worksheet_03_103

pdf

School

University of Wisconsin, Madison *

*We aren’t endorsed by this school

Course

103

Subject

Chemistry

Date

Jan 9, 2024

Type

pdf

Pages

8

Uploaded by ChancellorCaterpillarMaster871

Report
1 CHEMISTRY 103 – WORKSHEET #3 – Module 3 Chemical Reactions Do the topics appropriate for your course Prepared by Dr. Tony Jacob https://clc.chem.wisc.edu (Resource page) ACIDS: Produce H + in solution; for Chem 103 acids begin with H (except H 2 O) or contain: –COOH STRONG ACIDS ( best to memorize ): HCl, HBr, HI, HNO 3 , HClO 4 , H 2 SO 4 (note: H 2 SO 4 (aq) ® H + (aq) + HSO 4 - (aq)) WEAK ACIDS ( best to memorize ): CH 3 COO H (acetic acid); H 3 PO 4 (phosphoric acid); H 2 CO 3 (carbonic acid) BASES: Produce OH - in solution (e.g., NaOH(aq) ® Na + (aq) + OH - (aq)) STRONG BASES : LiOH, NaOH, KOH; Ca(OH) 2 , Sr(OH) 2 , Ba(OH) 2 WEAK BASES : NH 3 ELECTROLYTES: Chemicals that generate ions Strong electrolytes = large number of ions: 1. strong acids, 2. strong bases, 3. soluble ionic compounds Weak electrolytes = small number of ions: 1. weak acids, 2. weak bases Nonelectrolytes = no ions: 1. molecular compounds, 2. insoluble ionic compounds CONDUCTIVITY TEST: a light bulb dipped into a solution is used to test conductivity; bright light: strong electrolyte/many ions (strong acids, strong bases, soluble ionic compounds) dim light: weak electrolyte/small ions. (weak acids, weak bases) no light: nonelectrolyte/no ions. (insoluble ionic compounds, molecular compounds) Solubility Rules Soluble Exceptions Insoluble Exceptions Li + , Na + , K + , Rb + , Cs + , NH 4 + OH - , CO 3 2- , PO 4 3- , S 2- Li + , Na + , K + , Rb + , Cs + , NH 4 + NO 3 - , ClO 3 - , ClO 4 - , CH 3 COO - CrO 4 2- Li + , Na + , K + , Rb + , Cs + , NH 4 + , Mg 2+ Cl - , Br - , I - Ag + , Pb 2+ , Hg 2 2+ SO 4 2- Ca 2+ , Sr 2+ , Ba 2+ , Pb 2+ WRITING REACTIONS (steps) I. Molecular Reaction: All compounds are written in a molecular form; no ions. 1. Names ® formulas (if needed) 2. Assign charges and balance reactant formulas 3. For products: Switch partners; use only 1 of each ion initially 4. Assign charges to product formulas and balance product formulas 5. Balance reaction II. Complete Ionic Reaction: Break all appropriate chemicals into ions Break up 1. strong acids (memorized) 2. strong bases (memorized) 3. soluble ionic compounds (solubility rules) Don't break up 1. weak acids (acids that are not strong acids) 2. weak bases (bases that are not strong bases) 3. insoluble ionic compounds (solubility rules) 4. molecular compounds (2 or more nonmetals) Unusual ones: H 2 CO 3 (aq) ® H 2 O(l) + CO 2 (g); H 2 SO 3 (aq) ® H 2 O(l) + SO 2 (g); H 2 SO 4 (aq) ® H + (aq) + HSO 4 - (aq) III. Net Ionic Reaction : Cross out common ions (spectator ions); if everything cancels out ® no reaction H + A - H + A - H + A - H + A - A - H + H A H A H A
