic pressure test. Common Packaging Tests  Drop (UN)  Leakproofness (UN)  Hydrostatic Pressure  Stacking (UN)  Cooperage (UN)  Vibration (USA)  Internal Pressure Differential  Compatibility  Water Resistance Vibration (USA): Regulation: 49 CFR §178.608; AFMAN 24-204 Items to be tested: All packagings manufactured in the United States and subject to the provisions of 49 CFR (USA HMR) Exceptions: N/A NOTE: Not all packagings are subject to every test. For example, packagings containing solids are not subject to the hydrostatic pressure test.

Common Packaging Tests  Drop (UN)  Leakproofness (UN)  Hydrostatic Pressure  Stacking (UN)  Cooperage (UN)  Vibration (USA)  Internal Pressure Differential  Compatibility  Water Resistance Internal Pressure Differential: Regulation: 49 CFR §173.27(c) Items to be tested: Packagings for liquid retention (as its basic function) intended for transportation aboard aircraft Exceptions: Excepted quantities as stated in 49 CFR §173.4a NOTE: Not all packagings are subject to every test. For example, packagings containing solids are not subject to the hydrostatic pressure test. Common Packaging Tests  Drop (UN)  Leakproofness (UN)  Hydrostatic Pressure  Stacking (UN)  Cooperage (UN)  Vibration (USA)  Internal Pressure Differential  Compatibility  Water Resistance Compatibility: Items to be tested: Plastic single (drums, jerricans) and composite packagins, and plastic inner packagings to ensure that the plastic is compatible with the liquid contained in accordance with an reference 49 CRF 173.24 (e). NOTE: When shipping military or international air, compatibility testing of the packaging is conducted IAW the IATA 5.0.2.6 or AFMAN A3.1.3. Exceptions: N/A NOTE: Not all packagings are subject to every test. For example, packagings containing solids are not subject to the hydrostatic pressure test.

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Common Packaging Tests  Drop (UN)  Leakproofness (UN)  Hydrostatic Pressure  Stacking (UN)  Cooperage (UN)  Vibration (USA)  Internal Pressure Differential  Compatibility  Water Resistance Water Resistance: Regulation: 49 CFR §178.516(b)(1); §173.508(b)(4) Items to be tested:  Fiberboard outer packagings  Boxes  Fiber drums Exceptions: N/A NOTE: Not all packagings are subject to every test. For example, packagings containing solids are not subject to the hydrostatic pressure test. Package the Sulfuric Acid Shipment Select the Materials: Bags:  Bag (barrier): 4-mil, gusseted (18” x 30” x .004”)  Bag (barrier): 4-mil, gusseted (14” x 14” x 18”)  Bag (barrier): 4-mil, gusseted (16” x 18” x 40”) Absorbents/Cushioning:  Absorbent: A-900  Absorbent: General Purpose (GP)  Absorbent: Vermiculite, fine Tapes:  Tape, ¾”, Type II, med tensile, pressure sensitive  Tape, 1”, Type II, med tensile, pressure sensitive  Tape, 2”, Type II, med tensile, pressure sensitive  Tape, 1.5”, Type I, clear  Tape, 2”, Type I, clear  Tape, 3”, Type I, clear

Boxes:  Fiberboard Box: RSC, CF, V3c, WR, SW (18” x 14” x 14”)  Fiberboard Box: RSC, CF, V3c, WR, SW (14” x 14” x 18”)  Fiberboard Box: CSSC, CF, W3c, WR, SW (14” x 14” x 18”) Sulfuric Acid: Packaging According to the Test Report: Intro: Line inside of the box with 4-mil bag Pack 1-3/4” of absorbent material, tightly compressed, in bottom of lined box Place the wrapped bottle on top of the absorbent layer in the center of the box Place absorbent around bottle/jug, compressing every 4” until the box is filled Twist and tape outer bag with 2” plastic tape Embed a foam pad on top of the sealed box liner prior to closing Now we have our inner and intermediate packaging materials in our V3c fiberboard box, the test report tells us to need to seal it up using the 2” wide, type II, clear tape. What method does the test report tell us to use to seal the box?  2-strip method  6-strip method  7-strip method Apply UN Certification Marking: As ascertained from the UN label, the gross tested mass (GTM) is 20.9 kg. Per 49 CFR requirements, select the appropriate size for our label from the POP Program options.  Small (0.25” test height)  Large (0.5” text height)  Page (full 8.5 x 11) Mark and Label the Package: Now, per modal regulations, we will complete the marking and labeling of our Sulfuric Acid package. What are the markings and label we need for our package? Select the four that apply.  UN Certification Marking  Hazard Label 5.1 (oxidizer)  Cargo aircraft only  Overpack  Hazard Label 8 (Corrosive)  SPI Number  Orientation Marking  MIL-STD-129 ID Marking  Excepted Quantity  Marine Pollutant

