Integrated Rate Law practices

CM1131 Tutorial 9 AY 18/19 Question 4 (4a will be covered in week 12) a) At the appropriate condition, the reactant A undergoes three parallel reactions, where P 1 , P 2 and P 3 are the products: The rate constants at 22 °C are k 1 = 7.0 10 ‒ 4 s ‒ 1 , k 2 = 4.1 10 ‒ 3 s ‒ 1 and k 3 = 5.7 10 ‒ 3 s ‒ 1 . What × × × is the percent yield for P 1 formation? b) The interconversion of the “chair” and “boat” conformation of cyclohexane is shown below. The reaction is first order in each direction. The rate constants in a given solvent at 25 °C are k 1 = 2.75 10 4 s ‒ 1 and k − 1 = 4.34 10 8 s ‒ 1 . What is the equilibrium constant at 25 °C? × × CM1131 Tutorial 9Page 2