2 TYPES OF REACTIONS Precipitation (ppt) : MA(aq) + NB(aq) ® MB(aq) + NA (s) Acid/Base : acid(aq) + base(aq) ® salt(aq) + H 2 O(l) Gas forming : [HCO 3 - (aq) or CO 3 2- (aq)] + H + (acid)(aq) ® H 2 CO 3 (aq) ® H 2 O(l) + CO 2 (g) (see below) Combustion : C x H y (O z ) + O 2 (g) ® CO 2 (g) + H 2 O(g) (can be C x H y (O z ) or C x H y ) Redox : change in oxidation number TYPES OF REACTIONS (examples of molecular, complete ionic, and net ionic reactions for each type of reaction) 1. Precipitation 2 aqueous solutions switch partners: produce a solid and a salt (salt = soluble ionic compound) Example 1: Barium nitrate and potassium sulfate are mixed. Write the molecular, complete ionic and net ionic reactions. Answer 1: Ba(NO 3 ) 2 (aq) + K 2 SO 4 (aq) ® BaSO 4 (s) + 2KNO 3 (aq) ( molecular reaction ) Ba 2+ (aq) + 2NO 3 - (aq) + 2K + (aq) + SO 4 2- (aq) ® BaSO 4 (s) + 2K + (aq) + 2NO 3 - (aq) ( complete ionic reaction ) Ba 2+ (aq) + SO 4 2- (aq) ® BaSO 4 (s) ( net ionic reaction ) 2. Acid/Base (neutralization) Acid + Base ® H 2 O + salt; acid and base switch partners: usually produce H 2 O and a salt Example 2: Nitric acid and sodium hydroxide are mixed (strong acid (SA) + strong base (SB)). Write the molecular, complete ionic and net ionic reactions. Answer 2: SA + SB: HNO 3 (aq) + NaOH(aq) ® H 2 O(l) + NaNO 3 (aq) ( molecular reaction ) H + (aq) + NO 3 - (aq) + Na + (aq) + OH - (aq) ® H 2 O(l) + Na + (aq) + NO 3 - (aq) ( complete ionic reaction ) H + (aq) + OH - (aq) ® H 2 O(l) (net ionic reaction) Example 3: Acetic acid and lithium hydroxide are mixed (weak acid (WA) + strong base (SB)). Write the molecular, complete ionic and net ionic reactions. Answer 3: WA + SB: CH 3 COOH(aq) + LiOH(aq) ® H 2 O(l) + LiCH 3 COO(aq) ( molecular reaction ) CH 3 COOH(aq) + Li + (aq) + OH - (aq) ® H 2 O(l) + CH 3 COO - (aq) + Li + (aq) ( complete ionic reaction ) CH 3 COOH(aq) + OH - (aq) ® H 2 O(l) + CH 3 COO - (aq) ( net ionic reaction ; note difference from SA+SB (example 2) vs WA+SB) 3. Gas-Forming Carbon dioxide gas , CO 2 : acid (H + ) + CO 3 2- (aq) ® H 2 CO 3 (aq) ® H 2 O(l) + CO 2 (g) Sulfur dioxide gas , SO 2 : acid (H + ) + SO 3 2- (aq) ® H 2 SO 3 (aq) ® H 2 O(l) + SO 2 (g) Dihydrogen sulfide gas , H 2 S: acid (H + ) + S 2- (aq) ® H 2 S(g) Hydrogen gas , H 2 : metal(s) + H 2 O(l) or acid (H + ) ® M + (aq) + OH - (aq) + H 2 (g) (this is also a redox reaction) Example 4: Hydrochloric acid and sodium carbonate are mixed. Write the molecular, complete ionic and net ionic reactions. Answer 4: 2HCl(aq) + Na 2 CO 3 (aq) ® H 2 CO 3 (aq) + 2NaCl(aq) H 2 CO 3 (aq) breaks up: H 2 CO 3 (aq) ® H 2 O(l) + CO 2 (g) to yield: 2HCl(aq) + Na 2 CO 3 (aq) ® H 2 O(l) + CO 2 (g) + 2NaCl(aq) ( molecular reaction ; CO 2 (g) is the gas in this gas-forming reaction) 2H + (aq) + 2Cl - (aq) + 2Na + (aq) + CO 3 2- (aq) ® H 2 O(l) + CO 2 (g) + 2Na + (aq) + 2Cl - (aq) ( complete ionic reaction ) 2H + (aq) + CO 3 2- (aq) ® H 2 O(l) + CO 2 (g) ( net ionic reaction ) 4. Combustion C x H y (O z ) + O 2 (g) ® CO 2 (g) + H 2 O(g) {the bold part of this reaction is