CHM 101L M5 Equilibrium and LeChatlier Lab Report
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Southern New Hampshire University *
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Course
101L
Subject
Chemistry
Date
Feb 20, 2024
Type
docx
Pages
6
Uploaded by PrivateTeam20609
Equilibrium and Le Chatelier’s Principle
Student Name
Paul S. Nomsule
Date
02/12/2024
Data
Activities 1, 2, and 3
The goal of this lab is to determine the concentration of acetic acid.
Two different vinegar samples, one known and the other unknown, are used to determine the concentration of acetic acid in different types of acetic acid.
Data Table 1
Quantity
of
Reagents
Quantity
of
Reagents
Quantity
of
Reagents
Quantity
of
Reagents
Quantity
of
Reagents
Reagent
Test Tube
#1,
Control
Test Tube
#2
Test Tube
#3
Test Tube
#4
Test Tube
#5
Copper (II) Chlorid
e
2.0 mL
2.0 mL
2.0 mL
2.0 mL
2.0 mL
Sodium Chlorid
e
0.0 mL
1.0 mL
2.0 mL
4.0 mL 4.0 mL Color of
Solution
Bright blue
Dilute blue
Cloudy
white/blue
Faint blue
Diluted
blue
Silver Nitrate
N/A
N/A
1.0 mL
N/A
N/A
Color of
Solution
N/A
N/A
white
N/A
N/A
Water
N/A
N/A
N/A
3.0 mL
N/A
Color of
Solution
N/A
N/A
N/A
blue
N/A
© 2016 Carolina Biological Supply Company
Activity 4
Data Table 2
Stress
Water Bath
Temperatur
e (°C)
Solution
Temperatu
re
(°C)
Solution
Color
Direction of
Shift
(reactants or
products) (
or
)
Test tube #4 (Control Solution)
N/A
25
Light blue
At equilibrium
Hot Water
Bath 68
25
green
products
Cold Water
Bath
54
25
Dark blue
reactant
1.
What is the “common ion” that you added to test tubes #2–5?
It is copper II chloride (CuCl2
2.
How does the common ion affect the equilibrium reaction as the amount of NaCl
solution increases from 1–4 mL?
The noticeable concentration of the Sodium Chloride (NaCl2) dilutes the copper II chloride. Sodium chloride has a strong effect on copper II chloride.
3.
Based upon the color, in which direction does the equilibrium shift? The equilibrium shifted towards the product.
4.
Write an equation showing what happens when AgNO
3
is added and explain why the equilibrium shifts.
AgNO3 + Cl- → AgCl + NO3-
Silver ions in this reaction will react with chloride ions. This will make solid AgCl. The concentration of Cl ions shows a decrease on the right side. This is © 2016 Carolina Biological Supply Company
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because equilibrium shifts right or towards the product side; thus, resulting to production of more Cl- ions. Because of the dissociation of CuCl2, the color
of solution changes from light green to light blue.
5.
Explain the equilibrium shift that occurs when water is added to the original equilibrium reaction.
Cu(H
2
O)
6
2+
(aq) + 4Cl
–
(aq)
CuCl
4
2–
(aq) + 6H
2
O(l)
Blue Green
Upon adding H2O to the equilibrium, it shifted away from the side where water acted as a reactant. © 2016 Carolina Biological Supply Company
3
6.
Write “heat” on either the left or right side of this equation, based upon observations from the addition and removal of heat in steps 3 and 4, respectively, and the corresponding shifts in equilibrium.
_Heat____
+ Cu(H
2
O)
6
2+
(aq) + 4Cl
–
(aq)
CuCl
4
2–
(aq) + 6H
2
O(l) + _____
Blue
Green
7.
Given the equilibrium equation for a general reaction, A + B
C + D, explain what happens to the reactants and products from time 0 until the time at which the reaction reaches equilibrium.
In real sense, the solution was changed by the heat.
8.
Given this reaction at equilibrium, C(s) + CO
2
(g)
2CO(g) (∆H° = 119kJ), explain the changes that would occur when the following stresses are applied or removed for this reaction.
(a) CO is removed. = The concentration of products will decrease; thus, the momentum of the equation drifts to the reactant side. (b)Heat is added. = It will shift the reaction to the right, hence towards the product side.
(c) CO
2
is added. = On this occasion, the concentration of the reactants will increase. (d)Heat is removed. = This will however change the equilibrium. It will shift it towards the reactants. Photos
Place the tubes on a white paper with adequate light. Use of white paper as a background will assist with view and color comparisons. Color changes may
be subtle.
