Solutions for Mastering Chemistry with Pearson eText -- Standalone Access Card -- for Chemistry: A Molecular Approach (4th Edition)
Problem 2SAQ:
Q2. Which pair is a Brønsted–Lowry conjugate acid–base pair?
a) NH3; NH4+
b) H3O+; OH–
c) HCl;...Problem 5SAQ:
Q5. An HNO3(aq) solution has a pH of 1.75. What is the molar concentration of the HNO3(aq)...Problem 6SAQ:
Q6. Find the pH of a 0.350 M aqueous benzoic acid solution. For benzoic acid, Ka = 6.5 × 10–5.
a)...Problem 7SAQ:
Q7. Find the pH of a 0.155 M HClO2(aq) solution. For HClO2, Ka = 0.011.
a) 0.92
b) 1.44
c) 1.39
d)...Problem 15SAQ:
Q15. Which acid has the largest Ka: HClO2(aq), HBrO2(aq), or HIO2(aq)?
a) HClO2(aq)
b) HBrO2(aq)
c)...Problem 13E:
13. Write an equation for the autoionization of water and an expression for the ion product constant...Problem 22E:
22. How can you determine if an anion will act as a weak base? Write a generic equation showing the...Problem 23E:
23. What is the relationship between the acid ionization constant for a weak acid (Ka) and the base...Problem 25E:
25. When calculating the [H3O+] for a polyprotic acid, the second ionization step can often be...Problem 33E:
33. Identify each substance as an acid or a base and write a chemical equation showing how it is an...Problem 34E:
34. Identify each substance as an acid or a base and write a chemical equation showing how it is an...Problem 35E:
35. In each reaction, identify the Brønsted–Lowry acid, the Brønsted–Lowry base, the conjugate acid,...Problem 37E:
37. Write the formula for the conjugate base of each acid.
a. HCl
b. H2SO3
c. HCHO2
d. HF
Problem 38E:
38. Write the formula for the conjugate acid of each base.
a. NH3
b. ClO4–
c. HSO4–
d. CO32–
Problem 39E:
39. Both H2O and H2PO4– are amphoteric. Write an equation to show how each substance can act as an...Problem 40E:
40. Both HCO3– and HS– are amphoteric. Write an equation to show how each substance can act as an...Problem 47E:
47. Calculate [OH–] in each aqueous solution at 25 °C, and classify the solution as acidic or...Problem 50E:
50. Calculate [H3O+] and [OH–] for each solution at 25 °C.
a. pH = 8.55
b. pH = 11.23
c. pH = 2.87
Problem 53E:
53. Like all equilibrium constants, the value of Kw depends on temperature. At body temperature (37...Problem 55E:
55. Calculate the pH of each acid solution. Explain how the resulting pH values demonstrate that the...Problem 58E:
58. Determine the pH of each solution.
a. 0.048 M HI
b. 0.0895 M HClO4
c. a solution that is 0.045 M...Problem 61E:
61. What is the pH of a solution in which 224 mL of HCl(g), measured at 27.2 °C and 1.02 atm, is...Problem 65E:
65. Determine the pH of an HNO2 solution of each concentration. In which cases can you not make the...Problem 66E:
66. Determine the pH of an HF solution of each concentration. In which cases can you not make the...Problem 102E:
102. Determine if each salt will form a solution that is acidic, basic, or pH-neutral.
a....Problem 105E:
105. Determine the pH of each solution.
a. 0.10 M NH4Cl
b. 0.10 M NaC2H3O2
c. 0.10 M NaCl
Problem 106E:
106. Determine the pH of each solution.
a. 0.20 M KCHO2
b. 0.20 M CH3NH3I
c. 0.20 M KI
Problem 112E:
112. Calculate the [H3O+] and pH of each polyprotic acid solution.
a. 0.125 M H2CO3
b. 0.125 M...Problem 115E:
115. Calculate the [H3O+] and pH of each H2SO4 solution. At approximately what concentration does...Problem 119E:
119. Based on their molecular structure, pick the stronger acid from each pair of oxyacids. Explain...Problem 122E:
122. Which is a stronger base, PO43– or AsO43–? Explain.
Problem 123E:
123. Classify each species as either a Lewis acid or a Lewis base.
a. Fe3 +
b. BH3
c. NH3
d. F–
Problem 124E:
124. Classify each species as either a Lewis acid or a Lewis base.
a. BeCl2
b. OH–
c. B(OH)3
d. CN–
Problem 133E:
133. Acid rain over the Great Lakes has a pH of about 4.5. Calculate the [H3O+] of this rain and...Problem 134E:
134. White wines tend to be more acidic than red wines. Find the [H3O+] in a Sauvignon Blanc with a...Problem 135E:
135. Common aspirin is acetylsalicylic acid, which has the structure shown here and a pKa of...Problem 140E:
140. Determine the pH of each two-component solution.
a. 0.050 M KOH and 0.015 M Ba(OH)2
b. 0.265 M...Problem 143E:
143. The pH of a 1.00 M solution of urea, a weak organic base, is 7.050. Calculate the Ka of...Problem 144E:
144. A solution is prepared by dissolving 0.10 mol of acetic acid and 0.10 mol of ammonium chloride...Problem 145E:
145. Lactic acid is a weak acid found in milk. Its calcium salt is a source of calcium for growing...Problem 150E:
150. To what volume should you dilute 1 L of a solution of a weak acid HA to reduce the [H+] to...Problem 153E:
153. Calculate the pH of a solution prepared from 0.200 mol of NH4CN and enough water to make 1.00...Problem 154E:
154. To 1.0 L of a 0.30 M solution of HClO2 is added 0.20 mol of NaF. Calculate the [HClO2] at...Problem 155E:
155. A mixture of Na2CO3 and NaHCO3 has a mass of 82.2 g. It is dissolved in 1.00 L of water, and...Problem 156E:
156. A mixture of NaCN and NaHSO4 consists of a total of 0.60 mol. When the mixture is dissolved in...Problem 157E:
157. Without doing any calculations, determine which solution in each pair is more acidic.
a. 0.0100...Problem 158E:
158. Without doing any calculations, determine which solution in each pair is more basic.
a. 0.100 M...Browse All Chapters of This Textbook
Chapter 1 - Matter, Measurement, And Problem SolvingChapter 2 - Atoms And ElementsChapter 3 - Molecules, Compounds, And Chemical EquationsChapter 4 - Chemical Quantities And Aqueous ReactionsChapter 5 - GasesChapter 6 - ThermochemistryChapter 7 - The Quantum-Mechanical Model Of The AtomChapter 8 - Periodic Properties Of The ElementsChapter 9 - Chemical Bonding I: The Lewis ModelChapter 10 - Chemical Bonding II: Molecular Shapes, Valence Bond Theory, And Molecular Orbital Theory
Chapter 11 - Liquids, Solids, And Intermolecular ForcesChapter 12 - Solids And Modern MaterialsChapter 13 - SolutionsChapter 14 - Chemical KineticsChapter 15 - Chemical EquilibriumChapter 16 - Acids And BasesChapter 17 - Aqueous Ionic EquilibriumChapter 18 - Free Energy And ThermodynamicsChapter 19 - ElectrochemistryChapter 20 - Radioactivity And Nuclear ChemistryChapter 21 - Organic ChemistryChapter 22 - BiochemistryChapter 23 - Chemistry Of The NonmentalsChapter 24 - Metals And MetallurgyChapter 25 - Transition Metals And Coordination Compounds
Sample Solutions for this Textbook
We offer sample solutions for Mastering Chemistry with Pearson eText -- Standalone Access Card -- for Chemistry: A Molecular Approach (4th Edition) homework problems. See examples below:
Chapter 1, Problem 1SAQChapter 2, Problem 1SAQChapter 3, Problem 1SAQExplanation: Molar mass of MnO2= 55 + 2 × 16 = 55 + 32 = 87 Number of moles of MnO2= 25.087 = 0.287...Given: Initial pressure, P1 = 547 mmHg Initial volume, V1 = 0.500 L Final volume, V2 = 225 mL =...Chapter 6, Problem 1SAQChapter 7, Problem 1SAQJustify reasons for the correct statement: Coulomb’s law states that the potential energy (E) of two...Explanation: Ionic bond is formed between a positive ion and a negative ion. Positive ion results...
Reason for correct option: Lewis structure of CBr4: CBr4 Has 25 valence electrons. The central atom...The molecules of gases are not rigid. They have large space between them, more as compared to...Justify reasons for the correct answer: Calculate the separation between the atomic layers in the...Justify reasons for the correct statement: Octane is a nonpolar solvent. A compound or solute that...Justify reasons for the correct statement: The average rate of the reaction is written as follows:...Justify reasons for correct statement: The given reaction is as follows: C(s)+2H2(g)⇌CH4(g) Here,...Justification for the correct option: When an acid donates its hydrogen ion, a conjugate base is...In the given buffer of 0.100 M in NH4Cl and 0.100 M in NH3, NH3 is weak base and NH4Cl is a...The phase transition is from solid to gas during the chemical reaction, so entropy increases and...The equation for this reaction as follows: VO2+(aq)+Sn(s)+H+(aq)→VO2+(aq)+Sn2+(aq)+H2O(l) Separate...The original atom is called parent nuclide, and the product of the decay is called the daughter...Justification for the correct statement: Carbon has a valency of 4. So, carbon can form covalent...The lipids are a diverse group of naturally occurring organic compounds and chemical components of...Justify reasons for the correct statement: The AlO2− units substitute for three-fourths of SiO2;...Justify reason for correct statement: Gold occurs in elemental state with some small particles and...When we write the electron configuration of Cu+ ion using the periodic table, we see that argon is...
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