unchanged in other combustion reactions} Example 5: Octane, C 8 H 18 , is burned. Write the molecular, complete ionic and net ionic reactions. Answer 5: 2C 8 H 18 (g) + 25O 2 (g) ® 16CO 2 (g) + 18H 2 O(g) ( molecular reaction ; when balancing: first balance C, then H, then O) 2C 8 H 18 (g) + 25O 2 (g) ® 16CO 2 (g) + 18H 2 O(g) ( complete ionic reaction ) 2C 8 H 18 (g) + 25O 2 (g) ® 16CO 2 (g) + 18H 2 O(g) ( net ionic reaction ) 5. Redox (see the next page) oxidation numbers change as chemicals go from reactants to products
3 REDOX 1. Assign Oxidation Numbers 1. Elements = 0 2. In a compound: a. Group 1A (Li, Na,...) +1 (always) b. Group 2A (Be, Mg,...) +2 (always) c. F -1 (always) d. H +1 (usually; can also be –1 with MH x ; (e.g., NaH)) e. O -2 (usually; can also be: –1 with O 2 2- (e.g., H 2 O 2 ); 1 / 2 with O 2 - (e.g., KO 2 ); +1 with F (e.g., F 2 O 2 )) 3. Sum Rule: Sum of all the oxidation numbers = total charge on the compound 2. Identify: chemical oxidized, reduced, oxidizing agent, reducing agent; must be reactants (no products) LEO the lion goes GER (LEO = lose e - oxidized; GER = gain e - reduction) If oxidation numbers going from reactants ® products get more positive Þ reactant is oxidized If oxidation numbers get more negative Þ reactant is reduced Hint: What is oxidized is also the reducing agent; what is reduced is also the oxidizing agent. Example 6: a. In the reaction shown, what is oxidized, reduced, oxidizing agent, and reducing agent? b. How many electrons were transferred in the reaction? Cu(s) + 2HNO 3 (aq) ® CuO(s) + 2NO 2 (g) + H 2 O(l) Answer 6: a. Cu(s) = oxidized, HNO 3 (aq) = reduced, oxidizing agent = HNO 3 (aq), reducing agent = Cu(s) {Cu: 0 ® +2: becoming more positive ® oxidized; N in HNO 3 : 5 ® 4: becoming more negative ® reduced; HNO 3 is reduced ® oxidizing agent; Cu is oxidized ® reducing agent} b. 2 electrons transferred {Cu: 0 ® 2: 2e - ; or N: 5 ® 4: 1e - ; } 3. Is it a Redox Rxn? Redox reaction occurs when oxidation numbers change in a reaction. Hints: If reaction has an element on one side and that element is in a compound on the other side ® nearly always a redox reaction If reaction is a combustion reaction ® redox reaction If reaction is an acid/base , precipitation , or gas-forming reaction (except for metal + (H + or H 2 O)) ® not a redox reaction reduction oxidation - + 0 change in oxidation numbers 2e Cu atom 1Cu atom ( ) = 2e lost 1e N atom 2 N atom ( ) = 2e gained CuO(s) + 2NO 2 (g) + H 2 O(l) Cu(s) + 2HNO 3 (aq) 0 1 5 -2 2 -2 4 -2 1 -2 reduction oxidation
Your preview ends here
Eager to read complete document? Join bartleby learn and gain access to the full version
  • Access to all documents
  • Unlimited textbook solutions
  • 24/7 expert homework help