Photo 1
Insert the photo of test tubes #1-5 from Activity 1. Be sure you can compare the colors of the solutions in test tubes #2–5 to that in test tube #1. The following should be visible in this photo:
Labels of the tubes
Colors of the liquids in the tubes
© 2016 Carolina Biological Supply Company
3
Photo 2
Insert the photo of test tubes #1 and #3 from Activity 2. The following should be visible in this photo:
Label of the tubes
Colors of the liquids in the tubes
Photo 3
Insert the photo of test tubes #4 and #5 from Activity 3. The following should be visible in this photo:
Labels of the tubes
Colors of the liquids in the tubes
Photo 4
Insert the photo of test tubes #4 and #5 from Activity 4, step 8.
The following should be visible in this photo:
Labels of the tubes
Colors of the liquids in the tubes
Photo 5
Insert the photo of test tubes #4 and #5 from Activity 4, step 13.
The following should be visible in this photo:
Labels of the tubes
Colors of the liquids in the tubes
© 2016 Carolina Biological Supply Company
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A change in temperature.
An increase in the concentration of an aqueous or gaseous product.
A change in pressure when gaseous reagents are nonexistent.
A change in pressure when gases are present in differing mole amounts on each side of the equation.
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B) A change in temperature.
C) An increase in the concentration of an aqueous or gaseous product.
D) A decrease in the concentration of an aqueous or gaseous reactant.
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I
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True
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decrease the amount of product
increase the amount of reactants
shift the equilibrium to the left
all of the above
none of the above
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N2 + 3H2 <--> 2NH3
a.
cause an increase in the concentration of N2
b.
have no effect on reactants or products
c.
cause an increase in the concentration of H2
d.
cause an increase in the concentration of NH3
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H PAP Cheistry-29 X
PAP Chemistry-29 X
G diagram showing x
b ar-2903012.agilixbuzz.com/student/135113422/activity/c412d902
Mastery Assess It 8
PAP Chemistry-2903012-42100P-1/ Le Chatelier's Principle /Lesson 128
1. Which of the following would not add stress to an equilibrium reaction shown below?
A+B+C+D
increasing the pressure
removing product C
changing the order of reactants A and B
adding reactant A
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A.
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B.
Addition of an appropriately designed, and chosen, catalyst
C.
Fluctuation in reaction pressure
D.
Increase in the initial concentration of the chemical reagents
E.
Increase in reaction temperature
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increases as temperature decreases
decreases when a catalyst is added
increases as reactant concentration increases
decreases as reactant concentration increases
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Le Chatelier's Principles
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N2(g) + 3H2(g) ↔2NH3(g) + 22.0 kcal
Stress
Equilibrium Shift
[N2]
[H2]
[NH3]
K
Add N2
Add H2
Add NH3
Remove N2
Remove H2
Remove NH3
Increase Temperature
Decrease Temperature
Increase Pressure
Decrease Pressure
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H3N.
OH
OH
+ OH
O left
+ Nha
O left
+ H₂O
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+ CH3O
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CI
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HO
right O
H₂N.
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right ►
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2.
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Group of answer choices
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the concentrations of the reactants and products have become equal.
Reactants are used up.
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Le Châtelier Principle
Learning Goal:
To use the equilibrium constant and Le Châtelier's
principle to determine how a reaction will respond
to external factors.
A reaction is at equilibrium when the concentrations
of the reactants and products no longer change
over time. This does not mean the reaction is over,
rather, two competing reactions continue to occur
simultaneously at equal rates. The two competing
reactions are the forward reaction (reactants →
products) and the reverse reaction (products →
reactants).
If a reaction at equilibrium is subjected to a stress,
the concentrations of reactants and products adjust
to reestablish equilibrium. This is called Le
Châtelier's principle. A stress might be a change in
the concentration of reactants or products, a
change in the volume of the reaction container, a
change in temperature, or the addition of a catalyst.
0 O
▾
Part A
Given the concentrations, calculate the equilibrium constant for this
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BI U
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Times New..
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1
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| 3 4 5 |
6
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refer to the following exothermic reaction at equilibrium.
6 P205 + 16 KCl + 9 SO2
3 P4S3 + 16 KC103 + heat
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Not at equilibrium
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Answer Bank
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The concentrations of products and reactants are constant.
The forward reaction is occurring at a very slow rate.
The concentration of reactants is slowly increasing.
The forward and reverse reactions occur at equal rates.
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