inorganic chem
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Feb 20, 2024
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1.
Write of the ground electron configuration for the following molecules:
A)
࠵?
7
B)
࠵?࠵?
13
C)
࠵?࠵?
11
D)
࠵?࠵?
38
E)
࠵?
8
F)
࠵?࠵?
26
G)
࠵?࠵?
35
H)
࠵?࠵?
56
I)
࠵?࠵?
17
1252p3
S
=
2
P
=
6
T
He]25
2p3
d
=
10
f
=
14
152922033923p
[Ne]353p)
12522P335
[Ne]39'
152522043523064523d'4p6592
[Kr]SS2
1525204
T
He]25"2PY
15252p63523464534
[Ar]45
3d
152252p6352386453d'0
yp
SAr]
4923d104pS
152522833523864923d"4095524dSp3652
[Ne]6S2
15252043534
[Ney
35
"3pS
2. Write of the ground electron configuration for the following molecules:
A)
࠵?࠵?
18
B)
࠵?࠵?
29
C)
࠵?࠵?
21
D)
࠵?
3+
E)
࠵?࠵?
2+
F)
࠵?࠵?
6+
G)
࠵?࠵?
3+
H)
࠵?࠵?
83
3) How many orbitals are in a shell of principle quantum number n? Start from n=1 and see if
you find a pattern
4. Complete the following table:
n
l
ml
Orbital
designation
# of orbitals
2
2p
3
2
4s
4
-3,-2,-1,0,1,2,3
5. Which of the following is a correct set of quantum numbers for an electron in 4d?
A) n=4, l=0, ml= -1, ms=
−
1
2
B) n=4, l=1, ml= +3 , ms=
−
1
2
C) n=4, l=3, ml= 4, ms=
+
1
2
D) n=4, l=3, ml= +2, ms=
−
1
2
E) n=4, l=2, ml= -2, ms=
−
1
2
6. Which of the following sets of quantum numbers can correctly represent a 3p orbital?
A) n=3 , l=1, ml=2
B) n=3, l=3, ml=3
C) n=3, l=0, ml=1
D) n=3, l=1, ml=-1
E) n=3, l=0, ml=0
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7. Write the ground state electron configurations for:
A)
࠵?࠵?
25
B)
࠵?࠵?
29
C)
࠵?࠵?
14
8. Write the full electron configuration of a period 3 element with the following successive
ionization energies (kj/mol)
I1= 638, I2= 1250, I3=8732, and I4= 10,300
9. The first five ionization energies for a third-period element are shown below:
I1
578
I2
1817
I3
2745
I4
11578
I5
14842
What is the identity of the element?
10. What does the principle quantum number (n) describe?
11. What does the angular moment quantum number (l) describe?
12. What does the magnetic quantum number (ml) describe?
13. Label the following with their quantum number designation:
2࠵?࠵?
2=
p=
x=
14. All ____ _____ are spherical in shape but differ in size
15. How many orientations does a p orbital have?
16. How many orientations does a d orbital have?
17. How many electrons do the s, p, d, and f orbitals hold?
18. Write the electron configuration of calcium z=20
19. Give the electron configuration of potassium z=19 first in long handwriting and then in the
shortcut method.
Long-hand electron configuration:
Shortcut electron configuration:
20. Write the electronic configuration of chromium z=24 and copper z=29. Are these
exceptions? Please explain why.
21. What is the unit for the atomic radius?
22. What is the first ionization energy?
23. Please define electronegativity:
24. Ionization energy _______ as you move to higher number groups. Ionization energy ____
as you move down the periodic table.
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25. Solve for the packing efficiency of a simple cubic structure:
26. Solve for the packing efficiency for a body-centered cubic
27. Solve for the packing efficiency of a face centered cubic
28. The edge length of the unit cell of Ta is 330.6pm; the unit cell is a body-centered cubic.
Tantalum has a density of 16.69
࠵?
࠵?࠵?
