Chemistry: A Molecular Approach
3rd Edition
ISBN: 9780321809247
Author: Nivaldo J. Tro
Publisher: Prentice Hall
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Chapter 14, Problem 26E
Interpretation Introduction
To determine: Reason of getting more products in the reaction with a low equilibrium constant.
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For each reaction below, decide if the first stable organic product that forms in solution will create a new CC bond, and check
the appropriate box.
Next, for each reaction to which you answered "Yes" to in the table, draw this product in the drawing area below.
Note for advanced students: for this problem, don't worry if you think this product will continue to react under the current conditions
- just focus on the first stable product you expect to form in solution.
?
NH2
MgBr
Will the first product that forms in this reaction
create a new CC bond?
○ Yes
○ No
MgBr
?
Will the first product that forms in this reaction
create a new CC bond?
O Yes
O No
Click and drag to start drawing a
structure.
:☐
G
x
c
olo
Ar
HE
Predicting
As the lead product manager at OrganometALEKS Industries, you are trying to decide if the following reaction will make a molecule
with a new C - C bond as its major product:
H₂N
O
H
1.
?
2. H3O+
If this reaction will work, draw the major organic product or products you would expect in the drawing area below. If there's more
than one major product, you can draw them in any arrangement you like. Be sure you use wedge and dash bonds if necessary, for
example to distinguish between major products with different stereochemistry.
0
If the major products of this reaction won't have a new CC bond, just check the box under the drawing area and leave it blank.
فا
Explanation
Check
Click and drag to start drawing a
structure.
Highlight the chirality (or stereogenic) center(s) in the given compound. A compound may have one or more stereogenic centers.
OH
OH
OH
OH
OH
OH
Chapter 14 Solutions
Chemistry: A Molecular Approach
Ch. 14 - Prob. 1SAQCh. 14 - Q2. The equilibrium constant for the reaction...Ch. 14 - Q3. Use the data shown here to find the...Ch. 14 - Prob. 4SAQCh. 14 - Prob. 5SAQCh. 14 - Q6. For the reaction 2 A(g) B(g), the equilibrium...Ch. 14 - Q7. Consider the reaction between iodine gas and...Ch. 14 - Prob. 8SAQCh. 14 - Prob. 9SAQCh. 14 - Prob. 10SAQ
Ch. 14 - Prob. 11SAQCh. 14 - Prob. 12SAQCh. 14 - 1. How does a developing fetus get oxygen in the...Ch. 14 - Prob. 2ECh. 14 - Prob. 3ECh. 14 - Prob. 4ECh. 14 - Prob. 5ECh. 14 - Prob. 6ECh. 14 - Prob. 7ECh. 14 - Prob. 8ECh. 14 - Prob. 9ECh. 14 - Prob. 10ECh. 14 - Prob. 11ECh. 14 - Prob. 12ECh. 14 - Prob. 13ECh. 14 - Prob. 14ECh. 14 - Prob. 15ECh. 14 - Prob. 16ECh. 14 - Prob. 17ECh. 14 - Prob. 18ECh. 14 - Prob. 19ECh. 14 - Prob. 20ECh. 14 - Prob. 21ECh. 14 - Prob. 22ECh. 14 - 23. When this reaction comes to equilibrium, will...Ch. 14 - Prob. 24ECh. 14 - 25. H2 and I2 are combined in a flask and allowed...Ch. 14 - Prob. 26ECh. 14 - Prob. 27ECh. 14 - 28. This reaction has an equilibrium constant of...Ch. 14 - 29. Consider the reactions and their respective...Ch. 14 - 30. Use the reactions and their equilibrium...Ch. 14 - 31. Calculate Kc for each reaction.
a. I2(g) 2...Ch. 14 - 32. Calculate Kp for each reaction.
