homework #3

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North Dakota State University *

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210

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Material Science

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Jan 9, 2024

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PLSC 210 Horticulture Science Name____________________________ Fall Semester, 2010 Homework #3 (Total 25 points, due November 12, show calculations for full credit) 1. You have a 50 lb bag of 20-20-20 commercial analysis (general purpose) fertilizer. a. Indicate the amounts of each fertilizer (in oxide form) contained in the 50 lb bag. ( 2 points ) Answer: N = _______ lb, P 2 O 5 = _______ lb, K 2 O =_______ lb Calculations : b. What is the elemental analysis of this fertilizer? ( 2 points ) Answer: Elemental analysis ______ - _______ - _______ N - P - K. Calculations : c. How many lb of each fertilizer element (elemental analysis) is contained in the 50 lb bag? ( 2 points ) Answer: N =_______ lb, P =_______ lb, K =_______ lb Calculations : 2. You would like to fertilize your potted plants with a nutrient solution containing 200 ppm nitrogen (N),100 ppm phosphorus (P 2 O 5 ) and 250 ppm potassium (K 2 O) using a 100-gallon stock tank which is installed with a 1:200 proportion injector. Your fertilizers are ammonium nitrate (NH 4 NO 3 ), potassium mono- phosphate (KH 2 PO 4 ) and potassium chloride (KCl). Commercial analysis (N-P 2 O 5 -K 2 O): NH 4 NO 3 (33.5-0-0), KH 2 PO 4 (0-53-34), KCl (0-0-62) (see Table 1) Conversion factors: P/ P 2 O 5 = 0.44, K/K 2 O = 0.83 a. How many lb of each fertilizer should you use for the 100-gallon stock tank? ( 3 points ) Answer: NH 4 NO 3 =________ lb, KH 2 PO 4 =_________ lb, KCl=_________ lb Calculations : b. What are the concentrations of elemental nitrogen (N), phosphorus (P) and potassium (K) of your stock solution and the final fertilizer solution being applied? ( 3 points ) Answer: 1) Final fertilizer solution: N =__________ ppm, P =___________ ppm, K =___________ ppm 2) Stock solution: N =__________ ppm, P =___________ ppm, K= ___________ ppm Calculations :
c. You have 5,000 pots of chrysanthemums in your greenhouse and each pot requires 0.5 gallon of fertilizer solution per day. How many days would the stock tank (100 gallon) last after it has been filled once with your fertilizer stock? ( 2 points ) Answer: 1) Total volume of final solution:_____________ gallon 2) Total number of days: _____________ days Calculations : d. Using Table 1, calculate the cost of fertilizer needed to fill your stock tank and feed your crop. ( 3 points ) Answer: 1) Cost of fertilizers $_____________/100-gallon stock tank 2) Cost of fertilizers $_____________/5,000 pots per month 3) Cost of fertilizers $_____________/pot per month Calculations : Costs of chemical fertilizers: Commercial Cost per Fertilizer Formula analysis 50- lb bag Ammonium nitrate NH 4 NO 3 33.5-0-0 $20.50 Potassium mono-phosphate KH 2 PO 4 0-53-34 $22.30 Potassium chloride KCl 0-0-62 $15.50 3. You would like to prepare 100 liter of 200 ppm nitrogen (N) using magnesium nitrate [Mg(NO 3 ) 2 6H 2 O]. How many grams of this fertilizer should be used in 100 liter? ( 4 points ) Answer: Magnesium nitrate needed: _________________ g/100 liter. This solution will contain: _________________ ppm Mg. Calculations : 4. How many ounce (oz) of a 20-20-20 commercial fertilizer or potassium nitrate (KNO 3 ) should be dissolved in 100 gallon of water to make a 200 ppm nitrogen (N) solution? ( 4 points ) (Note: 1 oz/100 gallon = 75 ppm) Answer: 20-20-20 fertilizer: ________________ oz/100 gallon. KNO 3 : ________________ oz/100 gallon. Calculations : Note 1 gallon=3.8 liter, 1 kg=2.2 lb, 1 oz=29 g 1 kg=1,000 g=1,000,000 mg Atomic weights: N=14.01, P=30.98, K=39.1, Mg=24.32, S=32.07, Ca=40.08 H=1.01, C=12.01, O=16.0 Molecular weights: KNO 3 =101.11 Mg(NO 3 ) 2 6H 2 O=256.4 Commercial analysis: Mg(NO 3 ) 2 6H 2 O=11-0-0 KNO 3 =13-0-44 2
