CH_-_second_semester_review_page_2
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Date
Oct 30, 2023
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Chem
H
—
Second
Semester
Review
Sheet
7]
;>
Eifee
e
P
This
is
NOT
a
comprehensive
study
guide,
in
addition
to
the
topics
covered
2™
-
here
you
should
review:
(in
recommended
order)
.
4x
=
X
=
LEwo
1)
old
tests
4)
worksheets
2)
old
quizzes
5)
homework
=¥
.
)
.
D.0Mb
ST
3)
labs
6)
textbook
=\
(LRt
V.82
\»87g
of
KMnO4
are
dissolved
in
635ml
of
water.
What
is
the
molarity?
}","\.’
molality?
freezing
point?
What
is
the
new
molarity
if
it
is
diluted
to
1.6L?
”
)
-+
A
+
\o.
Ae
2)
A
reaction
occurs
between
a
35ml
of
2.5M
CH;COOH
and
45g
NaHCOs,
Whe
¥
Pg
=
U,
+
|}
/
Write
the
equation.
What
is
the
limiting
reagent?
How
many
grams
of
No—
)
gaseous
product
are
formed?
What
is
the
concentration
of
the
aqueous
0,
0S
L4
hAe
»
—
product?
If
only
84ml
of
gas
werg7
recovered,
what
is
the
percent
yield?
Larjume
3TC
3)
Use
the
table
of
thermodynamic
data
to
answer
the
following
AH°
AG®
AS°
reaction
1|
Cy
+
Oy
>
COxg
-393.5k]
|
-394.4K]
|
2.91/pae
reaction2__|
COg)
+
%0y
>
COxg
target
rxn
3
|
Cy)
+
%Oy
2
COq
0
S
%
Calculate
AG,
AH
and
AS
for
reaction
2.
Use
Hess’s
law
and
reactions
1
and
H
ot
et
s
e
ogeid
)
ey
c==J
2
to
find
AG,
AH
and
AS
for
reaction
3.
Recalculate
AG,
AH,
AS
for
reaction
v
(e
-
("“\
ey
4
3
from
the
thermodynamic
table.
How
do
the
two
methods
of
calculation
Mg
»
@
wd
compare?
I
there
an
intermediate
in
the
overall
reaction?
Is
there
a
catalyst?
As
the
temperature
is
lowered
what
happens
to
the
reaction
rate?
Explain
4)
Consider
the
system:
CO
+
H,0
>
CO,
+
Ha.
Write
the
equilibrium
expression.
If
the
reaction
starts
with
PCO
=
1.7atm
and
PH20
=
5.4atm
and
the
Kp
=
43,
what
are the
equilibrium
pressures?
If
an
additional
3.2
atm
of
CO
is
added,
which
direction
will
the
equilibrium
shift?
What
will
the
new
equilibrium
pressures
be?
5)
Acetic
acid
has
a
Ka
=
1.8x10-5.
Write
the
dissociation
equation
and
the
equilibrium
expression.
What
is
the
pH
of
a
12M
solution
of
it?
If
excess
magnesium
is
added
to
a
25ml
solution,
what
is
the
chemical
reaction
that
occurs?
How
many
moles
of
gas
are
produced?
If
the
gas
is
collected
in
a
balloon
at
a
temperature
of
19°C
and
the
final
volume
of
the
balloon
is
175ml,
what
is
the
pressure
in
the
balloon?
Assign
oxidation
states
to
each
element
in
the
reaction
and
identify
what
is
being
oxidized
and
reduced.
Will
the
resulting
solution
be
acidic
or
basic?
If
the
half
cells
were
separated,
how
many
volts
could
be
obtained
from
the
cell?
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Collision theory states that as molecules or ions bump into each other, a reaction
will only occur if the collision has the correct amount of energy and impact is at
the right angle and location.
Describe how collision theory helps predict how temperature, pressure, and
concentration impact reaction rates.
Bathtub cleaners used to remove hard water salts usually contain acid to help
dissolve the salts.
Which will remove the salts faster?
A) 2.5% acid
B) 3% acid
C) 5% acid
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1-32. A bottle of concentrated aqueous sulfuric acid, labeled 98.0
wt% H₂SO4, has a concentration of 18.0 M.
(a) How many milliliters of reagent should be diluted to 1.000 L to
give 1.00 M H₂SO4?
(b) Calculate the density of 98.0 wt% H₂SO4-
S
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Some matches consist of a wooden stick
and a head that contains tetraphosphorous
trisulfide, P4S3(s), and that can be ignited
on any rough surface. When the match is
drawn across a rough surface, enough
heat is generated to start the reaction
represented by the following equation.
and pur
The energy that is transferred when 69.1 g of XeF4(s) is produced is
DD
FO
Use the following information to answer the next question.
Xenon tetrafluoride is a binary compound made from a noble gas. The formation of
xenon tetrafluoride can be represented by the following equation.
Xe(g) + 2 F₂(g) → XeF4(s)
AH=-251 kJ
Use the following information to answer the next two questions.
DIDIOMBATILAI
P4S3(s) + 8 O₂(g) →
SO₂(g)
A,HP,S, (S)
A,HO
P.O₁0(s)
J
F10
kJ.