a. N2O4(g) 2...Ch. 14 - 33. Write an equilibrium expression for each...Ch. 14 - 34. Find and fix the mistake in the equilibrium...Ch. 14 - 35. Consider the reaction:
CO(g) + 2 H2(g) ...Ch. 14 - 36. Consider the reaction:
NH4HS(s) NH3(g) +...Ch. 14 - 37. Consider the reaction:
N2(g) + 3 H2(g) 2...Ch. 14 - 38. Consider the following reaction:
H2(g) + I2(g)...Ch. 14 - 39. Consider the reaction:
2 NO(g) + Br2(g) 2...Ch. 14 - 40. Consider the reaction:
SO2Cl2(g) SO2(g) +...Ch. 14 - 41. For the reaction A(g) 2 B(g), a reaction...Ch. 14 - 42. For the reaction 2 A(g) B(g) + 2 C(g), a...Ch. 14 - 43. Consider the reaction:
Fe3+(aq) + SCN–(aq) ...Ch. 14 - 44. Consider the reaction:
SO2Cl2(g) SO2(g) +...Ch. 14 - 45. Consider the reaction:
H2(g) + I2(g) 2...Ch. 14 - 46. Consider the reaction:
CO(g) + 2 H2(g) ...Ch. 14 - 47. Consider the reaction:
NH4HS(s) NH3(g) +...Ch. 14 - 48. Consider the reaction:
2 H2S(g) 2 H2(g) +...Ch. 14 - 49. Silver sulfate dissolves in water according to...Ch. 14 - 50. Nitrogen dioxide dimerizes according to the...Ch. 14 - 51. Consider the reaction and the associated...Ch. 14 - 52. Consider the reaction and the associated...Ch. 14 - 53. For the reaction shown here, Kc = 0.513 at 500...Ch. 14 - 54. For the reaction shown here, Kc = 255 at 1000...Ch. 14 - 55. Consider the reaction:
NiO(s) + CO(g) Ni(s) +...Ch. 14 - 56. Consider the reaction:
CO(g) + H2O(g) CO2(g)...Ch. 14 - 57. Consider the reaction:
HC2H3O2(aq) + H2O(l) ...Ch. 14 - 58. Consider the reaction:
SO2Cl2(g) SO2(g) +...Ch. 14 - 59. Consider the reaction:
Br2(g) + Cl2(g) 2...Ch. 14 - 60. Consider the reaction:
CO(g) + H2O(g) CO2(g)...Ch. 14 - Prob. 61ECh. 14 - Prob. 62ECh. 14 - Prob. 63ECh. 14 - 64. Consider this reaction at equilibrium:
2...Ch. 14 - 65. Consider this reaction at equilibrium:
2...Ch. 14 - 66. Consider this reaction at equilibrium:
C(s) +...Ch. 14 - 67. Each reaction is allowed to come to...Ch. 14 - Prob. 68ECh. 14 - Prob. 69ECh. 14 - Prob. 70ECh. 14 - Prob. 71ECh. 14 - Prob. 72ECh. 14 - 73. Carbon monoxide replaces oxygen in oxygenated...Ch. 14 - Prob. 74ECh. 14 - Prob. 75ECh. 14 - 76. A mixture of water and graphite is heated to...Ch. 14 - 77. At 650 K, the reaction MgCO3(s) MgO(s) +...Ch. 14 - 78. A system at equilibrium contains I2(g) at a...Ch. 14 - Prob. 79ECh. 14 - Prob. 80ECh. 14 - Prob. 81ECh. 14 - Prob. 82ECh. 14 - Prob. 83ECh. 14 - Prob. 84ECh. 14 - 85. The system described by the reaction: CO(g) +...Ch. 14 - Prob. 86ECh. 14 - 87. At 70 K, CCl4 decomposes to carbon and...Ch. 14 - 88. The equilibrium constant for the reaction...Ch. 14 - 89. A sample of CaCO3(s) is introduced into a...Ch. 14 - Prob. 90ECh. 14 - Prob. 91ECh. 14 - Prob. 92ECh. 14 - Prob. 93ECh. 14 - Prob. 94ECh. 14 - Prob. 95ECh. 14 - Prob. 96ECh. 14 - Prob. 97ECh. 14 - 98. When N2O5(g) is heated, it dissociates into...Ch. 14 - 99. A sample of SO3 is introduced into an...Ch. 14 - 100. A reaction A(g) B(g) has an equilibrium...Ch. 14 - Prob. 101ECh. 14 - Prob. 102ECh. 14 - Prob. 103ECh. 14 - Prob. 104E
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