Solutions for Chemistry: A Molecular Approach Selected Solutions Manual, Books a la Carte Edition
Problem 2SAQ:
Q2. Dinitrogen monoxide decomposes into nitrogen and oxygen when heated. The initial rate of the...Problem 3SAQ:
Q3. This plot shows the rate of the decomposition of SO2Cl2 into SO2 and Cl2 as a function of the...Problem 4SAQ:
Q4. For the reaction 2 A + B → C, the initial rate is measured at several different reactant...Problem 9SAQ:
Q9. The rate constant of a reaction is measured at different temperatures. A plot of the natural log...Problem 12SAQ:
Q12. Which statement is true regarding the function of a catalyst in a chemical reaction?
a) A...Problem 14SAQ:
Q14. Use collision theory to determine which single-step reaction has the smallest orientation...Problem 15SAQ:
Q15. Carbon monoxide and chlorine gas react to form phosgene (COCl2) according to the...Problem 4E:
4. Why is the reaction rate for reactants defined as the negative of the change in reactant...Problem 8E:
8. For a reaction with multiple reactants, how is the overall order of the reaction defined?
Problem 9E:
9. Explain the difference between the rate law for a reaction and the integrated rate law for a...Problem 10E:
10. Write integrated rate laws for zero-order, first-order, and second-order reactions of the form A...Problem 12E:
12. How do reaction rates typically depend on temperature? What part of the rate law is temperature...Problem 14E:
14. What is an Arrhenius plot? Explain the significance of the slope and intercept of an Arrhenius...Problem 17E:
17. In a reaction mechanism, what is an elementary step? Write down the three most common elementary...Problem 18E:
18. What are the two requirements for a proposed mechanism to be valid for a given reaction?
Problem 25E:
25. Consider the reaction:
2 HBr(g) → H2(g) + Br2(g)
a. Express the rate of the reaction in terms of...Problem 26E:
26. Consider the reaction:
2 N2O(g) → 2 N2(g) + O2(g)
a. Express the rate of the reaction in terms...Problem 27E:
27. For the reaction 2 A(g) + B(g) → 3 C(g),
a. determine the expression for the rate of the...Problem 28E:
28. For the reaction A(g) + B(g) → 2 C(g),
a. determine the expression for the rate of the reaction...Problem 34E:
34. Consider the reaction:
2 H2O2(aq) → 2 H2O(l) + O2(g)
The graph shows the concentration of H2O2...Problem 38E:
38. This reaction is first order in N2O5:
N2O5(g) → NO3(g) + NO2(g)
The rate constant for the...Problem 42E:
42. Consider the data showing the initial rate of a reaction (A → products) at several different...Problem 45E:
45. The tabulated data were collected for this reaction:
2 NO2(g) + F2(g) → 2 NO2F(g)
[NO2] [F2]...Problem 46E:
46. The tabulated data were collected for this reaction:
CH3Cl(g) + 3 Cl2(g) → CCl4(g) + 3...Problem 47E:
47. Indicate the order of reaction consistent with each observation.
a. A plot of the concentration...Problem 48E:
48. Indicate the order of reaction consistent with each observation.
a. The half-life of the...Problem 49E:
49. The tabulated data show the concentration of AB versus time for this reaction:
AB(g) → A(g) +...Problem 51E:
51. The tabulated data show the concentration of cyclobutane (C4H8) versus time for this...Problem 52E:
52. The reaction A → products was monitored as a function of time. The results are shown here.
Time...Problem 57E:
57. The half-life for the radioactive decay of U-238 is 4.5 billion years and is independent of...Problem 58E:
58. The half-life for the radioactive decay of C-14 is 5730 years and is independent of the initial...Problem 65E:
65. The data shown here were collected for the first-order reaction:
N2O(g) → N2(g) + O(g)
Use an...Problem 67E:
67. The tabulated data were collected for the second-order reaction:
Cl(g) + H2(g) → HCl(g) +...Problem 68E:
68. The tabulated data show the rate constant of a reaction measured at several different...Problem 69E:
69. A reaction has a rate constant of 0.0117/s at 400.0 K and 0.689/s at 450.0 K.
a. Determine the...Problem 70E:
70. A reaction has a rate constant of 0.000122/s at 27 °C and 0.228/s at 77 °C.
a. Determine the...Problem 80E:
80. Suppose that the reaction A → products is exothermic and has an activation barrier of 75 kJ/mol....Problem 81E:
81. Suppose that a catalyst lowers the activation barrier of a reaction from 125 kJ/mol to 55...Problem 91E:
91. Iodine atoms combine to form I2 in liquid hexane solvent with a rate constant of 1.5 × 1010...Problem 92E:
92. The hydrolysis of sucrose (C12H22O11) into glucose and fructose in acidic water has a rate...Problem 97E:
97. The desorption (leaving of the surface) of a single molecular layer of n-butane from a single...Problem 99E:
99. The kinetics of this reaction were studied as a function of temperature. (The reaction is first...Problem 102E:
102. Consider the two reactions:
a. Why is the activation barrier for the first reaction so much...Problem 103E:
103. Anthropologists can estimate the age of a bone or other sample of organic matter by its...Problem 104E:
104. Geologists can estimate the age of rocks by their uranium-238 content. The uranium is...Problem 106E:
106. Consider the reaction:
2 NH3(aq) + OCl–(aq) → N2H4(aq) + H2O(l) + Cl–(aq)
This three-step...Problem 113E:
113. In this chapter we have seen a number of reactions in which a single reactant forms products....Problem 115E:
115. The previous exercise shows how the first-order integrated rate law is derived from the...Browse All Chapters of This Textbook
Chapter 1 - Matter, Measurement, And Problem SolvingChapter 2 - Atoms And ElementsChapter 3 - Molecules, Compounds, And Chemical EquationsChapter 4 - Chemical Quantities And Aqueous ReactionsChapter 5 - GasesChapter 6 - ThermochemistryChapter 7 - The Quantum-Mechanical Model Of The AtomChapter 8 - Periodic Properties Of The ElementsChapter 9 - Chemical Bonding I: The Lewis ModelChapter 10 - Chemical Bonding II: Molecular Shapes, Valence Bond Theory, And Molecular Orbital Theory
Chapter 11 - Liquids, Solids, And Intermolecular ForcesChapter 12 - Solids And Modern MaterialsChapter 13 - SolutionsChapter 14 - Chemical KineticsChapter 15 - Chemical EquilibriumChapter 16 - Acids And BasesChapter 17 - Aqueous Ionic EquilibriumChapter 18 - Free Energy And ThermodynamicsChapter 19 - ElectrochemistryChapter 20 - Radioactivity And Nuclear ChemistryChapter 21 - Organic ChemistryChapter 22 - BiochemistryChapter 23 - Chemistry Of The NonmentalsChapter 24 - Metals And MetallurgyChapter 25 - Transition Metals And Coordination Compounds
Book Details
The Fourth Edition of Niva Tro's" Chemistry: A Molecular Approach" reinforces students development of 21st century skills including data interpretation and analysis, problem solving and quantitative reasoning, applying conceptual understanding to new situations and peer-to-peer collaboration. Nivaldo Tro presents chemistry visually through multi-level images macroscopic, molecular, and symbolic representations helping students see the connections between the world they see around them (macroscopic), the atoms and molecules that compose the world (molecular), and the formulas they write down on paper (symbolic). The benefits of Dr. Tro's problem-solving approach are reinforced through digital, Interactive Worked Examples that provide students with an office-hour type of environment and expanded coverage on the latest developments in chemistry. New Key Concept Videos explain difficult concepts while new end-of-chapter problems including Group Work questions and Data Interpretation and Analysis questions engage students in applying their understanding of chemistry.
Sample Solutions for this Textbook
We offer sample solutions for Chemistry: A Molecular Approach Selected Solutions Manual, Books a la Carte Edition homework problems. See examples below:
Chapter 1, Problem 1SAQChapter 2, Problem 1SAQChapter 3, Problem 1SAQExplanation: Molar mass of MnO2= 55 + 2 × 16 = 55 + 32 = 87 Number of moles of MnO2= 25.087 = 0.287...Given: Initial pressure, P1 = 547 mmHg Initial volume, V1 = 0.500 L Final volume, V2 = 225 mL =...Chapter 6, Problem 1SAQChapter 7, Problem 1SAQJustify reasons for the correct statement: Coulomb’s law states that the potential energy (E) of two...Explanation: Ionic bond is formed between a positive ion and a negative ion. Positive ion results...
Reason for correct option: Lewis structure of CBr4: CBr4 Has 25 valence electrons. The central atom...The molecules of gases are not rigid. They have large space between them, more as compared to...Justify reasons for the correct answer: Calculate the separation between the atomic layers in the...Justify reasons for the correct statement: Octane is a nonpolar solvent. A compound or solute that...Justify reasons for the correct statement: The average rate of the reaction is written as follows:...Justify reasons for correct statement: The given reaction is as follows: C(s)+2H2(g)⇌CH4(g) Here,...Justification for the correct option: When an acid donates its hydrogen ion, a conjugate base is...In the given buffer of 0.100 M in NH4Cl and 0.100 M in NH3, NH3 is weak base and NH4Cl is a...The phase transition is from solid to gas during the chemical reaction, so entropy increases and...The equation for this reaction as follows: VO2+(aq)+Sn(s)+H+(aq)→VO2+(aq)+Sn2+(aq)+H2O(l) Separate...The original atom is called parent nuclide, and the product of the decay is called the daughter...Justification for the correct statement: Carbon has a valency of 4. So, carbon can form covalent...The lipids are a diverse group of naturally occurring organic compounds and chemical components of...Justify reasons for the correct statement: The AlO2− units substitute for three-fourths of SiO2;...Justify reason for correct statement: Gold occurs in elemental state with some small particles and...When we write the electron configuration of Cu+ ion using the periodic table, we see that argon is...
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