Sentry Seal Paint Q1: Hazard Class Based on the SDS, what is the hazard class of the sentry seal paint?  Hazard Class 1: Explosive  Hazard Class 3: Flammable Liquid  Hazard Class 5: Oxidizer  Hazard Class 8: Corrosive Q2: Modal Regulation Since this material is being shipped by truck within the continental United States (CONUS), which modal regulation would you consult?  Air Force Manual (AFMAN) 24-204  Technical Instructions for the Safe Transport of Dangerous Goods by Air  49 Code of Federal Regulations (CFR)  Dangerous Goods Regulations (DGR) Q3: Packing Group Based on the SDS details, the PSN for the sentry seal paint is “Paint,” the UN number is UN1263. Which packing group (PG) does the SDS specify for this material?  PG I  PG II  PG III Q4: Special Provisions Using the 49 CFR Hazardous Materials table, what are the special provisions that apply to this PG II, non- bulk highway shipment of paint? Select the three that apply.  149  367  383  B131 Q5: Excepted and Limited Quantities The 49 CFR Hazmat Table specifies §173.150 as the applicable excepted quantity packaging paragraph. Based on this paragraph, does the 1-gallon shipment of paint meet the excepted quantity requirements?  Yes  No Q6: Outer Packaging The 49 CFR Hazmat Table specifies §173.173 as the non-bulk packaging paragraph. Based on this paragraph, can you use a fiberboard box as the outer packaging for this shipment?  Yes  No Q7: Consult the POP Program

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Next, you will run a Generic Test Search in the Performance Oriented Packaging (POP) Program to find tested specification packaging for the pain shipment. Specify the criteria to obtain a test report. 1. Transportation Mode: 49 CRF Surface 2. Package Type: Combination 3. Contents: Liquid 4. Packing Group: Packing Group II 5. Inner Container Type: Round Metal Can 6. Units of Measure: Gallons, Liquid (US) 7. Units Per Inner Container: 1.0 8. Number of Inner Containers Per Shipping Container: 1 9. Exterior Container Type: Fiberboard Q8: Select the Materials (Bag) Using the test report, select the bag needed for the liner of the package.  Bag (barrier): 2-mil gusseted (12” x 12” x .02”)  Bag (barrier): 4-mil gusseted (24” x 24” x .04”)  Bag (barrier): 2-mil gusseted (30” x 30” x .02”)  Bag (barrier): 4-mil gusseted (30” x 30” x .04”) Q9: Select the Materials (Absorbent) According to the test report, which absorbents can be used? Select all that apply.  Absorbent: A-900  Absorbent: General Purpose (GP)  Absorbent: Vermiculite, fine  No absorbent required Q10: Select the Materials (Tape) Using the test report, select the different tapes needed for the pain packaging. Select the two that apply.  Tape, 1”, Type I, waterproof, pressure sensitive, clear  Tape, 1-1/2”, Type I, waterproof, pressure sensitive, clear  Tape, 2”, Type I, waterproof, pressure sensitive, clear  Tape, ¾”, Type II, pressure sensitive, filament-reinforced  Tape, 1”, Type II, pressure sensitive, filament-reinforced  Tape, 2”, Type II, pressure sensitive, filament-reinforced Q11: Select the Materials (Box) Using the test report, select the outer packaging needed for the paint.  Fiberboard Box: RSC, CF, WR, SW, W3c (12” x 12” x 12”)  Fiberboard Box: RSC, CF, WR, SW, V3c (12” x 12” x 12”)  Fiberboard Box: CSSC, CF, W3c, WR, SW (12” x 12” x 12”) Q12: Inner Packaging Closure According to the test report, how is the inner container to be closed?  Use a commercially available locking ring  Use 1-inch filament-reinforced tape

