Solutions for Chemistry: A Molecular Approach
Problem 2SAQ:
Q2. The equilibrium constant for the reaction shown here is Kc = 1.0 × 103. A reaction mixture at...Problem 3SAQ:
Q3. Use the data shown here to find the equilibrium constant (Kc) for the reaction A(g) 2 B(g) +...Problem 6SAQ:
Q6. For the reaction 2 A(g) B(g), the equilibrium constant is Kp = 0.76. A reaction mixture...Problem 7SAQ:
Q7. Consider the reaction between iodine gas and chlorine gas to form iodine monochloride:
I2(g) +...Problem 23E:
23. When this reaction comes to equilibrium, will the concentrations of the reactants or products be...Problem 25E:
25. H2 and I2 are combined in a flask and allowed to react according to the reaction:
H2(g) + I2(g) ...Problem 28E:
28. This reaction has an equilibrium constant of Kp = 2.2 × 106 at 298 K.
2 COF2(g) CO2(g) +...Problem 29E:
29. Consider the reactions and their respective equilibrium constants:
NO(g) + Br2(g) NOBr(g) Kp =...Problem 30E:
30. Use the reactions and their equilibrium constants to predict the equilibrium constant for the...Problem 31E:
31. Calculate Kc for each reaction.
a. I2(g) 2 I(g) Kp = 6.26 × 10–22 (at 298 K)
b. CH4(g) +...Problem 32E:
32. Calculate Kp for each reaction.
a. N2O4(g) 2 NO2(g) Kc = 5.9 × 10–3 (at 298 K)
b. N2(g) + 3...Problem 33E:
33. Write an equilibrium expression for each chemical equation involving one or more solid or liquid...Problem 35E:
35. Consider the reaction:
CO(g) + 2 H2(g) CH3OH(g)
An equilibrium mixture of this reaction at a...Problem 36E:
36. Consider the reaction:
NH4HS(s) NH3(g) + H2S(g)
An equilibrium mixture of this reaction at a...Problem 37E:
37. Consider the reaction:
N2(g) + 3 H2(g) 2 NH3(g)
Complete the table. Assume that all...Problem 38E:
38. Consider the following reaction:
H2(g) + I2(g) 2 HI(g)
Complete the table. Assume that all...Problem 39E:
39. Consider the reaction:
2 NO(g) + Br2(g) 2 NOBr(g) Kp = 28.4 at 298 K
In a reaction mixture at...Problem 40E:
40. Consider the reaction:
SO2Cl2(g) SO2(g) + Cl2(g) Kp = 2.91 × 103 at 298 K
In a reaction at...Problem 41E:
41. For the reaction A(g) 2 B(g), a reaction vessel initially contains only A at a pressure of PA =...Problem 42E:
42. For the reaction 2 A(g) B(g) + 2 C(g), a reaction vessel initially contains only A at a...Problem 43E:
43. Consider the reaction:
Fe3+(aq) + SCN–(aq) FeSCN2+(aq)
A solution is made containing an initial...Problem 44E:
44. Consider the reaction:
SO2Cl2(g) SO2(g) + Cl2(g)
A reaction mixture is made containing an...Problem 45E:
45. Consider the reaction:
H2(g) + I2(g) 2 HI(g)
A reaction mixture in a 3.67-L flask at a certain...Problem 46E:
46. Consider the reaction:
CO(g) + 2 H2(g) CH3OH(g)
A reaction mixture in a 5.19-L flask at a...Problem 47E:
47. Consider the reaction:
NH4HS(s) NH3(g) + H2S(g)
At a certain temperature, Kc = 8.5 × 10–3. A...Problem 48E:
48. Consider the reaction:
2 H2S(g) 2 H2(g) + S2(g) Kp = 2.4 × 10–4 at 1073 K
A reaction mixture...Problem 49E:
49. Silver sulfate dissolves in water according to the reaction:
Ag2SO4(s) 2 Ag+(aq) + SO42–(aq)
Kc...Problem 50E:
50. Nitrogen dioxide dimerizes according to the reaction:
2 NO2(g) N2O4(g) Kp = 6.7 at 298 K
A...Problem 51E:
51. Consider the reaction and the associated equilibrium constant:
aA(g) bB(g) Kc = 4.0
Find the...Problem 52E:
52. Consider the reaction and the associated equilibrium constant:
aA(g) + bB(g) cC(g) Kc =...Problem 53E:
53. For the reaction shown here, Kc = 0.513 at 500 K.
N2O4(g) 2 NO2(g)
If a reaction vessel...Problem 54E:
54. For the reaction shown here, Kc = 255 at 1000 K.
CO(g) + Cl2(g) COCl2(g)
If a reaction mixture...Problem 55E:
55. Consider the reaction:
NiO(s) + CO(g) Ni(s) + CO2(g)
Kc = 4.0 × 103 at 1500 K
If a mixture of...Problem 56E:
56. Consider the reaction:
CO(g) + H2O(g) CO2(g) + H2(g) Kc = 102 at 500 K
If a reaction mixture...Problem 57E:
57. Consider the reaction:
HC2H3O2(aq) + H2O(l) H3O + (aq) + C2H3O2–(aq)
Kc = 1.8 × 10–5 at 25...Problem 59E:
59. Consider the reaction:
Br2(g) + Cl2(g) 2 BrCl(g) Kp = 1.11 × 10–4 at 150 K
A reaction mixture...Problem 64E:
64. Consider this reaction at equilibrium:
2 BrNO(g) 2 NO(g) + Br2(g)
Predict whether the reaction...Problem 65E:
65. Consider this reaction at equilibrium:
2 KClO3(s) 2 KCl(s) + 3 O2(g)
Predict whether the...Problem 66E:
66. Consider this reaction at equilibrium:
C(s) + H2O(g) CO(g) + H2(g)
Predict whether the reaction...Problem 67E:
67. Each reaction is allowed to come to equilibrium, and then the volume is changed as indicated....Problem 73E:
73. Carbon monoxide replaces oxygen in oxygenated hemoglobin according to the reaction:
HbO2(aq) +...Problem 76E:
76. A mixture of water and graphite is heated to 600 K. When the system comes to equilibrium, it...Problem 77E:
77. At 650 K, the reaction MgCO3(s) MgO(s) + CO2(g) has Kp = 0.026. A 10.0-L container at 650 K has...Problem 78E:
78. A system at equilibrium contains I2(g) at a pressure of 0.21 atm and I(g) at a pressure of 0.23...Problem 85E:
85. The system described by the reaction: CO(g) + Cl2(g) COCl2(g) is at equilibrium at a given...Problem 87E:
87. At 70 K, CCl4 decomposes to carbon and chlorine. The Kp for the decomposition is 0.76. Find the...Problem 88E:
88. The equilibrium constant for the reaction SO2(g) + NO2(g) SO3(g) + NO(g) is 3.0. Find the...Problem 89E:
89. A sample of CaCO3(s) is introduced into a sealed container of volume 0.654 L and heated to 1000...Problem 98E:
98. When N2O5(g) is heated, it dissociates into N2O3(g) and O2(g) according to the reaction:
N2O5(g)...Problem 99E:
99. A sample of SO3 is introduced into an evacuated sealed container and heated to 600 K. The...Browse All Chapters of This Textbook
Chapter 1 - Matter, Measurement, And Problem SolvingChapter 2 - Atoms And ElementsChapter 3 - Molecules, Compounds, And Chemical EquationsChapter 4 - Chemical Quantities And Aqueous ReactionsChapter 5 - GasesChapter 6 - ThermochemistryChapter 7 - The Quantum-mechanical Model Of The AtomChapter 8 - Periodic Properties Of The ElementsChapter 9 - Chemical Bonding I: The Lewis ModelChapter 10 - Chemical Bonding Ii: Molecular Shapes, Valence Bond Theory, And Molecular Orbital Theory
Chapter 11 - Liquids, Solids, And Intermolecular ForcesChapter 12 - SolutionsChapter 13 - Chemical KineticsChapter 14 - Chemical EquilibriumChapter 15 - Acids And BasesChapter 16 - Aqueous Ionic EquilibriumChapter 17 - Free Energy And ThermodynamicsChapter 18 - ElectrochemistryChapter 19 - Radioactivity And Nuclear ChemistryChapter 20 - Organic ChemistryChapter 21 - BiochemistryChapter 22 - Chemistry Of The NonmentalsChapter 23 - Metals And MetallurgyChapter 24 - Transition Metals And Coordination Compounds
Book Details
Chemistry: A Molecular Approach, Third Edition is an innovative, pedagogically driven text that explains challenging concepts in a student-oriented manner. Nivaldo Tro creates a rigorous and accessible treatment of general chemistry in the context of relevance and the big picture. Chemistry is presented visually through multi-level images - macroscopic, molecular, and symbolic representations - helping students see the connections between the world they see around them (macroscopic), the atoms and molecules that compose the world (molecular), and the formulas they write down on paper (symbolic). The hallmarks of Dr. Tro's problem-solving approach are reinforced through interactive media that provide students with an office-hour type of environment built around worked examples and expanded coverage on the latest developments in chemistry. Pioneering features allow students to sketch their ideas through new problems, and much more.
Sample Solutions for this Textbook
We offer sample solutions for Chemistry: A Molecular Approach homework problems. See examples below:
Chapter 1, Problem 1SAQChapter 2, Problem 1SAQChapter 3, Problem 1SAQExplanation: Molar mass of MnO2= 55 + 2 × 16 = 55 + 32 = 87 Number of moles of MnO2= 25.087 = 0.287...Given: Initial pressure, P1 = 547 mmHg Initial volume, V1 = 0.500 L Final volume, V2 = 225 mL =...Explanation: Given info: The amount of the heat produced = 155kJ. The amount of the work done =...Chapter 7, Problem 1SAQChapter 8, Problem 1SAQExplanation: Ionic bond is formed between a positive ion and a negative ion. Positive ion results...
Reason for correct option: Lewis structure of CBr4: CBr4 Has 25 valence electrons. The central atom...The molecules of gases are not rigid. They have large space between them, more as compared to...Justify reasons for the correct statement: Octane is a nonpolar solvent. A compound or solute that...Chapter 13, Problem 1SAQJustify reasons for correct statement: The given reaction is as follows: C(s)+2H2(g)⇌CH4(g) Here,...Justification for the correct option: When an acid donates its hydrogen ion, a conjugate base is...In the given buffer of 0.100 M in NH4Cl and 0.100 M in NH3, NH3 is weak base and NH4Cl is a...The phase transition is from solid to gas during the chemical reaction, so entropy increases and...The equation for this reaction as follows: VO2+(aq)+Sn(s)+H+(aq)→VO2+(aq)+Sn2+(aq)+H2O(l) Separate...The original atom is called parent nuclide, and the product of the decay is called the daughter...Justification for the correct statement: Carbon has a valency of 4. So, carbon can form covalent...The lipids are a diverse group of naturally occurring organic compounds and chemical components of...Justify reasons for the correct statement: The AlO2− units substitute for three-fourths of SiO2;...Justify reason for correct statement: Gold occurs in elemental state with some small particles and...When we write the electron configuration of Cu+ ion using the periodic table, we see that argon is...
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