3
A) Calculate the mass of the tantalum atom in grams.
B) Calculate the atomic weight in g/mol.
29. Chromium crystalyzes in a body-centered cubic structure the unit cell volume is
2.582
Determine the atomic radius od the Cr in pm.
࠵? 10
−23 ࠵?࠵?
3
30. Chromium crystallizes in a body-centered cubic unit cell. The radius of the chromium atom is
128pm. Calculate the density of solid crystalline chromium in grams per cubic meter. MW:
51.99g/mol
31. Barium has a radius of 224 pm and crystalizes body-centered cubic structure. What is the
edge length of the unit cell?
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32. Metallic potassium has a body-centered cubic structure. If the edge length of the unit cell is
533p, calculate the radius of the potassium atom.
33. Sodium has a density of 0.971
and crystalizes with a body-centered cubic unit cell. MW:
࠵?
࠵?࠵?
3
22.99g/mol
A) What is the radius of a sodium atom?
B) What is the edge length of the cell?
a
=
533Pm
od
as
en
a
=
7t
633
=
n
=
>
=
23
A)
a
=
n
=
4
.
28x10
-
%CM
=
-
N
=)
N
=
1
85
X10 -
8
od
att
d
=
0
97
s
e
d
=
m
B)
Natom
=
0
.
971
=
Latoms
(22
9991mol)
x
(Gx1023
atoms)
Ucell
a
&
=
Latoms
(22
9941mol)
(6x1023
atoys)
/
0
.
971
cm
i
3
·
a
X10-23
=
4
.
28 x10
-
8 Cm
=
34. Atomic packing factor (APF) is atom volume per cell volume. The APF for body-centered
cubic (bcc) system is 0.68. Show step-wise, the calculation that leads to the APF value for the
bcc structure.
35. The cubic unit cell volume for europium is 1.26
and its molar mass and density
࠵? 10
−22
࠵?࠵?
3
are 181.96
, respectively, determining a) the number of europium atoms in the unit cell and
࠵?/࠵?࠵?
3
b)The radius of europium atoms and
36. Calcium has a cubic closed-packed structure as a solid. Assuming that calcium has an
atomic radius of 197pm, calculate the density of solid calcium. Calcium MW: 40.08g/mol
37. Nickel has a face-centered cubic unit cell. The density of nickel is 6.84g/cm^3. Calculate the
radius of nickel. MW: 58.69g/mol
38. A certain lead form has a cubic closest packed structure with an edge length of 492pm.
Calculate the value of the atomic radius and the density of lead. Molecular weight:207.2g/mol
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39. The density of polonium metal is 9.2g/cm^3. If the extended lattice of polonium exhibits a
simple cubic unit cell, estimate the atomic radius of polonium. Molecular weight:208.98g/mol
40. How many atoms does a simple cubic unit cell have?
41. How many atoms does a body-centered cubic unit cell have?
42. How many atoms does a face-centered cubic unit cell have?
43. What is the equation for simple cubic? a=?
44. What is the equation for bcc? a=?
45. What is the equation for fcc? a=?
46. What is the packing factor equation?
47. Define constructive interference and destructive interference
48. What does the dual nature of particles mean?
49. There are two types of dense packing. Please label what they are and draw what they look
like.
50. Please define crystal lattice
51. Please draw and define AB and AB2 type lattices
52. Please fill in the table
Solid type
Solid
Coordination
AB
NaCl
6:6
CsCl
ZnS
NiAs
CaF2
Li2O2
TiO2
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P
یے
||
=
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m
m
m
m
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ms
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Here's an example of an energy level diagram
Energy
Photon
E5 (n=5)
E4 (n=4)
E3 (n=3)
E2 (n=2)
E1 (n=1)
How many possible electronic transitions are possible
from the ground state (E1) into any excited state?
02
O 3
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05
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1. II. II.
IV.
V.
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||
IV
O v
V
O II
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solve this
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Is2s²2p³
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