Syn and Ana Nickel complex lab report hutchinsae1 (1)

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Appalachian State University *

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1110

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Chemistry

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Dec 6, 2023

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docx

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3

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Introductory Chemistry 1110 Synthesis and Analysis of a Nickel Complex Lab reports are due during the week of Nov. 13 th – 17 th , 2023 (Note: this lab report is worth 200 points!) Your lab report must contain the following information: Experimental data may be collected with other students in introductory chemistry labs. However, I understand that sharing information required for a lab report or unknown submission (including but not limited to word processing or spreadsheet files, calculations, graphs, conclusions and additional problems at the end of the lab report) with other students is a violation of the University Academic Integrity Code. ____ hutchinsae1@appstate.edu__ _______________________________ Signature (or ASU email address, to indicate signature if an electronic copy is submitted) 1. Completed Tables 1 - 4 as found in your lab manual. Table 1 Mass of NiSO 4 · 6H 2 O 1.001 g Volume of en added 5.200 g Table 2 Mass of filter paper + beaker 30.448 g Filter paper + beaker + Ni-en complex 31.648 g Mass of your Ni-en complex 0.3020 g Table 3 Mass of Ni-en complex analyzed 0.3020 g Concentration of HCl (aq) 0.1333 M Initial buret reading 12.90 mL Final buret reading 36.72 mL Volume of HCl added 23.82 mL Moles of HCl added 0.0031 mol Moles of en in Ni-en complex analyzed 0.0015 mol Mass of en in Ni-en complex analyzed 0.0901 g Table 4 Mass of filter paper + watchglass 67.267 g Mass of filter paper + watchglass + Ni(DMG) 2 67.487 g
Mass of Ni(DMG) 2 0.22 g Moles Ni 2+ in Ni-en complex analyzed 7.61 x 10^-4 mol Ni^2+ Mass of Ni 2+ in Ni-en complex analyzed 0.0446 g Ni^2+ 2. Completed Tables 5 and 6 as found in your lab manual. Table 5 Moles of SO 4 2- in sample analyzed 7.61 x10 ^-4 SO 4 2 mol Mass of SO 4 2- in sample analyzed 0.0731 g SO 4 2 Table 6 g en + g Ni 2+ + g SO 4 2- 0.2078 g g of H 2 O in Ni-en complex analyzed 0.0942 g moles of H 2 O in Ni-en complex analyzed 0.0052 mol H 2 O 3. Show the calculation to determine the moles of HCl that was added during the titration. 0.1333 M x 0.02382 L = 0.0031 mol 4. Show the calculation to determine the moles of ethylenediamine, en, in your Ni-en complex you analyzed. Be sure to include any appropriate chemical reactions that were used in the calculation. 0.0031 mol x 1 mol en/2 mol HCl = 0.0015 mol en 5. Show the calculation to determine the grams of ethylenediamine in your Ni-en complex you analyzed. 0.0015 mol en x 60.089 g en/ 1 mol en = 0.0901 g en 6. Starting with the mass of Ni(DMG) 2 (that is the red precipitate), show the calculation to obtain the moles of Ni 2+ that is present in your Ni-en complex you analyzed. Be sure to include any appropriate chemical reactions that were used in the calculation. 0.220 g Ni(DMG)2 x 1 mol Ni(DMG)2/ 288.92 Ni(DMG)2 x 1 mol Ni2+/ 1 mol Ni(DMG)2 = 7.61 x10^-4 7. Show the calculation to determine the grams of Ni 2+ in your Ni-en complex you analyzed. 7.61 x10^-4 mol Ni2+ x 58. 6934 g/mol Ni2+/ 1 mol Ni2+ = 0.0446 g Ni2+ 8. Show the calculation to determine the grams of sulfate, SO 4 2 , in your Ni-en complex you analyzed. 7.61 x 10^-4 mol Ni2+ x 1 mol SO 4 2 / 1 mol Ni2+ = 7.61 x10 ^-4 SO 4 2
9. Show the calculation to obtain sum of the en, Ni 2+ , and SO 4 2 masses in your Ni-en complex. 7.61 x 10^-4 mol SO 4 2 x 96.0616 g SO 4 2 / 1mol SO 4 2 = 0.0731 g SO 4 2 10. Show the calculation to obtain the grams of water in your Ni-en complex you analyzed. .0901 g + 0.04469 g + 0.0731 g = 0.2078 0.302 - 0.2078 = 0.0942 g H2O 11. Show the calculation to determine the moles of water in your Ni-en complex you analyzed. 0.0942 g H 2 O x 1 mol H 2 O/ 18.015 g H 2 O = 0.0052 mol H 2 O 12. Using the moles of each species in your Ni-en complex, show the calculations to determine the empirical formula for your Ni-en complex. 7.61 x 10^-4 / 7.61 x10^-4 = 1 Ni2+ 7.61 x10 ^-4 / 7.61 x 10^-4 = 1 SO42- 0.0015 mol en/ 7.61 x 10^-4 = ~ 2 En 0.0052 / 7.61x10^-4 ~ 7 water 13. Knowing your Ni-en complex’s empirical formula, write the overall balanced reaction that took place describing your synthesis. NiSO 4 * 6H 2 O + 2 en + H 2 O --> [Ni(en)(H 2 O) 4 ]SO 4 * 4H 2 O 14. Show the theoretical yield calculation for your Ni-en complex you synthesized. 0.888 g NiSO 4 * 6H 2 O x 1 mol NiSO 4 * 6H 2 O / 262.91 g NiSO 4 * 6H 2 O x 1 mol complex/ 1 mol x 387.045 g complex/ 1 mol complex = 1.30 g 15. Show your percent yield calculation for your Ni-en complex you synthesized. 1.184 g / 1.30 g x 100 = 91 % Checklist of Items to Submit _______ Hard copy of lab report printed, academic integrity code signed, stapled and ready to hand in before the start of pre-lab (if required by your instructor) __ _check_ ___ Electronic copy with academic integrity code submitted on AsULearn before the start of pre-lab under topic “Synthesis and Analysis of a Ni Complex Lab Report Submission”
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