CHM 101L M5 Equilibrium and LeChatlier Lab Report

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Southern New Hampshire University *

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101L

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Chemistry

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Feb 20, 2024

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Equilibrium and Le Chatelier’s Principle Student Name Paul S. Nomsule Date 02/12/2024
Data Activities 1, 2, and 3 The goal of this lab is to determine the concentration of acetic acid. Two different vinegar samples, one known and the other unknown, are used to determine the concentration of acetic acid in different types of acetic acid. Data Table 1 Quantity of Reagents Quantity of Reagents Quantity of Reagents Quantity of Reagents Quantity of Reagents Reagent Test Tube #1, Control Test Tube #2 Test Tube #3 Test Tube #4 Test Tube #5 Copper (II) Chlorid e 2.0 mL 2.0 mL 2.0 mL 2.0 mL 2.0 mL Sodium Chlorid e 0.0 mL 1.0 mL 2.0 mL 4.0 mL 4.0 mL Color of Solution Bright blue Dilute blue Cloudy white/blue Faint blue Diluted blue Silver Nitrate N/A N/A 1.0 mL N/A N/A Color of Solution N/A N/A white N/A N/A Water N/A N/A N/A 3.0 mL N/A Color of Solution N/A N/A N/A blue N/A © 2016 Carolina Biological Supply Company
Activity 4 Data Table 2 Stress Water Bath Temperatur e (°C) Solution Temperatu re (°C) Solution Color Direction of Shift (reactants or products) ( or ) Test tube #4 (Control Solution) N/A 25 Light blue At equilibrium Hot Water Bath 68 25 green products Cold Water Bath 54 25 Dark blue reactant 1. What is the “common ion” that you added to test tubes #2–5? It is copper II chloride (CuCl2 2. How does the common ion affect the equilibrium reaction as the amount of NaCl solution increases from 1–4 mL? The noticeable concentration of the Sodium Chloride (NaCl2) dilutes the copper II chloride. Sodium chloride has a strong effect on copper II chloride. 3. Based upon the color, in which direction does the equilibrium shift? The equilibrium shifted towards the product. 4. Write an equation showing what happens when AgNO 3 is added and explain why the equilibrium shifts. AgNO3 + Cl- → AgCl + NO3- Silver ions in this reaction will react with chloride ions. This will make solid AgCl. The concentration of Cl ions shows a decrease on the right side. This is © 2016 Carolina Biological Supply Company
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because equilibrium shifts right or towards the product side; thus, resulting to production of more Cl- ions. Because of the dissociation of CuCl2, the color of solution changes from light green to light blue. 5. Explain the equilibrium shift that occurs when water is added to the original equilibrium reaction. Cu(H 2 O) 6 2+ (aq) + 4Cl (aq) CuCl 4 2– (aq) + 6H 2 O(l) Blue Green Upon adding H2O to the equilibrium, it shifted away from the side where water acted as a reactant. © 2016 Carolina Biological Supply Company
3 6. Write “heat” on either the left or right side of this equation, based upon observations from the addition and removal of heat in steps 3 and 4, respectively, and the corresponding shifts in equilibrium. _Heat____ + Cu(H 2 O) 6 2+ (aq) + 4Cl (aq) CuCl 4 2– (aq) + 6H 2 O(l) + _____ Blue Green 7. Given the equilibrium equation for a general reaction, A + B C + D, explain what happens to the reactants and products from time 0 until the time at which the reaction reaches equilibrium. In real sense, the solution was changed by the heat. 8. Given this reaction at equilibrium, C(s) + CO 2 (g) 2CO(g) (∆H° = 119kJ), explain the changes that would occur when the following stresses are applied or removed for this reaction. (a) CO is removed. = The concentration of products will decrease; thus, the momentum of the equation drifts to the reactant side. (b)Heat is added. = It will shift the reaction to the right, hence towards the product side. (c) CO 2 is added. = On this occasion, the concentration of the reactants will increase. (d)Heat is removed. = This will however change the equilibrium. It will shift it towards the reactants. Photos Place the tubes on a white paper with adequate light. Use of white paper as a background will assist with view and color comparisons. Color changes may be subtle. Photo 1 Insert the photo of test tubes #1-5 from Activity 1. Be sure you can compare the colors of the solutions in test tubes #2–5 to that in test tube #1. The following should be visible in this photo: Labels of the tubes Colors of the liquids in the tubes © 2016 Carolina Biological Supply Company
3 Photo 2 Insert the photo of test tubes #1 and #3 from Activity 2. The following should be visible in this photo: Label of the tubes Colors of the liquids in the tubes Photo 3 Insert the photo of test tubes #4 and #5 from Activity 3. The following should be visible in this photo: Labels of the tubes Colors of the liquids in the tubes Photo 4 Insert the photo of test tubes #4 and #5 from Activity 4, step 8. The following should be visible in this photo: Labels of the tubes Colors of the liquids in the tubes Photo 5 Insert the photo of test tubes #4 and #5 from Activity 4, step 13. The following should be visible in this photo: Labels of the tubes Colors of the liquids in the tubes © 2016 Carolina Biological Supply Company
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