Mastering Chemistry with Pearson eText ...4th EditionNivaldo J. Tro Publisher: PEARSONISBN: 9780134162485
Mastering Chemistry with Pearson eText ...
Solutions for Mastering Chemistry with Pearson eText -- Standalone Access Card -- for Chemistry: A Molecular Approach (4th Edition)
Problem 2SAQ:
Q2. Dinitrogen monoxide decomposes into nitrogen and oxygen when heated. The initial rate of the...Problem 3SAQ:
Q3. This plot shows the rate of the decomposition of SO2Cl2 into SO2 and Cl2 as a function of the...Problem 4SAQ:
Q4. For the reaction 2 A + B → C, the initial rate is measured at several different reactant...Problem 9SAQ:
Q9. The rate constant of a reaction is measured at different temperatures. A plot of the natural log...Problem 12SAQ:
Q12. Which statement is true regarding the function of a catalyst in a chemical reaction?
a) A...Problem 14SAQ:
Q14. Use collision theory to determine which single-step reaction has the smallest orientation...Problem 15SAQ:
Q15. Carbon monoxide and chlorine gas react to form phosgene (COCl2) according to the...Problem 4E:
4. Why is the reaction rate for reactants defined as the negative of the change in reactant...Problem 8E:
8. For a reaction with multiple reactants, how is the overall order of the reaction defined?
Problem 9E:
9. Explain the difference between the rate law for a reaction and the integrated rate law for a...Problem 10E:
10. Write integrated rate laws for zero-order, first-order, and second-order reactions of the form A...Problem 12E:
12. How do reaction rates typically depend on temperature? What part of the rate law is temperature...Problem 14E:
14. What is an Arrhenius plot? Explain the significance of the slope and intercept of an Arrhenius...Problem 17E:
17. In a reaction mechanism, what is an elementary step? Write down the three most common elementary...Problem 18E:
18. What are the two requirements for a proposed mechanism to be valid for a given reaction?
Problem 25E:
25. Consider the reaction:
2 HBr(g) → H2(g) + Br2(g)
a. Express the rate of the reaction in terms of...Problem 26E:
26. Consider the reaction:
2 N2O(g) → 2 N2(g) + O2(g)
a. Express the rate of the reaction in terms...Problem 27E:
27. For the reaction 2 A(g) + B(g) → 3 C(g),
a. determine the expression for the rate of the...Problem 28E:
28. For the reaction A(g) + B(g) → 2 C(g),
a. determine the expression for the rate of the reaction...Problem 34E:
34. Consider the reaction:
2 H2O2(aq) → 2 H2O(l) + O2(g)
The graph shows the concentration of H2O2...Problem 38E:
38. This reaction is first order in N2O5:
N2O5(g) → NO3(g) + NO2(g)
The rate constant for the...Problem 42E:
42. Consider the data showing the initial rate of a reaction (A → products) at several different...Problem 45E:
45. The tabulated data were collected for this reaction:
2 NO2(g) + F2(g) → 2 NO2F(g)
[NO2] [F2]...Problem 46E:
46. The tabulated data were collected for this reaction:
CH3Cl(g) + 3 Cl2(g) → CCl4(g) + 3...Problem 47E:
47. Indicate the order of reaction consistent with each observation.
a. A plot of the concentration...Problem 48E:
48. Indicate the order of reaction consistent with each observation.
a. The half-life of the...Problem 49E:
49. The tabulated data show the concentration of AB versus time for this reaction:
AB(g) → A(g) +...Problem 51E:
51. The tabulated data show the concentration of cyclobutane (C4H8) versus time for this...Problem 52E:
52. The reaction A → products was monitored as a function of time. The results are shown here.
Time...Problem 57E:
57. The half-life for the radioactive decay of U-238 is 4.5 billion years and is independent of...Problem 58E:
58. The half-life for the radioactive decay of C-14 is 5730 years and is independent of the initial...Problem 65E:
65. The data shown here were collected for the first-order reaction:
N2O(g) → N2(g) + O(g)
Use an...Problem 67E:
67. The tabulated data were collected for the second-order reaction:
Cl(g) + H2(g) → HCl(g) +...Problem 68E:
68. The tabulated data show the rate constant of a reaction measured at several different...Problem 69E:
69. A reaction has a rate constant of 0.0117/s at 400.0 K and 0.689/s at 450.0 K.
a. Determine the...Problem 70E:
70. A reaction has a rate constant of 0.000122/s at 27 °C and 0.228/s at 77 °C.
a. Determine the...Problem 80E:
80. Suppose that the reaction A → products is exothermic and has an activation barrier of 75 kJ/mol....Problem 81E:
81. Suppose that a catalyst lowers the activation barrier of a reaction from 125 kJ/mol to 55...Problem 91E:
91. Iodine atoms combine to form I2 in liquid hexane solvent with a rate constant of 1.5 × 1010...Problem 92E:
92. The hydrolysis of sucrose (C12H22O11) into glucose and fructose in acidic water has a rate...Problem 97E:
97. The desorption (leaving of the surface) of a single molecular layer of n-butane from a single...Problem 99E:
99. The kinetics of this reaction were studied as a function of temperature. (The reaction is first...Problem 102E:
102. Consider the two reactions:
a. Why is the activation barrier for the first reaction so much...Problem 103E:
103. Anthropologists can estimate the age of a bone or other sample of organic matter by its...Problem 104E:
104. Geologists can estimate the age of rocks by their uranium-238 content. The uranium is...Problem 106E:
106. Consider the reaction:
2 NH3(aq) + OCl–(aq) → N2H4(aq) + H2O(l) + Cl–(aq)
This three-step...Problem 113E:
113. In this chapter we have seen a number of reactions in which a single reactant forms products....Problem 115E:
115. The previous exercise shows how the first-order integrated rate law is derived from the...Browse All Chapters of This Textbook
Chapter 1 - Matter, Measurement, And Problem SolvingChapter 2 - Atoms And ElementsChapter 3 - Molecules, Compounds, And Chemical EquationsChapter 4 - Chemical Quantities And Aqueous ReactionsChapter 5 - GasesChapter 6 - ThermochemistryChapter 7 - The Quantum-Mechanical Model Of The AtomChapter 8 - Periodic Properties Of The ElementsChapter 9 - Chemical Bonding I: The Lewis ModelChapter 10 - Chemical Bonding II: Molecular Shapes, Valence Bond Theory, And Molecular Orbital Theory
Chapter 11 - Liquids, Solids, And Intermolecular ForcesChapter 12 - Solids And Modern MaterialsChapter 13 - SolutionsChapter 14 - Chemical KineticsChapter 15 - Chemical EquilibriumChapter 16 - Acids And BasesChapter 17 - Aqueous Ionic EquilibriumChapter 18 - Free Energy And ThermodynamicsChapter 19 - ElectrochemistryChapter 20 - Radioactivity And Nuclear ChemistryChapter 21 - Organic ChemistryChapter 22 - BiochemistryChapter 23 - Chemistry Of The NonmentalsChapter 24 - Metals And MetallurgyChapter 25 - Transition Metals And Coordination Compounds
Sample Solutions for this Textbook
We offer sample solutions for Mastering Chemistry with Pearson eText -- Standalone Access Card -- for Chemistry: A Molecular Approach (4th Edition) homework problems. See examples below:
Chapter 1, Problem 1SAQChapter 2, Problem 1SAQChapter 3, Problem 1SAQExplanation: Molar mass of MnO2= 55 + 2 × 16 = 55 + 32 = 87 Number of moles of MnO2= 25.087 = 0.287...Given: Initial pressure, P1 = 547 mmHg Initial volume, V1 = 0.500 L Final volume, V2 = 225 mL =...Chapter 6, Problem 1SAQChapter 7, Problem 1SAQJustify reasons for the correct statement: Coulomb’s law states that the potential energy (E) of two...Explanation: Ionic bond is formed between a positive ion and a negative ion. Positive ion results...
Reason for correct option: Lewis structure of CBr4: CBr4 Has 25 valence electrons. The central atom...The molecules of gases are not rigid. They have large space between them, more as compared to...Justify reasons for the correct answer: Calculate the separation between the atomic layers in the...Justify reasons for the correct statement: Octane is a nonpolar solvent. A compound or solute that...Justify reasons for the correct statement: The average rate of the reaction is written as follows:...Justify reasons for correct statement: The given reaction is as follows: C(s)+2H2(g)⇌CH4(g) Here,...Justification for the correct option: When an acid donates its hydrogen ion, a conjugate base is...In the given buffer of 0.100 M in NH4Cl and 0.100 M in NH3, NH3 is weak base and NH4Cl is a...The phase transition is from solid to gas during the chemical reaction, so entropy increases and...The equation for this reaction as follows: VO2+(aq)+Sn(s)+H+(aq)→VO2+(aq)+Sn2+(aq)+H2O(l) Separate...The original atom is called parent nuclide, and the product of the decay is called the daughter...Justification for the correct statement: Carbon has a valency of 4. So, carbon can form covalent...The lipids are a diverse group of naturally occurring organic compounds and chemical components of...Justify reasons for the correct statement: The AlO2− units substitute for three-fourths of SiO2;...Justify reason for correct statement: Gold occurs in elemental state with some small particles and...When we write the electron configuration of Cu+ ion using the periodic table, we see that argon is...
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