 Use 1-inch thick foam pad taped over the lid with 1-inch filament-reinforced tape  No special closure is required Q13: Intermediate Packaging Arrange the packaging details in the correct order to properly protect and secure the paint in its intermediate packaging. Line inside of the box with 4-mil bag, spreading into box corners Pack 2” of absorbent material, tightly compressed, in bottom of lined box Place the wrapped and padded can on top of the absorbent layer in the center of the box Place absorbent around can, continually tamping down as the box is filled Cover can with 2” of absorbent, packing down until tightly compressed Twist liner bag and secure with tape Q14: Outer Packaging Closure According to the test report, what method is used to seal the box using the 2” wide, type II, clear tape?  2-strip method  6-strip method  7-strip method Q15: Packaging Reinforcement Per the test report, what method should be used to reinforce the exterior shipping container?  2-inch tape applied 1-inch from two ends  1-inch reinforced tape applied 1-inch from two ends  2-inch tape applied 1-inch from all four ends  1-inch reinforced tape applied 1-inch from all four ends Q16: Marks and Labels Now, per modal regulations, complete the marking and labeling of the pain package. What are the markings and labels needed on the package of paint? Select the five that apply.  UN Certification Marking  3: Flammable Liquid  Cargo aircraft only  Flash Point  8: Corrosive  SPI Number  Orientation Marking  MIL-STD-129 ID Marking  Excepted Quantity  Marine Pollutant Q17: Place Marks and Labels Select and place each marking and label in the appropriate area and side of the container to complete the packaging.

Triethylamine: Q1: Hazard Class Based on the SDS, what is the hazard class of the triethylamine?  Hazard Class 1: Explosive  Hazard Class 3: Flammable Liquid  Hazard Class 5: Oxidizer  Hazard Class 8: Corrosive Q2: Modal Regulation Since this material is being shipped via military aircraft, which modal regulation would you consult?  Air Force Manual (AFMAN) 24-204  Technical Instructions for the Safe Transport of Dangerous Goods by Air  49 Code of Federal Regulations (CFR)  Dangerous Goods Regulations (DGR) Q3: Packing Group Using the SDS or AFMAN 24-204, what is the packing group (PG) for Triethylamine?  PG I  PG II  PG III Q4: Subsidiary Risk Based on the SDS/AFMAN 24-204, what is the subsidiary risk of the Triethylamine?  Explosive (Hazard Class 1)  Oxidizer (Hazard Class 5)  Poison (Hazard Class 6)  Corrosive (Hazard Class 8)

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Q5: Special Provisions The AFMAN 24-204 hazardous materials table (A4.1) lists special provision P4 for Triethylamine. What does this special provision mean?  Transport this material on Special Assignment Airlift Mission aircraft as identified in attachment 24. Material authorized on cargo aircraft only. Passenger deviation are not authorized.  Transport this material on cargo aircraft only. Passenger deviations are not authorized.  Transport this material on cargo aircraft only. Deviations are authorized according to paragraph 2.2 and attachment 22. DoD duty passengers do not require a deviation.  Transport this material on passenger or cargo aircraft without passenger restriction. Q6: Excepted and Limited Quantities Based on the AFMAN 24-204, Attachment 19 Excepted and Limited Quantities, what is the maximum quantity of a Hazard Class 3, PG II material as an inner packaging that is exempt from the specification packaging, marking, labeling, certification, and compatibility requirements of this manual if the provisions of paragraph A19.2 are met?  30 mL  300 mL  Material is not eligible as Excepted or Limited Qty  1 L Q7: Outer Packaging Based on the AFMAN 24-204, Attachment 7: Class 3-Flammable Liquids, can you use a tested plywood box as the outer packaging?  Yes  No Q8: Consult the POP Program Next, you will run a Generic Test Search in the Performance Oriented Packaging (POP) Program to find testing specification packaging for the Triethylamine. Specify the criteria to obtain a test report. 1. Transportation Mode: Military Air 2. Package Type: Combination 3. Contents: Liquid 4. Packing Group: Packing Group II 5. Inner Container Type: Round Glass Bottle 6. Units of Measure: Gallons, Liquid (US) 7. Units Per Inner Container: 1.0 8. Number of Inner Containers Per Shipping Container: 6 9. Exterior Container Type: Plywood Box

