Solutions for Mastering Chemistry with Pearson eText -- Standalone Access Card -- for Chemistry: A Molecular Approach (4th Edition)
Problem 2SAQ:
Q2. Which electron in sulfur is most shielded from nuclear charge?
a) an electron in the 1s...Problem 13SAQ:
Q13. The ionization energies of an unknown third-period element are listed here. Identify the...Problem 15SAQ:
Q15. For which element is the gaining of an electron most exothermic?
a) Li
b) N
c) F
d) B
Problem 1E:
1. What are periodic properties?
Problem 4E:
4. Who is credited with arranging the periodic table? How are the elements arranged in the modern...Problem 10E:
10. What is penetration? How does the penetration of an orbital into the region occupied by core...Problem 11E:
11. Why are the sublevels within a principal level split into different energies for multielectron...Problem 12E:
12. What is an orbital diagram? Provide an example.
Problem 21E:
21. Describe the relationship between an element’s row number in the periodic table and the highest...Problem 22E:
22. Which of the transition elements in the first transition series have anomalous electron...Problem 23E:
23. Describe how to write the electron configuration for an element based on its position in the...Problem 33E:
33. What is ionization energy? What is the difference between first ionization energy and second...Problem 34E:
34. What is the general trend in the first ionization energy as you move down a column in the...Problem 35E:
35. What are the exceptions to the periodic trends in the first ionization energy? Why do they...Problem 39E:
39. Write a general equation for the reaction of an alkali metal with each substance.
a. a...Problem 45E:
45. Use the periodic table to write an electron configuration for each element. Represent core...Problem 46E:
46. Use the periodic table to determine the element corresponding to each electron configuration.
Problem 47E:
47. Use the periodic table to determine each quantity.
a. The number of 2s electrons in Li.
b. The...Problem 48E:
48. Use the periodic table to determine each quantity.
a. The number of 3s electrons in Mg
b. The...Problem 49E:
49. Name an element in the fourth period (row) of the periodic table with the following:
a. Five...Problem 50E:
50. Name an element in the third period (row) of the periodic table with the following:
a. Three...Problem 51E:
51. Determine the number of valence electrons in an atom of each element.
a. Ba b. Cs c. Ni d. S
Problem 53E:
53. Which outer electron configuration would you expect to belong to a reactive metal? To a reactive...Problem 55E:
55. According to Coulomb’s law, which pair of charged particles has the lowest potential energy?
a....Problem 56E:
56. According to Coulomb’s law, rank the interactions between charged particles from lowest...Problem 57E:
57. Which of the following will experience a greater effective nuclear charge: the valence electrons...Problem 58E:
58. Arrange the atoms according to decreasing effective nuclear charge experienced by their valence...Problem 59E:
59. If core electrons completely shielded valence electrons from nuclear charge (i.e., if each core...Problem 67E:
67. Write orbital diagrams for each ion and indicate whether the ion is diamagnetic or...Problem 73E:
73. Choose the element with the higher first ionization energy from each pair.
a. Br or Bi b. Na or...Problem 77E:
77. For each element, predict where the “jump” occurs for successive ionization energies. (For...Problem 78E:
78. Consider this set of ionization energies.
To which third-period element do these ionization...Problem 79E:
79. Choose the element with the more negative (more exothermic) electron affinity from each pair:
a....Problem 81E:
81. Choose the more metallic element from each pair.
a. Sr or Sb b. As or Bi c. Cl or O d. S or As
Problem 83E:
83. Arrange these elements in order of increasing metallic character: Fr, Sb, In, S, Ba, Se.
Problem 99E:
99. Consider these elements: N, Mg, O, F, and Al.
a. Write the electron configuration for each...Problem 106E:
106. The electron affinity of each group 5A element is more positive than that of each corresponding...Problem 107E:
107. The elements with atomic numbers 35 and 53 have similar chemical properties. Based on their...Problem 112E:
112. The first ionization energy of sodium is 496 kJ/mol. Use Coulomb’s law to estimate the average...Problem 113E:
113. Consider the elements: B, C, N, O, F.
a. Which element has the highest first ionization...Problem 115E:
115. Consider the densities and atomic radii of the noble gases at 25 °C:
Element Atomic Radius...Problem 116E:
116. As you have seen, the periodic table is a result of empirical observation (i.e., the periodic...Problem 117E:
117. Consider the metals in the first transition series. Use periodic trends to predict a trend in...Problem 118E:
118. Imagine a universe in which the value of ms can be +, 0, and –. Assuming that all the other...Problem 123E:
123. Unlike the elements in groups 1A and 2A, those in group 3A do not show a regular decrease in...Problem 124E:
124. Using the data in Figures 8.15 and 8.16, calculate ΔE for the reaction Na(g) + Cl(g) → Na+(g) +...Problem 125E:
125. Even though adding two electrons to O or S forms an ion with a noble gas electron...Problem 127E:
127. The heaviest known alkaline earth metal is radium, atomic number 88. Find the atomic numbers of...Problem 131E:
131. Imagine that in another universe atoms and elements are identical to ours, except that atoms...Problem 132E:
132. The outermost valence electron in atom A experiences an effective nuclear charge of 2+ and is...Browse All Chapters of This Textbook
Chapter 1 - Matter, Measurement, And Problem SolvingChapter 2 - Atoms And ElementsChapter 3 - Molecules, Compounds, And Chemical EquationsChapter 4 - Chemical Quantities And Aqueous ReactionsChapter 5 - GasesChapter 6 - ThermochemistryChapter 7 - The Quantum-Mechanical Model Of The AtomChapter 8 - Periodic Properties Of The ElementsChapter 9 - Chemical Bonding I: The Lewis ModelChapter 10 - Chemical Bonding II: Molecular Shapes, Valence Bond Theory, And Molecular Orbital Theory
Chapter 11 - Liquids, Solids, And Intermolecular ForcesChapter 12 - Solids And Modern MaterialsChapter 13 - SolutionsChapter 14 - Chemical KineticsChapter 15 - Chemical EquilibriumChapter 16 - Acids And BasesChapter 17 - Aqueous Ionic EquilibriumChapter 18 - Free Energy And ThermodynamicsChapter 19 - ElectrochemistryChapter 20 - Radioactivity And Nuclear ChemistryChapter 21 - Organic ChemistryChapter 22 - BiochemistryChapter 23 - Chemistry Of The NonmentalsChapter 24 - Metals And MetallurgyChapter 25 - Transition Metals And Coordination Compounds
Sample Solutions for this Textbook
We offer sample solutions for Mastering Chemistry with Pearson eText -- Standalone Access Card -- for Chemistry: A Molecular Approach (4th Edition) homework problems. See examples below:
Chapter 1, Problem 1SAQChapter 2, Problem 1SAQChapter 3, Problem 1SAQExplanation: Molar mass of MnO2= 55 + 2 × 16 = 55 + 32 = 87 Number of moles of MnO2= 25.087 = 0.287...Given: Initial pressure, P1 = 547 mmHg Initial volume, V1 = 0.500 L Final volume, V2 = 225 mL =...Chapter 6, Problem 1SAQChapter 7, Problem 1SAQJustify reasons for the correct statement: Coulomb’s law states that the potential energy (E) of two...Explanation: Ionic bond is formed between a positive ion and a negative ion. Positive ion results...
Reason for correct option: Lewis structure of CBr4: CBr4 Has 25 valence electrons. The central atom...The molecules of gases are not rigid. They have large space between them, more as compared to...Justify reasons for the correct answer: Calculate the separation between the atomic layers in the...Justify reasons for the correct statement: Octane is a nonpolar solvent. A compound or solute that...Justify reasons for the correct statement: The average rate of the reaction is written as follows:...Justify reasons for correct statement: The given reaction is as follows: C(s)+2H2(g)⇌CH4(g) Here,...Justification for the correct option: When an acid donates its hydrogen ion, a conjugate base is...In the given buffer of 0.100 M in NH4Cl and 0.100 M in NH3, NH3 is weak base and NH4Cl is a...The phase transition is from solid to gas during the chemical reaction, so entropy increases and...The equation for this reaction as follows: VO2+(aq)+Sn(s)+H+(aq)→VO2+(aq)+Sn2+(aq)+H2O(l) Separate...The original atom is called parent nuclide, and the product of the decay is called the daughter...Justification for the correct statement: Carbon has a valency of 4. So, carbon can form covalent...The lipids are a diverse group of naturally occurring organic compounds and chemical components of...Justify reasons for the correct statement: The AlO2− units substitute for three-fourths of SiO2;...Justify reason for correct statement: Gold occurs in elemental state with some small particles and...When we write the electron configuration of Cu+ ion using the periodic table, we see that argon is...
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