Mastering Chemistry with Pearson eText ...4th EditionNivaldo J. Tro Publisher: PEARSONISBN: 9780134162485
Mastering Chemistry with Pearson eText ...
Solutions for Mastering Chemistry with Pearson eText -- Standalone Access Card -- for Chemistry: A Molecular Approach (4th Edition)
Problem 1SAQ:
A chemical system produces 155 kJ of heat and does 22 kJ of work. What is E for the surroundings? a)...Problem 2SAQ:
Q2. Which sample is most likely to undergo the smallest change in temperature upon the absorption of...Problem 4SAQ:
Q4. A 12.5-g sample of granite initially at 82.0 °C is immersed into 25.0 g of water initially at...Problem 5SAQ:
Q5. A cylinder with a moving piston expands from an initial volume of 0.250 L against an external...Problem 7SAQ:
Q7. Hydrogen gas reacts with oxygen to form water:
2 H2(g) + O2(g) → 2 H2O(g) ΔH = –483.5...Problem 15SAQ:
Q15. Natural gas burns in air to form carbon dioxide and water, releasing heat.
CH4(g) + O2(g) →...Problem 1E:
1. What is thermochemistry? Why is it important?
Problem 4E:
4. State the law of conservation of energy. How does it relate to energy exchanges between a...Problem 10E:
10. If energy flows out of a chemical system and into the surroundings, what is the sign of...Problem 11E:
11. If the internal energy of the products of a reaction is higher than the internal energy of the...Problem 14E:
14. Explain how the sum of heat and work can be a state function, even though heat and work are...Problem 15E:
15. What is heat capacity? Explain the difference between heat capacity and specific heat capacity.
Problem 16E:
16. Explain how the high specific heat capacity of water can affect the weather in coastal regions.
Problem 17E:
17. If two objects, A and B, of different temperature come into direct contact, what is the...Problem 19E:
19. What is calorimetry? Explain the difference between a coffee-cup calorimeter and a bomb...Problem 20E:
20. What is the change in enthalpy (ΔH) for a chemical reaction? How is ΔH different from ΔE?
Problem 21E:
21. Explain the difference between an exothermic and an endothermic reaction. Give the sign of ΔH...Problem 22E:
22. From a molecular viewpoint, where does the energy emitted in an exothermic chemical reaction...Problem 23E:
23. From a molecular viewpoint, where does the energy absorbed in an endothermic chemical reaction...Problem 24E:
24. Is the change in enthalpy for a reaction an extensive property? Explain the relationship between...Problem 36E:
36. A particular frost-free refrigerator uses about 745 kWh of electrical energy per year. Express...Problem 37E:
37. Which statement is true of the internal energy of a system and its surroundings during an energy...Problem 39E:
39. Identify each energy exchange as primarily heat or work and determine whether the sign of ΔE is...Problem 40E:
40. Identify each energy exchange as primarily heat or work and determine whether the sign of ΔE is...Problem 41E:
41. A system releases 622 kJ of heat and does 105 kJ of work on the surroundings. What is the change...Problem 42E:
42. A system absorbs 196 kJ of heat and the surroundings do 117 kJ of work on the system. What is...Problem 43E:
43. The gas in a piston (defined as the system) warms and absorbs 655 J of heat. The expansion...Problem 47E:
47. How much heat is required to warm 1.50 L of water from 25.0 °C to 100.0 °C? (Assume a density of...Problem 49E:
49. Suppose that 25 g of each substance is initially at 27.0 °C. What is the final temperature of...Problem 50E:
50. An unknown mass of each substance, initially at 23.0 °C, absorbs 1.95 × 103 J of heat. The final...Problem 51E:
51. How much work (in J) is required to expand the volume of a pump from 0.0 L to 2.5 L against an...Problem 53E:
53. The air within a piston equipped with a cylinder absorbs 565 J of heat and expands from an...Problem 54E:
54. A gas is compressed from an initial volume of 5.55 L to a final volume of 1.22 L by an external...Problem 55E:
55. When 1 mol of a fuel burns at constant pressure, it produces 3452 kJ of heat and does 11 kJ of...Problem 56E:
56. The change in internal energy for the combustion of 1.0 mol of octane at a pressure of 1.0 atm...Problem 57E:
57. Determine whether each process is exothermic or endothermic and indicate the sign of ΔH.
a....Problem 58E:
58. Determine whether each process is exothermic or endothermic and indicate the sign of ΔH.
a. dry...Problem 59E:
59. Consider the thermochemical equation for the combustion of acetone (C3H6O), the main ingredient...Problem 60E:
60. What mass of natural gas (CH4) must burn to emit 267 kJ of heat?
CH4(g) + 2 O2(g) → CO2(g) + 2...Problem 65E:
65. A silver block, initially at 58.5 °C, is submerged into 100.0 g of water at 24.8 °C, in an...Problem 67E:
67. A 31.1-g wafer of pure gold, initially at 69.3 °C, is submerged into 64.2 g of water at 27.8 °C...Problem 70E:
70. A 2.74-g sample of a substance suspected of being pure gold is warmed to 72.1 °C and submerged...Problem 71E:
71. Exactly 1.5 g of a fuel burns under conditions of constant pressure and then again under...Problem 72E:
72. In order to obtain the largest possible amount of heat from a chemical reaction in which there...Problem 73E:
73. When 0.514 g of biphenyl (C12H10) undergoes combustion in a bomb calorimeter, the temperature...Problem 75E:
75. Zinc metal reacts with hydrochloric acid according to the balanced equation:
Zn(s) + 2 HCl(aq) →...Problem 77E:
77. For each generic reaction, determine the value of ΔH2 in terms of ΔH1.
a. A + B → 2 C ΔH1
...Problem 79E:
79. Calculate ΔHrxn for the reaction:
Fe2O3(s) + 3 CO(g) → 2 Fe(s) + 3 CO2(g)
Use the following...Problem 80E:
80. Calculate ΔHrxn for the reaction:
CaO(s) + CO2(g) → CaCO3(s)
Use the following reactions and...Problem 81E:
81. Calculate ΔHrxn for the reaction:
5 C(s) + 6 H2(g) → C5H12(l)
Use the following reactions and...Problem 82E:
82. Calculate ΔHrxn for the reaction:
CH4(g) + 4 Cl2(g) → CCl4(g) + 4 HCl(g)
Use the following...Problem 83E:
83. Write an equation for the formation of each compound from its elements in their standard states,...Problem 85E:
85. Hydrazine (N2H4) is a fuel used by some spacecraft. It is normally oxidized by N2O4 according to...Problem 89E:
89. During photosynthesis, plants use energy from sunlight to form glucose (C6H12O6) and oxygen from...Problem 91E:
91. Top fuel dragsters and funny cars burn nitromethane as fuel according to the balanced combustion...Problem 92E:
92. The explosive nitroglycerin (C3H5N3O9) decomposes rapidly upon ignition or sudden impact...Problem 93E:
93. Determine the mass of CO2 produced by burning enough of each fuel to produce 1.00 × 102 kJ of...Problem 99E:
99. Evaporating sweat cools the body because evaporation is an endothermic process:
H2O(l) →...Problem 101E:
101. Use standard enthalpies of formation to calculate the standard change in enthalpy for the...Problem 102E:
102. Dry ice is solid carbon dioxide. Instead of melting, solid carbon dioxide sublimes according to...Problem 103E:
103. A 25.5-g aluminum block is warmed to 65.4 °C and plunged into an insulated beaker containing...Problem 107E:
107. Derive a relationship between ΔH and ΔE for a process in which the temperature of a fixed...Problem 112E:
112. When 10.00 g of phosphorus is burned in O2(g) to form P4O10(s), enough heat is generated to...Problem 114E:
114. The of TiI3(s) is –328 kJ/mol and the ΔH° for the reaction 2 Ti(s) + 3 I2(g) → 2 TiI3(s) is...Problem 118E:
118. A pure gold ring and a pure silver ring have a total mass of 14.9 g. The two rings are heated...Problem 131E:
131. Which statement is true of the internal energy of the system and its surroundings following a...Problem 133E:
133. Which expression describes the heat evolved in a chemical reaction when the reaction is carried...Problem 135E:
135. A 1-kg cylinder of aluminum and 1-kg jug of water, both at room temperature, are put into a...Problem 137E:
137. When 1 mol of a gas burns at constant pressure, it produces 2418 J of heat and does 5 J of...Browse All Chapters of This Textbook
Chapter 1 - Matter, Measurement, And Problem SolvingChapter 2 - Atoms And ElementsChapter 3 - Molecules, Compounds, And Chemical EquationsChapter 4 - Chemical Quantities And Aqueous ReactionsChapter 5 - GasesChapter 6 - ThermochemistryChapter 7 - The Quantum-Mechanical Model Of The AtomChapter 8 - Periodic Properties Of The ElementsChapter 9 - Chemical Bonding I: The Lewis ModelChapter 10 - Chemical Bonding II: Molecular Shapes, Valence Bond Theory, And Molecular Orbital Theory
Chapter 11 - Liquids, Solids, And Intermolecular ForcesChapter 12 - Solids And Modern MaterialsChapter 13 - SolutionsChapter 14 - Chemical KineticsChapter 15 - Chemical EquilibriumChapter 16 - Acids And BasesChapter 17 - Aqueous Ionic EquilibriumChapter 18 - Free Energy And ThermodynamicsChapter 19 - ElectrochemistryChapter 20 - Radioactivity And Nuclear ChemistryChapter 21 - Organic ChemistryChapter 22 - BiochemistryChapter 23 - Chemistry Of The NonmentalsChapter 24 - Metals And MetallurgyChapter 25 - Transition Metals And Coordination Compounds
Sample Solutions for this Textbook
We offer sample solutions for Mastering Chemistry with Pearson eText -- Standalone Access Card -- for Chemistry: A Molecular Approach (4th Edition) homework problems. See examples below:
Chapter 1, Problem 1SAQChapter 2, Problem 1SAQChapter 3, Problem 1SAQExplanation: Molar mass of MnO2= 55 + 2 × 16 = 55 + 32 = 87 Number of moles of MnO2= 25.087 = 0.287...Given: Initial pressure, P1 = 547 mmHg Initial volume, V1 = 0.500 L Final volume, V2 = 225 mL =...Chapter 6, Problem 1SAQChapter 7, Problem 1SAQJustify reasons for the correct statement: Coulomb’s law states that the potential energy (E) of two...Explanation: Ionic bond is formed between a positive ion and a negative ion. Positive ion results...
Reason for correct option: Lewis structure of CBr4: CBr4 Has 25 valence electrons. The central atom...The molecules of gases are not rigid. They have large space between them, more as compared to...Justify reasons for the correct answer: Calculate the separation between the atomic layers in the...Justify reasons for the correct statement: Octane is a nonpolar solvent. A compound or solute that...Justify reasons for the correct statement: The average rate of the reaction is written as follows:...Justify reasons for correct statement: The given reaction is as follows: C(s)+2H2(g)⇌CH4(g) Here,...Justification for the correct option: When an acid donates its hydrogen ion, a conjugate base is...In the given buffer of 0.100 M in NH4Cl and 0.100 M in NH3, NH3 is weak base and NH4Cl is a...The phase transition is from solid to gas during the chemical reaction, so entropy increases and...The equation for this reaction as follows: VO2+(aq)+Sn(s)+H+(aq)→VO2+(aq)+Sn2+(aq)+H2O(l) Separate...The original atom is called parent nuclide, and the product of the decay is called the daughter...Justification for the correct statement: Carbon has a valency of 4. So, carbon can form covalent...The lipids are a diverse group of naturally occurring organic compounds and chemical components of...Justify reasons for the correct statement: The AlO2− units substitute for three-fourths of SiO2;...Justify reason for correct statement: Gold occurs in elemental state with some small particles and...When we write the electron configuration of Cu+ ion using the periodic table, we see that argon is...
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