Q9: Inner Packaging Closure According to the test report, what is the closure method for the inner container?  Use a commercially available locking ring  Use one piece 1-inch filament-reinforced tape around the neck of the bottle to secure the cap  Wrap each bottle in bubble wrap, secure with 1-inch filament tape  No special closure is required Q10: Intermediate Packaging Arrange the packaging details in the correct order to properly protect and secure the glass bottles of Triethylamine in the intermediate packaging. Wrap each bottle in bubble wrap and secure using 1-inch filament tape Place bottle in a 5.6 quart paint can Use a rubber mallet to tap the entire friction lid securely in place Apply a plastic ICC locking ring with a rubber mallet over the paint can lid Q11: Outer Packaging Arrange the packaging details in the correct order to properly protect and secure the intermediate packages in the outer container. Place 32” x 28” x 48” gusseted 4-mil-poly bag in plywood box Add 2-3/4 inches of firmly packed, loose-fill absorbent cushioning in bottom of box Evenly space the six cans on the absorbent Add approximately 2-1/2 inches of absorbent around the cans and sides of the box; firmly pack Twist liner bag and secure with 1-inch filament-reinforced tape Cover the cans with 2-3/4 inches of firmly packed, loose-fill absorbent Q12: Seal and Reinforce According to the test report, what method is used to close the exterior shipping container?  Nail the box closed with 8-penny cement-coated steel sinkers  Band with 2 girthwise and 2 lengthwise steel straps  Nail the box closed with 8-penny cement coated steel sinkers, then band with 2 girthwise and 2 lengthwise steep straps

Q13: Marks and Labels Now, per modal regulations, complete the marking and labeling of the package. What are the markings and labels needed on the package of Triethylamine? Select the eight that apply.  UN Certification Marking  3: Flammable Liquid  Cargo aircraft only  Flash Point  8: Corrosive  6: Poison  Orientation Marking  MIL-STD-129 ID Marking  UN Number and PSN  Marine Pollutant Q14: Place Marks and Labels Select and place each marking and label int eh appropriate area on the front of the container to complete the packaging. Orientation arrows have already been applied to the sides and the UN marking to the back. Ball Ammunition Q1: Hazard Class According to the JHCS, what is the Hazard Class for the 7.62 mm Ball Ammunition, NSN 1377-01-012- 2961?  PG II  1.4C  Unknown, because military explosives are exempt from hazard labels Q2: UN Number According to the JHCS, what is the UN number for the cartridges (NSN 1377-01-012-2961)?  UN0014  UN032B  UN0276  None

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Q3: Outer Packaging Is the metal can listed for the container in the test report acceptable according to the packaging paragraph in AFMAN 24-204?  Yes  No Q4: Packaging Modifications Based on SPI, are there any authorized modifications for the packaging configurations>  Cartridges can be placed in cartons with cushioning or filler added to obtain a tight pack  Cartridges can be placed in cartons or fiber tubes  Cushioning or filler can be added to obtain to a tight pack  No changes are authorized for the packaging configuration Q5: Secondary Closures According to the SPI, what secondary closure method is required when using the M191A steel box as an outer shipping container?  A seal is placed on the latch  1-inch wide, reinforced tape is wrapped around the container between the end of the handle and the latch  1-inch wide, reinforced tape is used to secure the latch  No special precaution or secondary closure method is required Q6: Marks and Labels Per modal regulations, complete the marking and labeling of the Ball Ammunition shipment. What are the markings and labels needed on the rectangular steel box? Select the five that apply.  UN Certification Marking  1.4C: Explosive  Cargo aircraft only  Flash Point  1: Explosives  SPI/Drawing Number  Orientation Marking  MIL-STD-129 ID Marking  UN Number and PSN  Inhalation Hazard

