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6 of 6 individual&family development ‘ X C9_GI_MOs Wl OO O E E E T - -=00 @ CHEM106 Molecular Orbitals Spring 2016 Some of the most beautiful colors in aurora’s comes from the movement of electrons in molecular orbitals. For example, when an electron falls from an excited state position to the ground state, there is an emission of light that can be in the visible region of the spectra, producing color. For example, the transition N, >N, produces a deep red color (the * represents a molecule in an excited state — meaning it has an electron that is not in the lowest energy orbital). The transition N, > N, produces a blue violet color. Draw a MO diagram for N," and N,"". Assume the excited electron in N, is in the next available electronic orbital above the ground state. Would you expect the bond in N, or N, to be stronger, and why? Which better explains molecular geometry: valence bond theory (hybridization) or molecular orbital theory? Why? Which better explains magnetic properties of a diatomic molecule: valence bond theory (hybridization) or molecular orbital theory? Why?
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Be sure to answer all parts. Januvia, the trade name for sitagliptin, was introduced in 2006 for the treatment of type 2 diabetes. In what type of orbital does the lone pair on each N atom reside. CF3 F N. N 4 N. NH2 1 F N 1: sp orbital N 2: (select) orbital N 3: (select) orbital N 4: sp2 orbital N 5: sp? orbital 2)
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