4 4. Metal Activity Series – a list of how easily a metal is oxidized; a metal higher on the list will react with an ion lower on the list ( down and to the right ); reactions that are up and to the right will not occur Reactions Occur: Mn(s) + FeBr 2 (aq) ® MnBr 2 (aq) + Fe(s) Þ reaction occurs since down and to the left on the activity series 2Cr(s) + 6HBr(aq) ® 2CrBr 3 (aq) + 3H 2 (g) Þ reaction occurs since down and to the left on the activity series Reactions Don’t Occur: Cu(s) + Cr 3+ (aq) Þ no reaction occurs since up and to the right on the activity series Fe(s) + Mn 2+ (aq) Þ no reaction occurs since up and to the right on the activity series Reaction Occurs When metal is above the cation No Reaction Occurs When metal is below the cation 1. Which of the following is a weak acid and strong base reaction? a. HF(aq) + NH 3 (aq) ® NH 4 + (aq) + F - (aq) b. Ba(OH) 2 (aq) + 2HCl(aq) ® Ba 2+ (aq) + 2Cl - (aq) + 2H 2 O(l) c. H 3 PO 4 (aq) + 3LiOH(aq) ® 3Li + (aq) + PO 4 3- (aq) + 3H 2 O(l) d. CH 3 COOH(aq) + NH 3 (aq) ® CH 3 COO - (aq) + NH 4 + (aq) e. None of the above reactions match the above statement. 2. Which reaction is the balanced molecular reaction for iron(II) nitrate reacting with sodium sulfide to form a precipitate? a. NO 3 - (aq) + Na + (aq) ® NaNO 3 (aq) b. Fe 2 (NO 3 )(aq) + NaS(aq) ® Fe 2 S(s) + NaNO 3 (aq) c. Fe(NO 3 ) 2 (aq) + Na 2 S(aq) ® FeS(s) + 2NaNO 3 (aq) d. 2Fe(NO 3 ) 2 (aq) + Na 2 S(aq) ® 2FeNa(s) + S(NO 3 ) 4 (aq) e. Fe 2+ (aq) + 2NO 3 - (aq) + 2Na + (aq) + S 2- (aq) ® FeS(s) + 2Na + (aq) + 2NO 3 - (aq) 3. What is the sum of the coefficients for the balanced combustion reaction for propanol, C 3 H 8 O(l)? a. 6 b. 11 c. 13 d. 25 e. None of these are correct. Mn(s) Mn 2+ (aq) + 2e - Cr(s) Cr 3+ (aq) + 3e - Fe(s) Fe 2+ (aq) + 2e - Cu(s) Cu 2+ (aq) + 2e - H 2 (g) 2H + (aq) + 2e - Al(s) Al 3+ (aq) + 3e - Zn(s) Zn 2+ (aq) + 2e - More Easily Oxidized Mn(s) Mn 2+ (aq) + 2e - Cr(s) Cr 3+ (aq) + 3e - Fe(s) Fe 2+ (aq) + 2e - Cu(s) Cu 2+ (aq) + 2e - H 2 (g) 2H + (aq) + 2e - Al(s) Al 3+ (aq) + 3e - Zn(s) Zn 2+ (aq) + 2e -
5 4. What is the oxidation number of sulfur in S 2 O 3 2- ? a. 6 b. -3 c. 4 d. 2 e. 3 5. Using the chemical reaction shown select which statements are CORRECT . 8S 2- (aq) + 16NO 3 - (aq) + 32H + (aq) ® 16NO 2 (g) + S 8 (s) + 16H 2 O(l) i. S 2- is oxidized ii. N in NO 3 - is oxidized iii. NO 3 - is the oxidizing agent a. i b. i, ii c. ii, iii d. i, iii e. i, ii, iii 6. Which reaction is the balanced net ionic reaction for the reaction of acetic acid and sodium hydroxide? a. H + (aq) + OH - (aq) ® H 2 O(l) b. CH 3 COOH(aq) + NaOH(aq) ® CH 3 COONa(aq) + H 2 O(l) c. CH 3 COOH(aq) + OH - (aq) ® CH 2 COOH(aq) + H 2 O(l) d. CH 3 COOH(aq) + OH - (aq) ® CH 3 COO - (aq) + H 2 O(l) e. H + (aq) + NaOH(aq) ® Na + (aq) + H 2 O(l) 7. The following compounds were used in a conductivity test. Which will cause the light bulb to shine brightly when dissolved in water? i. lead(II) chloride ii. potassium fluoride iii. acetic acid a. i b. ii c. iii d. i, ii e. i, iii f. ii, iii