Q7: Place Marks and Labels In accordance with the SPI ADPLBOX003 place each marking and label in the appropriate area of the container to complete the packaging. Detonating Assembly Q1: Modal Regulation As an explosive shipping via military aircraft, what modal regulation governs this shipment of detonators?  Air Force Manual (AFMAN) 24-204  Technical Instructions for the Safe Transport of Dangerous Goods by Air  49 Code of Federal Regulations (CFR)  Dangerous Goods Regulations (DGR) Q2: UN Number Using the AFMAN 24-404, what is the United Nations (UN) number for the detonating cord (PSN: Fuzes, Detonating) with a hazard class of 1.4S?  UN 0257  UN 0317  UN 0367  UN 03678 Q3: Special Provisions The AFMAN 24-204 hazardous materials table (A4.1) lists special provisions in column 7. What does the “PS” provision listed for the detonators mean?  Transport this material on Special Assignment Airlift Mission aircraft as identified in attachment 24. Material authorized on cargo aircraft only. Passenger deviation are not authorized.  Transport this material on cargo aircraft only. Passenger deviations are not authorized.  Transport this material on cargo aircraft only. Deviations are authorized according to paragraph 2.2 and attachment 22. DoD duty passengers do not require a deviation.  Transport this material on passenger or cargo aircraft without passenger restriction. Q4: Excepted and Limited Quantities AFMAN 24-204, Attachment 19 Excepted and Limited Quantities, lists excepted quantities for shipment via military aircraft. The detonators contain a total of 0.000900 pounds of explosive. Is this quantity excepted from specification packaging, marking, labeling, certification, and compatibility requirements?  Yes  No

Q5: Outer Packaging The table in AFMAN 24-204 lists paragraph “A5.24” as the packaging paragraph in column 8. Which of the following are authorized for use as the outer packaging?  Expanded Plastic Box (4H1)  Fiberboard Barrel (2G)  Plastic Jerrican (3H)  Fiberboard Box (4G) Q6: Variation Eligibility Based on the details in the SPI, is the tested packaging eligible for variation packaging? If so which variation?  Not eligible for variation  Eligible for variation 1  Eligible for variation 2  Eligible for variation 3  Eligible for variation 4  Eligible for variation 5  Eligible for variation 6 Q7: Package the Material Arrange the packaging details in the correct order to properly protect and secure the detonating cords. Wrap each unit in anti-static polyethylene foam Place unit in a watervaporproof, electrostatic protective, barrier bag Remove air and heat seal the bag Place units in shipping container using cushioning as required to ensure a snug fit Q8: Outer Packaging Closure According to the test report and SPI, using ASTM D5486 Type I or V, 2-inch wide tape, what closure method is specified for the outer packaging?  Tape length and width (2-strip method)  H-Method (6-strip method)  ASTM D1974 Method C (7-strip method)

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Q9: Marks and Labels Now, per modal regulations, complete the marking and labeling of the detonating assembly. What are the markings and labels needed on the package. Select the five that apply.  UN Certification Marking  1.4S: Explosive  Cargo Aircraft only  Flash Point  1.1: Explosives  SPI Number Orientation Marking  MIL-STD-129 ID Marking  UN Number and PSN  Inhalation Hazard Q10: Place Marks and Labels Select and place each marking and label in the appropriate area and side of the container to complete the packaging. Corrosive Liquid Q1: Primary Hazard Based on the SDS, what is the primary hazard class of this material?  Hazard Class 1: Explosive  Hazard Class 3: Flammable Liquid  Hazard Class 6: Poison  Hazard Class 8: Corrosive Q2: Modal Regulation This material is shipping within CONUS via truck. Which modal regulation will you consult?  Air Force Manual (AFMAN) 24-204  Technical Instructions for the Safe Transport of Dangerous Goods by Air  49 Code of Federal Regulations (CRF)  Dangerous Goods Regulations (DGR)

