Syn and Ana Nickel complex lab report hutchinsae1 (1)
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Introductory Chemistry 1110
Synthesis and Analysis of a Nickel Complex
Lab reports are due during the week of Nov. 13
th
– 17
th
, 2023
(Note: this lab report is worth 200 points!)
Your lab report must contain the following information:
Experimental data may be collected with other students in introductory chemistry labs.
However, I understand that sharing information required for a lab report or unknown
submission (including but not limited to word processing or spreadsheet files,
calculations, graphs, conclusions and additional problems at the end of the lab report)
with other students is a violation of the University Academic Integrity Code.
____
hutchinsae1@appstate.edu__
_______________________________
Signature (or ASU email address, to indicate signature if an electronic copy is submitted)
1. Completed Tables 1 - 4 as found in your lab manual.
Table 1
Mass of NiSO
4
· 6H
2
O
1.001 g
Volume of en added
5.200 g
Table 2
Mass of filter paper + beaker
30.448 g
Filter paper + beaker + Ni-en complex
31.648 g
Mass of your Ni-en complex
0.3020 g
Table 3
Mass of Ni-en complex analyzed
0.3020 g
Concentration of HCl (aq)
0.1333 M
Initial buret reading
12.90 mL
Final buret reading
36.72 mL
Volume of HCl added
23.82 mL
Moles of HCl added
0.0031 mol
Moles of en in Ni-en complex analyzed
0.0015 mol
Mass of en in Ni-en complex analyzed
0.0901 g
Table 4
Mass of filter paper + watchglass
67.267 g
Mass of filter paper + watchglass +
Ni(DMG)
2
67.487 g
Mass of Ni(DMG)
2
0.22 g
Moles Ni
2+
in Ni-en complex analyzed
7.61 x 10^-4 mol Ni^2+
Mass of Ni
2+
in Ni-en complex analyzed
0.0446 g Ni^2+
2. Completed Tables 5 and 6 as found in your lab manual.
Table 5
Moles of SO
4
2-
in sample analyzed
7.61 x10 ^-4 SO
4
2
mol
Mass of SO
4
2-
in sample analyzed
0.0731 g SO
4
2
Table 6
g en + g Ni
2+
+ g SO
4
2-
0.2078 g
g of H
2
O
in Ni-en complex analyzed
0.0942 g
moles of H
2
O
in Ni-en complex analyzed
0.0052 mol H
2
O
3. Show the calculation to determine the moles of HCl that was added during the
titration.
0.1333 M x 0.02382 L = 0.0031 mol
4. Show the calculation to determine the moles of ethylenediamine, en, in your Ni-en
complex you analyzed. Be sure to include any appropriate chemical reactions that were
used in the calculation.
0.0031 mol x 1 mol en/2 mol HCl = 0.0015 mol en
5. Show the calculation to determine the grams of ethylenediamine in your Ni-en
complex you analyzed.
0.0015 mol en x 60.089 g en/ 1 mol en = 0.0901 g en
6. Starting with the mass of Ni(DMG)
2
(that is the red precipitate), show the calculation
to obtain the moles of Ni
2+
that is present in your Ni-en complex you analyzed. Be sure to
include any appropriate chemical reactions that were used in the calculation.
0.220 g Ni(DMG)2 x 1 mol Ni(DMG)2/ 288.92 Ni(DMG)2 x 1 mol Ni2+/ 1 mol
Ni(DMG)2 = 7.61 x10^-4
7. Show the calculation to determine the grams of Ni
2+
in your Ni-en complex you
analyzed.
7.61 x10^-4 mol Ni2+ x 58. 6934 g/mol Ni2+/ 1 mol Ni2+ = 0.0446 g Ni2+
8. Show the calculation to determine the grams of sulfate, SO
4
2
, in your Ni-en complex
you analyzed.
7.61 x 10^-4 mol Ni2+ x 1 mol SO
4
2
/ 1 mol Ni2+ = 7.61 x10 ^-4 SO
4
2
9. Show the calculation to obtain sum of the en, Ni
2+
, and SO
4
2
masses in your Ni-en
complex.
7.61 x 10^-4 mol SO
4
2
x 96.0616 g SO
4
2
/ 1mol SO
4
2
= 0.0731 g SO
4
2
10. Show the calculation to obtain the grams of water in your Ni-en complex you
analyzed.
.0901 g + 0.04469 g + 0.0731 g = 0.2078 0.302 - 0.2078 = 0.0942 g H2O
11. Show the calculation to determine the moles of water in your Ni-en complex you
analyzed.
0.0942 g H
2
O x 1 mol H
2
O/ 18.015 g H
2
O = 0.0052 mol H
2
O
12. Using the moles of each species in your Ni-en complex, show the calculations to
determine the empirical formula for your Ni-en complex.
7.61 x 10^-4 / 7.61 x10^-4 = 1 Ni2+
7.61 x10 ^-4 / 7.61 x 10^-4 = 1 SO42-
0.0015 mol en/ 7.61 x 10^-4 = ~ 2 En
0.0052 / 7.61x10^-4 ~ 7 water
13. Knowing your Ni-en complex’s empirical formula, write the overall balanced
reaction that took place describing your synthesis.
NiSO
4 *
6H
2
O + 2 en + H
2
O --> [Ni(en)(H
2
O)
4
]SO
4
*
4H
2
O
14. Show the theoretical yield calculation for your Ni-en complex you synthesized.
0.888 g NiSO
4
* 6H
2
O x 1 mol NiSO
4
* 6H
2
O / 262.91 g NiSO
4
* 6H
2
O x 1 mol
complex/ 1 mol x 387.045 g complex/ 1 mol complex = 1.30 g
15. Show your percent yield calculation for your Ni-en complex you synthesized.
1.184 g / 1.30 g x 100 = 91 %
Checklist of Items to Submit
_______
Hard copy of lab report printed, academic integrity code signed, stapled and
ready to hand in before the start of pre-lab (if required by your instructor)
__
_check_
___
Electronic copy with academic integrity code submitted on AsULearn
before the start of pre-lab under topic “Synthesis and Analysis of a Ni
Complex Lab Report Submission”
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