6 8. When ammonia gas reacted with oxygen gas over a catalyst, nitrogen gas and water were formed. What chemical is the reducing agent ? (Hint 1: Write the chemical reaction. Hint 2: No need to balance; stoichiometric coefficients not used when assigning oxidation numbers.) a. ammonia gas b. oxygen gas c. nitrogen gas d. water e. the catalyst 9. Use the table below with the given chemical reaction observations to determine the unknown chemicals A and B . There are three possibilities for the unknown chemical shown in the last row: BaCO 3 , AgNO 3 , and Fe(NO 3 ) 2 . Chemical mixed with the Unknown Unknown A Unknown B HCl Bubbles Precipitate KOH No observed change Precipitate H 2 SO 4 Precipitate; bubbles No observed change Unknowns: BaCO 3 AgNO 3 Fe(NO 3 ) 2 BaCO 3 AgNO 3 Fe(NO 3 ) 2 a. Unknown A = BaCO 3 , Unknown B = AgNO 3 b. Unknown A = BaCO 3 , Unknown B = Fe(NO 3 ) 2 c. Unknown A = AgNO 3 , Unknown B = Fe(NO 3 ) 2 d. Unknown A = AgNO 3 , Unknown B = BaCO 3 e. Unknown A = Fe(NO 3 ) 2 , Unknown B = BaCO 3 f. Unknown A = Fe(NO 3 ) 2 , Unknown B = AgNO 3 10. Which of the following reactions are redox reactions ? i. C 2 H 4 (g) + 3O 2 (g) ® 2CO 2 (g) + 2H 2 O(g) ii. Al(s) + Fe(NO 3 ) 3 (aq) ® Al(NO 3 ) 3 (aq) + Fe(l) iii. N 2 (g) + 3O 2 (g) ® 2NO 3 (g) a. i b. ii c. iii d. i, ii e. i, iii f. ii, iii g. i, ii, iii
Your preview ends here
Eager to read complete document? Join bartleby learn and gain access to the full version
  • Access to all documents
  • Unlimited textbook solutions
  • 24/7 expert homework help
7 CHEMISTRY 103 – WORKSHEET #3 - ANSWERS Chemical Reactions Do the topics appropriate for your lecture Prepared by Dr. Tony Jacob https://clc.chem.wisc.edu (Resource page) ANSWERS 1. c {“a”: weak acid + weak base; “b”: strong acid + strong base; “c”: weak acid + strong base; “d”: weak acid + weak base} 2. c {converting names to formulas: iron(II) = Fe 2+ ; nitrate = NO 3 - ; iron(II) nitrate = Fe(NO 3 ) 2 ; sodium = Na + ; sulfide = S 2- ; sodium sulfide = Na 2 S; switch partners to yield (Fe 2+ )(S 2- ) and balance = FeS, and (Na + )(NO 3 - ) and balance = NaNO 3 ; these are the two products; for molecular reactions the chemicals are kept in their molecular form and are not broken into ions ; since reactions “a” and “e” have ions they are not correct; reaction “b” has the wrong individual formulas in both reactants and products: for instance, NaS rather than Na 2 S; reaction “d” the product formed contain 2 cations (Fe 2+ )(Na + ) and 2 anions (S 2- )(NO 3 - ) which is incorrect; only reaction “c” has the correct chemical formulas and is not broken into ions} 3. d {combustion reactions: C x H y O z + O 2 (g) ® CO 2 (g) + H 2 O(g); C 3 H 8 O(l) + O 2 (g) ® CO 2 (g) + H 2 O(g); when balancing combustion reactions balance in the order: C, H, then O: Balance C: C 3 H 8 O(l) + O 2 (g) ® 3CO 2 (g) + H 2 O(g); Balance H: C 3 H 8 O(l) + O 2 (g) ® 3CO 2 (g) + 4H 2 O(g); Balance O: C 3 H 8 O(l) + 9 / 2 O 2 (g) ® 3CO 2 (g) + 4H 2 O(g); get rid of fraction by multiplying entire reaction by 2: 2C 3 H 8 O(l) + 9O 2 (g) ® 6CO 2 (g) + 8H 2 O(g); coefficients: 2 + 9 + 6 + 