Q3: Proper Shipping Name Presto Black is the common name for the liquid, what is the proper shipping name (PSN)?  ACID MIXTURE  CORROSIVE LIQUID  CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S  CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S (SELENIOUS ACID, NITRIC ACID)  CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S (SELENIOUS ACID, CUPRIC SULFATE, NITRIC ACID) Q4: Packing Group Based on the available resources, what is the packing group (PG) for this material?  PG I  PG II  PG III Q5: Special Provisions Based on the special provisions listed in the 49 CFR hazmat table Corrosive Liquid, acidic, inorganic, n.o.s., what special provisions apply to this non-bulk shipment?  IB3  TP4  TP1  TP28  None Q6: Excepted and Limited Quantities Based on packaging paragraph §173.154 in the 49 CFR hazmat table, is this PG III shipment of corrosive liquid excepted from labeling and specification packaging requirements?  Yes – if shipped individually  Yes – all four quarts may be shipped in the same outer container  No – may not be shipped as excepted quantity  Yes – if shipped in a quantity of two Q7: Consult the POP Program Next, you will run a Generic Test Search in the Performance Oriented Packaging (POP) Program to find tested specification packaging for the shipment. Specify the criteria to obtain a test report. 1. Transportation Mode: 49 CFR Surface 2. Package Type: Combination 3. Contents: Liquid 4. Packing Group: Packing Group III 5. Inner Container Type: Round Glass Bottle 6. Units of Measure: Quart, Liquid 7. Units Per Inner Container: 1.0 8. Number of Inner Container Per Shipping Container: 4

Q8: Test Report Configuration Based on the test report, what inner container(s) is (are) specified in this test report?  One 4-Liter, round, glass bottle with handle  Four 1-Liter, round, amber glass bottles with handles  One 4-Quart, round, abler glass bottles  Four 1-Quart, round amber glass bottles Q9: Test Report Variations What variation allow for the shipment of four, 1-quart, round, amber glass bottles with handles in a single packaging rather than the four, 1-Liter, round, amber glass bottles with handles?  Variation 1: Decrease size of inner packagings  Variation 2: use any inner packagings  Variation 3: Reduce Size of Single or Composite Packagings  Variation 4: Reduce Size of Outer Packagings  Variation 5: Different Closure  Variation 6: Articles Considered Same as Inner Packagings Q10: Air Eligibility Based on the test report, can this configuration be used to transport the corrosive liquid, packing group PG III, via by air?  Yes  No Q1: Inner Packaging Closure According to the test report, how are the inner packagings to be closed:  Use 24 mm wide, glass filament-reinforced, plastic film-backed, pressure-sensitive adhesive tape  Use a commercially available locking ring  Sealing method B using 2-inch tape  No special closure is required Q12: Intermediate Packaging Arrange the packaging details in the correct order to secure the glass bottles in intermediate packaging. Place glass bottle in plastic bag, fold bag & secure with tape Place 3 (qty) double wall (or 6 single wall) pads on uppermost bundles and cell dividers Encapsulate bottle in absorbent sheets, fold up and over and place in 4-mil bag, twist and tape Build and place multi-cell frame on pads in the fiberboard box Place one padded/bagged inner in each cell; fill empty cells with 2x2 divider; fill voids with CF Place 7 (qty) 1-inch fiberboard bundles across shoulders of receptables on both side of cap Place 3 (qty) double wall (or 6 single wall) pads on bottom of fiberboard box Repeat framed layers as needed to accommodate total quantity of receptacles Fold box flaps into place and close with 2 strips of tape

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Q13: Outer Packaging Closure What closure method is used to seal the exterior shipping container?  Lever ring, sponge gasket; no plugs into head; sponge gasket  Use a rubber mallet to tap the entire friction lid securely in place  Bolt ring, jam nut, sponge gasket; 2-inc Tri-Sure plug; 3/4-inch Tri-Sure plug  Bolt ring, jam nut, no plugs into head Q14: Marks and Labels Now, per modal regulations, complete the marking and labeling of the package. What are the markings and labels needed on the package of Presto Black? Select the four that apply.  UN Certification Marking  3: Flammable Liquid  Cargo aircraft only  Flash Point  8: Corrosive  SPI Number  Orientation Marking  MIL-STD-129 ID Marking  Excepted Quantity  Marine Pollutant Q15: Place Marks and Labels Select and place each marking and label in the appropriate area and side of the container to complete the packaging. The drum already has an embossed UN certification marking. Calcium Hypochlorite Q1: Hazardous Material Based on the SDS, is the Calcium Hypochlorite a hazardous material?  Yes, it has a hazard class, so it’s a hazardous material  No, it has no hazard class, so it’s not a hazardous material  Unable to determine from the SDS

