inorganic chem

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Chemistry

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Feb 20, 2024

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1. Write of the ground electron configuration for the following molecules: A) ࠵? 7 B) ࠵?࠵? 13 C) ࠵?࠵? 11 D) ࠵?࠵? 38 E) ࠵? 8 F) ࠵?࠵? 26 G) ࠵?࠵? 35 H) ࠵?࠵? 56 I) ࠵?࠵? 17 1252p3 S = 2 P = 6 T He]25 2p3 d = 10 f = 14 152922033923p [Ne]353p) 12522P335 [Ne]39' 152522043523064523d'4p6592 [Kr]SS2 1525204 T He]25"2PY 15252p63523464534 [Ar]45 3d 152252p6352386453d'0 yp SAr] 4923d104pS 152522833523864923d"4095524dSp3652 [Ne]6S2 15252043534 [Ney 35 "3pS
2. Write of the ground electron configuration for the following molecules: A) ࠵?࠵? 18 B) ࠵?࠵? 29 C) ࠵?࠵? 21 D) ࠵? 3+ E) ࠵?࠵? 2+ F) ࠵?࠵? 6+ G) ࠵?࠵? 3+ H) ࠵?࠵? 83
3) How many orbitals are in a shell of principle quantum number n? Start from n=1 and see if you find a pattern 4. Complete the following table: n l ml Orbital designation # of orbitals 2 2p 3 2 4s 4 -3,-2,-1,0,1,2,3 5. Which of the following is a correct set of quantum numbers for an electron in 4d? A) n=4, l=0, ml= -1, ms= 1 2 B) n=4, l=1, ml= +3 , ms= 1 2 C) n=4, l=3, ml= 4, ms= + 1 2 D) n=4, l=3, ml= +2, ms= 1 2 E) n=4, l=2, ml= -2, ms= 1 2 6. Which of the following sets of quantum numbers can correctly represent a 3p orbital? A) n=3 , l=1, ml=2 B) n=3, l=3, ml=3 C) n=3, l=0, ml=1 D) n=3, l=1, ml=-1 E) n=3, l=0, ml=0
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7. Write the ground state electron configurations for: A) ࠵?࠵? 25 B) ࠵?࠵? 29 C) ࠵?࠵? 14 8. Write the full electron configuration of a period 3 element with the following successive ionization energies (kj/mol) I1= 638, I2= 1250, I3=8732, and I4= 10,300 9. The first five ionization energies for a third-period element are shown below: I1 578 I2 1817 I3 2745 I4 11578 I5 14842 What is the identity of the element?
10. What does the principle quantum number (n) describe? 11. What does the angular moment quantum number (l) describe? 12. What does the magnetic quantum number (ml) describe? 13. Label the following with their quantum number designation: 2࠵?࠵? 2= p= x= 14. All ____ _____ are spherical in shape but differ in size 15. How many orientations does a p orbital have? 16. How many orientations does a d orbital have? 17. How many electrons do the s, p, d, and f orbitals hold? 18. Write the electron configuration of calcium z=20
19. Give the electron configuration of potassium z=19 first in long handwriting and then in the shortcut method. Long-hand electron configuration: Shortcut electron configuration: 20. Write the electronic configuration of chromium z=24 and copper z=29. Are these exceptions? Please explain why. 21. What is the unit for the atomic radius? 22. What is the first ionization energy? 23. Please define electronegativity: 24. Ionization energy _______ as you move to higher number groups. Ionization energy ____ as you move down the periodic table.
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25. Solve for the packing efficiency of a simple cubic structure: 26. Solve for the packing efficiency for a body-centered cubic 27. Solve for the packing efficiency of a face centered cubic
28. The edge length of the unit cell of Ta is 330.6pm; the unit cell is a body-centered cubic. Tantalum has a density of 16.69 ࠵? ࠵?࠵? 3 A) Calculate the mass of the tantalum atom in grams. B) Calculate the atomic weight in g/mol. 29. Chromium crystalyzes in a body-centered cubic structure the unit cell volume is 2.582 Determine the atomic radius od the Cr in pm. ࠵? 10 −23 ࠵?࠵? 3
30. Chromium crystallizes in a body-centered cubic unit cell. The radius of the chromium atom is 128pm. Calculate the density of solid crystalline chromium in grams per cubic meter. MW: 51.99g/mol 31. Barium has a radius of 224 pm and crystalizes body-centered cubic structure. What is the edge length of the unit cell?
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32. Metallic potassium has a body-centered cubic structure. If the edge length of the unit cell is 533p, calculate the radius of the potassium atom. 33. Sodium has a density of 0.971 and crystalizes with a body-centered cubic unit cell. MW: ࠵? ࠵?࠵? 3 22.99g/mol A) What is the radius of a sodium atom? B) What is the edge length of the cell? a = 533Pm od as en a = 7t 633 = n = > = 23 A) a = n = 4 . 28x10 - %CM = - N =) N = 1 85 X10 - 8 od att d = 0 97 s e d = m B) Natom = 0 . 971 = Latoms (22 9991mol) x (Gx1023 atoms) Ucell a & = Latoms (22 9941mol) (6x1023 atoys) / 0 . 971 cm i 3 · a X10-23 = 4 . 28 x10 - 8 Cm =
34. Atomic packing factor (APF) is atom volume per cell volume. The APF for body-centered cubic (bcc) system is 0.68. Show step-wise, the calculation that leads to the APF value for the bcc structure. 35. The cubic unit cell volume for europium is 1.26 and its molar mass and density ࠵? 10 −22 ࠵?࠵? 3 are 181.96 , respectively, determining a) the number of europium atoms in the unit cell and ࠵?/࠵?࠵? 3 b)The radius of europium atoms and
36. Calcium has a cubic closed-packed structure as a solid. Assuming that calcium has an atomic radius of 197pm, calculate the density of solid calcium. Calcium MW: 40.08g/mol 37. Nickel has a face-centered cubic unit cell. The density of nickel is 6.84g/cm^3. Calculate the radius of nickel. MW: 58.69g/mol 38. A certain lead form has a cubic closest packed structure with an edge length of 492pm. Calculate the value of the atomic radius and the density of lead. Molecular weight:207.2g/mol
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39. The density of polonium metal is 9.2g/cm^3. If the extended lattice of polonium exhibits a simple cubic unit cell, estimate the atomic radius of polonium. Molecular weight:208.98g/mol 40. How many atoms does a simple cubic unit cell have? 41. How many atoms does a body-centered cubic unit cell have? 42. How many atoms does a face-centered cubic unit cell have? 43. What is the equation for simple cubic? a=? 44. What is the equation for bcc? a=? 45. What is the equation for fcc? a=? 46. What is the packing factor equation?
47. Define constructive interference and destructive interference 48. What does the dual nature of particles mean? 49. There are two types of dense packing. Please label what they are and draw what they look like. 50. Please define crystal lattice 51. Please draw and define AB and AB2 type lattices
52. Please fill in the table Solid type Solid Coordination AB NaCl 6:6 CsCl ZnS NiAs CaF2 Li2O2 TiO2
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