Table 1. Common fertilizers supplying macronutrients required by plants. ____________________________________________________________________________________________________________ Effect Molec. Equiv. on Solubility c Other Compound Formula a Analysis b weight weight acidity g/100 ml lbs/100 gal materials ____________________________________________________________________________________________________________ Ammonium chloride NH 4 Cl 25-0-0 53.5 53.5 acid 39.7 248 --- Amdmonium nitrate NH 4 NO 3 33.5-0-0 80.05 80.05 acid 118.3 991 --- Monoammonium NH 4 H 2 PO 4 11-48-0 115.04 115.04 acid 22.7 190 1.4% Ca phosphate 2.6% S Diammonium phosphate (NH 4 ) 2 HPO 4 21-53-0 132.07 66.0 acid 42.9 359 --- Ammonium sulfate (NH 4 ) 2 SO 4 20-0-0 132.15 66.1 very acid 70.6 591 24% S Aluminum sulfate Al 2 (SO 4 ) 3 . 18H 2 O 0-0-0 666.45 222.15 very acid soluble soluble 14% S Calcium sulfate CaSO 4 . 2H 2 O 0-0-0 172.18 86.09 neutral 0.2 1.7 23% Ca. 19% S (gypsum) Calcium nitrate Ca(NO 3 ) 2 . 4H 2 O 15-0-0 236.16 118.1 basic 102.0 854 17% Ca Sodium nitrate NaNO 3 16-0-0 85.01 85.01 basic 73.0 611 27% Na Urea CO(NH 2 ) 2 45-0-0 60.06 30.03 acid 78.0 653 --- Superphosphate CaH 4 (PO 4 ) 2 0-20-0 --- --- neutral 1.8 15 18% Ca, 12% S Treble superphosphate CaH 4 (PO 4 ) 2 0-46-0 --- --- neutral 1.8 15 12% Ca Phosphoric acid H 3 PO 4 0-52-0 98.0 98.0 very acid 548 4,600 --- Potassium chloride (muriate of potash) KCl 0-0-62 74.55 74.55 neutral 34.7 291 --- Potassium nitrate (saltpeter) KNO 3 13-0-44 101.1 101.1 basic 13.3 111 --- Potassium sulfate K 2 SO 4 0-0-53 174.26 87.13 neutral 6.9 58 18% S Magnesium sulfate MgSO 4 . 7H 2 O 0-0-0 246.5 123.25 neutral 71 595 10% Mg, 13% S (epsom salts) Magnesium nitrate Mg(NO 3 ) 2 . 6H 2 O 11-0-0 256.4 128.2 neutral 42.3 354 10% Mg Calcium carbonate (limestone) CaCO 3 0-0-0 100.1 50.1 basic 0.002 0.01 40% Ca Calcium hydroxide (hydrated lime) Ca(OH) 2 0-0-0 74.1 37.1 basic 0.19 1.6 60-80% Ca Potassium mono- phosphate KH 2 PO 4 0-53-34 120.1 120.1 basic 33 276 --- Potassium diphosphate K 2 HPO 4 0-41-54 174.2 87.1 basic 167 1,400 --- Calcium cyanamide CaCN 2 20-0-0 80.11 --- basic decomposes --- Sulfur S 0-0-0 32.1 --- acid insoluble --- Dolomite MgCO 3 . CaCO 3 0-0-0 --- --- basic --- --- 22% Ca, 13% Mg (dolomitic limestone) Basic slag CaO . P 2 O 5 . SiO 2 0-17-0 --- --- basic --- --- 33% Ca, 10% Fe ____________________________________________________________________________________________________________ a Formula may differ due to addition of water molecules; or source of material as the case of limestone, superphosphates, etc. b Percentage N, P 2 O 5 , and K 2 O will differ between sources, depending upon manufacturing process. Molecular and equivalent weights are for the formulas as given. c Solubility of materials in water, usually 0 o C. 3
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Table 2. Parts per million (ppm) and milliequivalents per liter (meq/ ) supplied when one pound or kg of material is dissolved in 1000 gal or 10 m 3 ( 10,000 ) of water. Analysis a ppm meq/ b Compound (N-P 2 O 5 -K 2 O) lb/1000 gal kg/10 m 3 lb/1000 gal kg/10 m 3 NH 4 NO 3 33.5-0-0 40 N 34 1.5 NH 4 + 1.3 1.5 NO 3 - 1.3 NH 4 Cl 25-0-0 30 N 25 2.2 NH 4 + 1.9 79 Cl 66 2.2 Cl - 1.9 (NH 4 ) 2 SO 4 20-0-0 24 N 20 1.8 NH 4 + 1.5 29 S 24 1.8 SO 4 - 1.5 Ca(NO 3 ) 2 4H 2 O 15-0-0 18 N 15 1.0 NO 3 - 0.8 44 Ca 37 1.0 Ca 2+ 0.8 NaNO 3 16-0-0 19 N 16 1.4 NO 3 - 1.2 32 Na 27 1.4 Na + 1.2 H 3 PO 4 0-80-0 c 80 P 64 1.2 H 2 PO 4 - 1.0 KNO 3 13-0-44 16 N 13 1.2 K + 1.0 53 K 2 O 53 1.2 NO 3 - 1.0 KCl 0-0-62 74 K 2 O 62 1.6 K + 1.3 57 Cl 48 1.6 Cl - 1.3 (NH 4 ) 2 HPO 4 21-53-0 25 N 21 1.8 NH 4 + 1.5 63 P 2 O 5 53 1.8 HPO 4 2- 1.5 K 2 SO 4 0-0-53 63 K 2 O 53 1.4 K + 1.1 21 S 18 1.4 SO 4 2- 1.1 NH 4 H 2 PO 4 11-18-0 13 N 11 1.0 NH 4 + 0.9 57 P 2 O 5 48 1.0 H 2 PO 4 - 0.9 MgSO 4 - 24 Mg 20 2.0 Mg 2+ 1.7 32 S 27 2.0 SO 4 2- 1.7 Mg(NO 3 ) 2 6H 2 O 11-0-0 13 N 11 0.9 Mg 2+ 0.8 11 Mg 10 0.9 NO 3 - 0.8 HNO 3 (pure) 18-0-0 21 N 18 1.9 NO 3 - 1.6 K 2 HPO 4 0-11-54 49 P 2 O 5 41 1.4 K + 1.1 64 K 2 O 54 1.4 HPO 4 2- 1.1 KH 2 PO 4 0-53-34 61 P 2 O 5 53 1.0 K + 0.8 41 K 2 O 34 1.0 H 2 PO 4 - 0.8 a Analyses in percentage N, P 2 O 5 , and K 2 O. b Milliequivalents are calculated on the basis of equivalent weight. c Percentage of H 2 PO 4 in liquid. 4