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Q2: Hazard Class Based on the SDS, what hazard class is specified for the Calcium Hypochlorite?  Hazard Class 4: Flammable Solid  Hazard Class 5.1: Oxidizer  Hazard Class 5.2: Organic Peroxide  Hazard Class 6: Toxic  Hazard Class 8: Corrosive Q3: Modal Regulation Your orders tell you this is a domestic transport via highway. What modal regulation will govern this shipment?  Air Force Manual (AFMAN) 24-204  Technical Instructions for the Safe Transport of Dangerous Goods by Air  49 Code of Federal Regulations (CFR)  Dangerous Goods Regulations (DGR) Q4: UN Number Using the SDS and DOT 49 CFR, determine the United Nations (UN) identification number for the Calcium Hypochlorite.  UN1748  UN2880  UN1734  UN2208 Q5: Special Provisions The special provisions for the Calcium Hypochlorite are 165, IB8, IP2, IP4, IP13, W9. You already know that IB and IP codes only apply to transportation in Intermediate Bulk Containers.  165  W9  None Q6: Packaging Paragraph The 49 CFR Hazmat Table specifies §173.152 as the applicable limited quantity packaging paragraph. Based on this paragraph and packing group (PG) for the material, do the 5-pound bottles of Calcium Hypochlorite meet the limited quantity requirements?  Yes  No Q7: Outer Packaging Based on paragraph 49 CFR §173.212, is a fiberboard box authorized for outer packaging of this material?  Yes  No

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Q8: Consult the POP Program Next, you will run a Generic Test Search in the Performance Oriented Packaging (POP) Program to find tested specification packaging for the Calcium Hypochlorite. Specify the criteria to obtain a test report. 1. Transportation Mode: 49 CFR Surface 2. Package Type: Combination 3. Contents: Solid 4. Packing Group: Packing Group II 5. Inner Container Type: Round Plastic Inner Container 6. Units of Measure: Pounds 7. Units Per Inner Container: 5.0 8. Number of Inner Containers Per Shipping Container: 4 9. Exterior Container Type: Fiberboard Q9: Test Report Variations What variation allow for combination packaging allows for the shipment of four, 5-pound, round, plastic bottles of a PG II material in the specified outer packaging rather than the tested four, 4-liter, glass bottles of a PG I material?  Variation 1: Decrease size of inner packagings  Variation 2: Use any inner packagings  Variation 4: Reduce Size of Outer Packagings  Variation 6: Articles Considered Same as Inner Packagings Q10: Select the Materials (Bag) Using the test report, select the bag(s) needed package. Select the two that apply.  Bag (barrier): 2-mil, LDPE (10” x 8” x 24”)  Bag (barrier): 3-mil, gusseted (10” x 8” x 24”)  Bag (barrier): 3-mil, gusseted (22” x 22” x 47”)  Bag (barrier): 4-mil, gusseted (22” x 22” x 47”) Q1: Select the Materials (Absorbent) Using the test report and variation criteria, select the absorbent needed for the Calcium Hypochlorite. Remember, you are packing a solid material.  1Absorbent: A-900  1Absorbent: General Purpose (GP)  Absorbent: Vermiculite, fine  No Absorbent Required

