Mastering Chemistry with Pearson eText ...4th EditionNivaldo J. Tro Publisher: PEARSONISBN: 9780134162485
Mastering Chemistry with Pearson eText ...
Solutions for Mastering Chemistry with Pearson eText -- Standalone Access Card -- for Chemistry: A Molecular Approach (4th Edition)
Problem 2SAQ:
Q2. Which set of elements is arranged in order of increasing electronegativity?
a) O < S < As <...Problem 5E:
5. Describe the octet rule in the Lewis model.
Problem 7E:
7. How do you draw an ionic Lewis structure?
Problem 8E:
8. How can Lewis structures be used to determine the formula of ionic compounds? Give an example.
Problem 15E:
15. In a covalent Lewis structure, what is the difference between lone pair and bonding pair...Problem 17E:
17. How does the Lewis model for covalent bonding account for why certain combinations of atoms are...Problem 18E:
18. How does the Lewis model for covalent bonding account for the relatively low melting and boiling...Problem 22E:
22. What is a dipole moment?
Problem 27E:
27. Do resonance structures always contribute equally to the overall structure of a molecule?...Problem 29E:
29. Why does the octet rule have exceptions? List the three major categories of exceptions and an...Problem 30E:
30. Which elements can have expanded octets? Which elements should never have expanded octets?
Problem 35E:
35. Write the electron configuration for N. Then write the Lewis symbol for N and show which...Problem 36E:
36. Write the electron configuration for Ne. Then write the Lewis symbol for Ne and show which...Problem 39E:
39. Write the Lewis symbols for the ions in each ionic compound.
a. NaF
b. CaO
c. SrBr2
d. K2O
Problem 40E:
40. Write the Lewis symbols for the ions in each ionic compound.
a. SrO
b. Li2S
c. CaI2
d. RbF
Problem 41E:
41. Use Lewis symbols to determine the formula for the compound that forms between each pair of...Problem 42E:
42. Use Lewis symbols to determine the formula for the compound that forms between each pair of...Problem 43E:
43. Explain the trend in the lattice energies of the alkaline earth metal oxides.
Metal...Problem 44E:
44. Rubidium iodide has a lattice energy of –617 kJ/mol, while potassium bromide has a lattice...Problem 45E:
45. The lattice energy of CsF is –744 kJ/mol, whereas that of BaO is –3029 kJ/mol. Explain this...Problem 46E:
46. Arrange these compounds in order of increasing magnitude of lattice energy: KCl, SrO, RbBr,...Problem 47E:
47. Use the Born–Haber cycle and data from Appendix IIB, Chapter 8 and this chapter to calculate the...Problem 48E:
48. Use the Born–Haber cycle and data from Appendix IIB and Table 9.3 to calculate the lattice...Problem 49E:
49. Use covalent Lewis structures to explain why each element (or family of elements) occurs as...Problem 50E:
50. Use covalent Lewis structures to explain why the compound that forms between nitrogen and...Problem 53E:
53. Write the Lewis structure for each molecule.
a. SF2
b. SiH4
c. HCOOH (both O bonded to C)
d....Problem 54E:
54. Write the Lewis structure for each molecule.
a. CH2O
b. C2Cl4
c. CH3NH2
d. CFCl3 (C central)
Problem 55E:
55. Determine if a bond between each pair of atoms would be pure covalent, polar covalent, or...Problem 56E:
56. Determine if a bond between each pair of atoms would be pure covalent, polar covalent, or...Problem 57E:
57. Draw the Lewis structure for CO with an arrow representing the dipole moment. Refer to Figure...Problem 58E:
58. Draw the Lewis structure for BrF with an arrow representing the dipole moment. Refer to Figure...Problem 60E:
60. Write the Lewis structure for each molecule or ion.
a. H3COH
b. OH–
c. BrO–
d. O22–
Problem 61E:
61. Write the Lewis structure for each molecule or ion.
a. N2H2
b. N2H4
c. C2H2
d. C2H4
Problem 62E:
62. Write the Lewis structure for each molecule or ion.
a. H3COCH3
b. CN–
c. NO2–
d. ClO–
Problem 63E:
63. Write a Lewis structure that obeys the octet rule for each molecule or ion. Include resonance...Problem 64E:
64. Write a Lewis structure that obeys the octet rule for each ion. Include resonance structures if...Problem 67E:
67. How important is the resonance structure shown here to the overall structure of carbon dioxide?...Problem 68E:
68. In N2O, nitrogen is the central atom and the oxygen atom is terminal. In OF2, however, oxygen is...Problem 69E:
69. Draw the Lewis structure (including resonance structures) for the acetate ion (CH3COO–). For...Problem 70E:
70. Draw the Lewis structure (including resonance structures) for methyl azide (CH3N3). For each...Problem 73E:
73. Write the Lewis structure for each molecule (octet rule not followed).
a. BCl3
b. NO2
c. BH3
Problem 74E:
74. Write the Lewis structure for each molecule (octet rule not followed).
a. BBr3
b. NO
c. ClO2
Problem 75E:
75. Write the Lewis structure for each ion. Include resonance structures if necessary and assign...Problem 76E:
76. Write Lewis structures for each molecule or ion. Include resonance structures if necessary and...Problem 77E:
77. Write Lewis structures for each molecule or ion. Use expanded octets as necessary.
a. PF5
b....Problem 78E:
78. Write Lewis structures for each molecule or ion. Use expanded octets as necessary.
a. ClF5
b....Problem 79E:
79. Order these compounds in order of increasing carbon–carbon bond strength and in order of...Problem 80E:
80. Which compound shown here has the stronger nitrogen–nitrogen bond? The shorter nitrogen–nitrogen...Problem 81E:
81. Hydrogenation reactions are used to add hydrogen across double bonds in hydrocarbons and other...Problem 82E:
82. Ethanol is a possible fuel. Use average bond energies to calculate ΔHrxn for the combustion of...Problem 83E:
83. Hydrogen, a potential future fuel, can be produced from carbon (from coal) and steam by this...Problem 85E:
85. Write an appropriate Lewis structure for each compound. Make certain to distinguish between...Problem 86E:
86. Write an appropriate Lewis structure for each compound. Make certain to distinguish between...Problem 87E:
87. Each compound contains both ionic and covalent bonds. Write ionic Lewis structures for each of...Problem 88E:
88. Each compound contains both ionic and covalent bonds. Write ionic Lewis structures for each of...Problem 89E:
89. Carbon ring structures are common in organic chemistry. Draw a Lewis structure for each carbon...Problem 90E:
90. Amino acids are the building blocks of proteins. The simplest amino acid is glycine...Problem 91E:
91. Formic acid is responsible for the sting of ant bites. By mass, formic acid is 26.10% C, 4.38%...Problem 92E:
92. Diazomethane is a highly poisonous, explosive compound because it readily evolves N2....Problem 93E:
93. The reaction of Fe2O3(s) with Al(s) to form Al2O3(s) and Fe(s) is called the thermite reaction...Problem 94E:
94. NaCl has a lattice energy of –787 kJ/mol. Consider a hypothetical salt XY. X3+ has the same...Problem 95E:
95. Draw the Lewis structure for nitric acid (the hydrogen atom is attached to one of the oxygen...Problem 96E:
96. Phosgene (Cl2CO) is a poisonous gas used as a chemical weapon during World War I. It is a...Problem 97E:
97. The cyanate ion (OCN–) and the fulminate ion (CNO–) share the same three atoms but have vastly...Problem 101E:
101. Draw the Lewis structure for HCSNH2. (The carbon and nitrogen atoms are bonded together, and...Problem 102E:
102. Draw the Lewis structure for urea, H2NCONH2, one of the compounds responsible for the smell of...Problem 103E:
103. Some theories of aging suggest that free radicals cause certain diseases and perhaps aging in...Problem 104E:
104. Free radicals are important in many environmentally significant reactions (see the Chemistry in...Problem 106E:
106. Calculate ΔHrxn for the combustion of octane (C8H18), a component of gasoline, by using average...Problem 107E:
107. Draw the Lewis structure for each compound.
a. Cl2O7 (no Cl—Cl bond)
b. H3PO3 (two OH bonds)
c....Problem 110E:
110. Calculate for the reaction using the bond energy values. The of is not equal to one-half of...Problem 113E:
113. A compound composed of only carbon and hydrogen is 7.743% hydrogen by mass. Propose a Lewis...Problem 115E:
115. The main component of acid rain (H2SO4) forms from SO2 pollutant in the atmosphere via these...Problem 116E:
116. A 0.167-g sample of an unknown acid requires 27.8 mL of 0.100 M NaOH to titrate to the...Problem 120E:
120. The standard heat of formation of CaBr2 is –675 kJ/mol. The first ionization energy of Ca is...Problem 126E:
126. Which statement is true of an endothermic reaction?
a. Strong bonds break and weak bonds...Browse All Chapters of This Textbook
Chapter 1 - Matter, Measurement, And Problem SolvingChapter 2 - Atoms And ElementsChapter 3 - Molecules, Compounds, And Chemical EquationsChapter 4 - Chemical Quantities And Aqueous ReactionsChapter 5 - GasesChapter 6 - ThermochemistryChapter 7 - The Quantum-Mechanical Model Of The AtomChapter 8 - Periodic Properties Of The ElementsChapter 9 - Chemical Bonding I: The Lewis ModelChapter 10 - Chemical Bonding II: Molecular Shapes, Valence Bond Theory, And Molecular Orbital Theory
Chapter 11 - Liquids, Solids, And Intermolecular ForcesChapter 12 - Solids And Modern MaterialsChapter 13 - SolutionsChapter 14 - Chemical KineticsChapter 15 - Chemical EquilibriumChapter 16 - Acids And BasesChapter 17 - Aqueous Ionic EquilibriumChapter 18 - Free Energy And ThermodynamicsChapter 19 - ElectrochemistryChapter 20 - Radioactivity And Nuclear ChemistryChapter 21 - Organic ChemistryChapter 22 - BiochemistryChapter 23 - Chemistry Of The NonmentalsChapter 24 - Metals And MetallurgyChapter 25 - Transition Metals And Coordination Compounds
Sample Solutions for this Textbook
We offer sample solutions for Mastering Chemistry with Pearson eText -- Standalone Access Card -- for Chemistry: A Molecular Approach (4th Edition) homework problems. See examples below:
Chapter 1, Problem 1SAQChapter 2, Problem 1SAQChapter 3, Problem 1SAQExplanation: Molar mass of MnO2= 55 + 2 × 16 = 55 + 32 = 87 Number of moles of MnO2= 25.087 = 0.287...Given: Initial pressure, P1 = 547 mmHg Initial volume, V1 = 0.500 L Final volume, V2 = 225 mL =...Chapter 6, Problem 1SAQChapter 7, Problem 1SAQJustify reasons for the correct statement: Coulomb’s law states that the potential energy (E) of two...Explanation: Ionic bond is formed between a positive ion and a negative ion. Positive ion results...
Reason for correct option: Lewis structure of CBr4: CBr4 Has 25 valence electrons. The central atom...The molecules of gases are not rigid. They have large space between them, more as compared to...Justify reasons for the correct answer: Calculate the separation between the atomic layers in the...Justify reasons for the correct statement: Octane is a nonpolar solvent. A compound or solute that...Justify reasons for the correct statement: The average rate of the reaction is written as follows:...Justify reasons for correct statement: The given reaction is as follows: C(s)+2H2(g)⇌CH4(g) Here,...Justification for the correct option: When an acid donates its hydrogen ion, a conjugate base is...In the given buffer of 0.100 M in NH4Cl and 0.100 M in NH3, NH3 is weak base and NH4Cl is a...The phase transition is from solid to gas during the chemical reaction, so entropy increases and...The equation for this reaction as follows: VO2+(aq)+Sn(s)+H+(aq)→VO2+(aq)+Sn2+(aq)+H2O(l) Separate...The original atom is called parent nuclide, and the product of the decay is called the daughter...Justification for the correct statement: Carbon has a valency of 4. So, carbon can form covalent...The lipids are a diverse group of naturally occurring organic compounds and chemical components of...Justify reasons for the correct statement: The AlO2− units substitute for three-fourths of SiO2;...Justify reason for correct statement: Gold occurs in elemental state with some small particles and...When we write the electron configuration of Cu+ ion using the periodic table, we see that argon is...
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