CHEM 102 Lab 7 Acids and Bases

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Chemistry

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Jan 9, 2024

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Chem Lab 102-102 02/22/2023 Acids and Bases
I. Photo of Experimental procedure II. Signed Data Page III. I n t r o d u c t i o n The purpose of this experiment is to determine the differences, relationships between acids and bases that were gotten from the experiment. We will use titration, also pH indicator and burette to observe and find the equivalence point.
In order to understand the topic, it is necessary to know the definition of acids and bases. By the Bronsted-Lowry theory, acids is a proton (H + ion) donor and the base is a proton acceptor. There are some examples for strong acids like HCL, HBr, and sulfuric acid. Also, there are some examples of strong bases like lithium hydroxide, or sodium hydroxide. When an acid and a base combine to generate water and salt, this process is known as neutralization, and the resultant solution has a pH of 7. An illustration of a neutralizing reaction is as follows: Hydrochloric acid (HCl) + Sodium hydroxide (NaOH) -> Sodium chloride(NaCl) + Water (H 2 O) In this reaction, the sodium ions (Na+) from the base and the chloride ions (Cl-) from the acid combine to make sodium chloride, which is a salt, while the hydrogen ions (H+) from the hydrochloric acid and the hydroxide ions (OH-) from the sodium hydroxide combine to generate water. The resultant mixture has a pH of 7, making it neutral. Titration is an analytical technique that uses a known quantity of one material to react with an unknown ingredient to determine its concentration in a solution. In a typical titration, a solution of the unknown substance is progressively mixed with a solution of a known concentration, or the titrant, until the reaction between the two is complete. The endpoint of the reaction is identified by an indicator that changes color to indicate completion of the reaction. The equivalence point is a point where pH is the acid with the stoichiometric amount of the base in the solution. It is necessary to indicate equivalence point as it helps to indicate the exact volume when the reaction was complete. Furthermore, titration curves shows us the relationship between the Volume of NaOH added and pH so that it the curves are visually seen, and equivalence point, greatest change in pH can be seen too. Acidic strength is measured using a standard called the dissociation constant, or K a . K a can be calculated by the help of the data observed, like a equivalence point and the corresponding pH. This can be determined by the following formula: K a =10 -pH at half volume IV. Calculations and Discussions
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Volume of NaOH pH 0 2.3 3.1 2.7 6 3.1 9 3.3 12 3.5 15 3.7 18 3.8 21 4 24 4.1 27 4.4 30 4.6 33.1 5 33.4 5.1 33.7 5.2 34 5.3 34.3 5.4 34.6 5.5 34.9 5.6 35.2 5.8 35.5 5.9 35.9 6.3 36.2 7 36.3 8.4 36.4 8.6 36.5 8.7 36.8 9.1 39.8 10.7 41.8 11.3 44.8 11.6 47.4 11.8 50 12
The equivalence point is a (36.3, 8.4) with the values of Volume of NaOH = 36.3mL, and pH = 8.4. The moles of NaOH and CH 3 COOH = 0.0363L * 0.0970 = 0.0035211 moles The mass of CH 3 COOH in vinegar: 0.0035211 moles CH 3 COOH * 60.052grams/mole CH 3 COOH = 0.2114grams Percent of CH 3 COOH in vinegar: % CH 3 COOH = (mass of CH 3 COOH/ mass of vinegar ) * 100% = (0.2114/4.05)*100% = 5.22% Percent error: Percent error = ((experimental value – actual value)/actual value)*100% [(5.22-5.00)/5.00]*100% = 4.4% K a of the acid K a =10 -pH at half volume Half volume = 36.3/2= 18.15 At 18.15 pH ~ 3.8 10 -3.8 = 1.58*10 -4 V. Conclusion The main purpose of this experiment was to identify the differences between acids and bases. The equivalence point was found through titration curve was measured to be a pH of 8.4 and Volume of NaOh of 36.3mL The percentage of CH 3 COOH in vinegar is around 5.22% which is close to the theoretical value of 5.00%. The percent error was 4.40%, which shows that there was a little uncertainty in results. The K a experimental result is 1.58*10 -4 which is close to the theoretical result = 1.84*10 -4 . From this experiment, I have learned to do accurate titration method, how to calculate K a constant, pH of the solutions, and differentiate the acids and base. There can appear some mistakes while adding volumes during titration which
eventually leads to some deviations in numbers. However, the results that we got from this experiment are very close to their theoretical values.
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