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Q12: Select the Materials (Tape) Using the test report, select the different tapes needed for the packaging. Select the two that apply.  Tape, 1”, Type I, waterproof, pressure sensitive, clear  Tape, 1-1/2”, Type I, waterproof, pressure sensitive, clear  ASTM D5486, Type I, Class II, Clear, 2  Tape, ¾”, Type II, pressure sensitive, filament-reinforced  Tape, 1”, Type II, pressure sensitive, filament-reinforced  ASTM D5486, Tape, 2”, Type II, pressure sensitive, filament-reinforced Q13: Select the Materials (Box) Using the test report, select the outer packaging needed for the Calcium Hypochlorite.  Corrugated Fiberboard (CF): RSC, CF, WR, SW, V3c (20” x 20” x 20”)  Solid Fiberboard (SF): RSC, SF, WR, W5s (20” x 20” x 20”)  Corrugated Fiberboard (CF): CSSC, CF, WR, SW, V3c (20” x 20” x 20”) Q14: Inner Packaging Closure According to the test report, how are the inner containers to be closed? Select the two that apply.  Seal with a commercially available locking ring  Use one piece 1-inch filament-reinforced tape; wrap 1-1/2 times around and overlapping cap base and bottle neck, with tape end adhered to the side of the bottle  Use two pieces of 1-inch filament-reinforced tape; tape over the lid, perpendicular to each other  Place in 3-mil LDPE bag, remove air, twist shut (leaving some slack), and tape closed with filament-reinforced tape Q15: Intermediate Packaging Arrange the packaging details in the correct order to properly protect and secure the wrapped bottles of Calcium Hypochlorite in the fiberboard box. Place 2 horizontal girthwise bands on box, one 6 inches from the top, on 6 inches from the bottom Line the box with a gusseted, 4-mil, LDPE bag Place 3.5 inches of absorbent in the bottom of the box Place the bottles on the absorbent layer, centered and evenly spaced Place absorbent around the bottles and to the top of the box, tamping down every 2 inches Twist or fold-down bag and tape closed with fiber reinforced tape Q16: Seal and Reinforce According to the test report, what method is used to close the outer packaging?  Use clear tape to seal using the 7-strip method  Add two vertical girthwise bands, 6 inches from parallel box sides and crossing closure line at right angles  Apply clear tape using 7-strip method, and then add two vertical bands, 6 inches from parallel box sides and crossing line at right angles

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Q17: Marks and Labels Now, per modal regulations, complete the marking and labeling of the paint package. What are the markings and labels needed on the package of Calcium Hypochlorite? Select the four that apply.  4: Flammable Solid  5.1: Oxidizer  6: Toxic  8: Corrosive  Marine Pollutant  MIL-STD-129 ID Marking  Orientation Marking  ORM-D  UN Certification Marking  UN Number and PSN Q18: UN Certification Marking Tested specification packaging requires a UN certification marking. Select the correct marking for this package of Calcium Hypochlorite? Q19: Place Marks and Labels Select and place each marking and label in the appropriate area and side of the container to complete the packaging. Supplementary Packaging Q1: Exterior Container Since the packages do not currently meet internal hydrostatic pressure standards for transport by air, which exterior container should be used?

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Q2: Packaging Requirements What are the packaging requirements for this material?  Add cushioning material as needed to create a tight fit  Add at least enough absorbent to absorb the contents of one, 1-pint bottle  Add at least enough absorbent to absorb the contents of all three 1-pint bottles  Additional absorbent is not required Q3: Marks and Labels Now, based on modal regulations, determine which markings and labels are needed on the exterior container. Remember, the three packages contain 1-pint plastic bottle each of a PG II corrosive liquid. Select the five that apply.  UN Certification Marking  3: Flammable Liquid  Identification Marking  Flash Point: -15 deg F  8: Corrosive  Cargo aircraft only  Orientation Marking  MIL-STD-129 ID Marking  Limited Quantity  6: Poison Q4: Place Marks and Labels Select and place each marking and label in the appropriate area and side of the container to complete the packaging. The drum already contains the UN certification marking. Consolidate Air Eligible Packages Q1: Air Eligiblity Is consolidation packaging of compatible materials permissible for military air?  Yes  No

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Q2: Exterior Container Since they are compatible and meet the internal hydrostatic pressure standards for transport by air, which exterior container should be used? Q3: Marks and Labels Now, per modal regulations, which markings and labels are required on the consolidated packaging? Remember, the original packages both contain a PG II, flammable liquid. Select the six that apply.  Identification Markings  3: Flammable Liquid  Cargo aircraft only  Flash Point  6: Poison  Overpack label  Orientation Marking  MIL-STD-129 ID Marking  Limited Quantity  Inhalation Hazard Q4: Place Marks and Labels Select and place each marking and label in the appropriate area and surface of the container to complete the packaging.

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