P4010(s) + 3
= -155.0 kJ/mol
= -2 984.0 kJ/mol
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Identifying the limiting reactant in a drawing of a mixture
The drawing below shows a mixture of molecules:
key
carbon
hydrogen
nitrogen
sulfur
oxygen
chlorine
Suppose the following chemical reaction can take place in this mixture:
CS,(9)+30,(9)
- CO2(9)+2 SO,(9)
Of which reactant are there the most initial moles? Enter its chemical formula:
Of which reactant are there the least initial moles? Enter its chemical formula:
Which reactant is the limiting reactant? Enter its chemical formula:
Explanation
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Question 7 of 40
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Which of the following compounds can form intermolecular hydrogen bonds?
A) CH4
B) H2Se
C) NH3
D) H2
E) All of these compounds can form hydrogen
bonds.
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A common alkyne starting material is shown below. Predict the major product or missing
reagent to complete each reaction. Ignore inorganic byproducts.
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CI CI
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143,176
@
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#
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31,
80
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6
C
F6
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B
с
D
F7
*
8
F8
Cla (1 equiv)
Cla (2 equiv)
HCI (excess)
NaCl (2 equiv)
THF
Done
9
F9
-
.
F10
0
F11
27
F12
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10) In the reversible reaction A (aq) + B(aq) E → C(aq), reactant A is very expensive.
What are two ways to get it to react as fully as possible to form as much C as possible?
a) remove C as it forms, and use an excess of A
b) add another reactant that will form a precipitate with B
c) remove C as it forms, and use an excess of B
d) add another reactant that will form a precipitate with A
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●ENTROPY AND FREE ENERGY
Calculating dG from dH and dS
S
A chemical engineer is studying the two reactions shown in the table below.
In each case, he fills a reaction vessel with some mixture of the reactants and products at a constant temperature of 53.0 °C and constant total pressure. Then,
he measures the reaction enthalpy AH and reaction entropy AS of the first reaction, and the reaction enthalpy AH and reaction free energy AG of the second
reaction. The results of his measurements are shown in the table.
Complete the table. That is, calculate AG for the first reaction and AS for the second. (Round your answer to zero decimal places.) Then, decide whether, under
the conditions…
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Thank you!arrow_forwardO Course Home b Chemistry Question | bartleby + O X -> A openvellum.ecollege.com/course.html?courseld=16561285&OpenVellumHMAC=Ddd25775cc7b85cec3204f753df519590#10001 Q * E Apps YouTube O Maps E Connect - To Do As... O ocCC Moodle P chem work b help A Balance Chemical E. Gmail CHEM-1123-EW40S Late Spring 2021 Hi, ashlee v Sign Out Help Mastering Chemistry Course Home O My Courses Syllabus Part A Scores Classify these amino acids as acidic, basic, neutral polar, or neutral nonpolar. еТext Drag each item to the appropriate bin. Document Sharing • View Available Hint(s) User Settings Reset Help NH2 c=NH2 NH CH2 CH2 CH2 H,N-C-coo Course Tools > CH, CH, CH NH2 NH2 CH2 CH2 CH, CH2 CH3 CH3 HN-C-coo H,N-C-coo HN-C-coo H,Ñ-c-coo H. H. H. Asparagine Glutamine Arginine Leucine Alanine Acidic Basic Neutral polar Neutral nonpolar 10:59 PM P Type here to search 99 3/10/2021arrow_forwardX Achieve > Students: Register X Assessment - Chem 101 002X nillanlearning.com/courses/55ace5f9-441e-4942-b91a-6dde768c655e/3/k6bu5e/tools/assessment/items/9f6b56a8-92b9-4b ent Check A LGive Up? O Hint OResources Score: 25 Perform the conversions. atm 1.196 atm = 860.8 mmHg = %3D Pa 1386.9 mmHg : atm %3D 287.3 kPa = %3Darrow_forwardI need the answer for question 3arrow_forwardMon 4:35 PM nnections | Un X * Student Employment | Car X Illinois State University : H X Mind Tap - Cengage Learn X G If a sample of lithium con index.html?deploymentld%3D55750828934189288909969212&elSBN=9781305657571&nbld%3D2199898&snapshotld%3219989. * DTAP Q Search this Use the References to access important values if needed for this question. If a sample of lithium contains 2.50x10 atoms of lithium-7 and 2.00×10³ atoms of lithium-6, what is the percentage of lithium-6 atoms in the sample? Submit Answer 5 question attempts remaining Next Autosaved at 4:32 PM Backarrow_forward26) The floor tiles in SE 27 are about 1 square foot and the lab is about 25 tiles wide and about 36 tiles from front to back. When the emergency shower was demonstrated, in 10. seconds the water in the trash can was about 1 foot deep. One student estimated this was 2.5 gallons. Estimate how deep the room will get in inches after a 15 minute shower. List 3 simplifving assumptions you make in this calculation rea L-36 Tile fiDw ill it cost2 The density of gold is 27l An artist plans to apply gold leaf to a painting with an area of 2.32 f? and a thickness of 1.50arrow_forward:0: :O: VTITTO DAAMG DELLAL TTITVJTTTV Assessment - Chem 101 002 - Ac X A Achieve > Students: Register for X Applications | Rapidldentity xN Canvas LMS e-4942-b91a-6dde768c655e/3/k6bu5e/tools/assessment/items/b5bf51ff-1873-4e20-b78d-15d1b43e186d/assignments/5395362?redirectBackToOnClose%=true&en L Give Up? O Hint Resources 89.9% In each of these Lewis structures, one atom has a nonzero formal charge. Locate the atom, and indicate the charge on the atom in the Lewis structure. CH,CO, CH,NH, Rings Erase Select Draw More Erase Select Draw More sau C. // H. H N H H. H. 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