8 = 25} 4. d {sum of the oxidation numbers = charge: 2S + 3O = -2; 2(x) + 3(-2) = -2; 2x - 6 = -2; 2x = 4; x = 2} 5. d {S 2- : S = -2; S 8 : S = 0; S: -2 ® 0 ® S 2- oxidized = reducing agent; therefore choice “i” is true ; NO 3 - : N = +5; NO 2 : N = +4; N: +5 ® +4 ® N is reduced = oxidizing agent; therefore choice “ii” is false and choice “iii” is true ; option “d” has “i” and “iii”} 6. d {CH 3 COOH is a weak acid so it does not break up and therefore answers “a” and “e” are incorrect ; the acidic H is the H bolded/underlined: CH 3 COO H therefore answer “c” is incorrect because the wrong H came off as shown in the product formula; answer “b” is a correctly written reaction, but it represents the molecular reaction rather than the net ionic reaction; the correct answer is “d” with the correct H being removed from CH 3 COO H , NaOH being broken up (strong base) and the Na + being canceled out as it is a spectator ion} 7. b {“i”: lead(II) chloride = PbCl 2 is an insoluble ionic compound : non-electrolyte therefore no light ; “ii”: potassium fluoride = KF is a soluble ionic compound : strong electrolyte therefore bright light ; “iii”: acetic acid = CH 3 COOH is a weak acid : weak electrolyte therefore dim light }
8 8. a {write the reaction: 4NH 3 (g) + 3O 2 (g) ® 2N 2 (g) + 6H 2 O(l); Note: the reaction does not need to be balanced ; only the correct formulas for each chemical is needed since the stoichiometric coefficients are not used when assigning oxidation numbers; assign oxidation numbers: ; what is oxidized: NH 3 : N: goes from -3 to 0; reduced: O 2 : O: goes from 0 to -2; oxidizing agent: O 2 (same as what is reduced); reducing agent: NH 3 (same as what is oxidized); all must be reactants } 9. a { Unknown A must be BaCO 3 as a carbonate, CO 3 2- , when combined with an acid like HCl will form H 2 CO 3 which then breaks into CO 2 (g) and H 2 O(l). Neither AgNO 3 nor Fe(NO 3 ) 2 will generate any bubbles with HCl. Unknown B must be AgNO 3 since AgNO 3 mixed with HCl will form AgCl(s) which is insoluble and forms a precipitate. To contrast, BaCO 3 mixed with HCl will form BaCl 2 which is soluble and does not form a precipitate. Likewise, Fe(NO 3 ) 2 mixed with HCl will form FeCl 2 which is soluble and does not form a precipitate.} 10. g {Rxn i: combustion reaction which is a redox reaction; also oxidation number of O starts at 0 in O 2 and goes to -2 in both CO 2 (g) and H 2 O; change in oxidation number ® redox; can also focus on C: -2 in C 2 H 4 to +4 in CO 2 ® redox! Rxn ii: for Al(s): Al = 0; for Al in Al(NO 3 ) 3 (aq): Al = +3 since the charge on NO 3 - is -1; so Al goes from 0 to +3 ® redox! can also focus on Fe: goes from +3 in Fe(NO 3 ) 3 to 0 in Fe(l) ® redox! Rxn iii: N in N 2 (g): N = 0 while in NO 3 - , N has an oxidation number of +6; change in oxidation number ® redox; can also focus on O: goes from 0 in O 2 ® -2 in NO 3 - ® redox} + + 4NH 3 (g) 3O 2 (g) 2N 2 (g) 6H 2 O(l) +1 -3 0 0 +1 -2 oxidized reduced