Organic Chemistry, 12e Study Guide/Student Solutions Manual
12th Edition
ISBN: 9781119077329
Author: T. W. Graham Solomons, Craig B. Fryhle, Scott A. Snyder
Publisher: WILEY
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Chapter H, Problem 8PP
Interpretation Introduction
Interpretation:
The structure of heroin is to be determined, which formed when morphine reacts with two moles of acetic anhydride.
Concept Introduction:
>Morphine is found naturally in a number of plants and animals. It acts directly on the central nervous system to decrease the feeling of pain. It can be taken for both acute pain and chronic pain.
>Alkaloids are a huge and complex group of cyclic compounds that contain N-atom. Morphine is an example of alkaloid.
>Acetic anhydride is an acetylating agent.
>The reaction of morphine with acetic anhydride as the acetylating agent leads to the formation of 3-acetylmorphine, which on further treatment with acetic anhydride, leads to the formation of heroin.
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Г
C-RSA CHROMATOPAC CH=1
DATA 1: @CHRM1.C00
ATTEN=10 SPEED= 10.0
0.0 b.092
0.797
1.088
1.813
C-RSA CHROMATOPAC CH=1 Report No. =13
** CALCULATION REPORT **
DATA=1: @CHRM1.000 11/03/05 08:09:52
CH PKNO
TIME
1
2
0.797
3
1.088
4
1.813
AREA
1508566
4625442
2180060
HEIGHT
207739
701206 V
287554 V
MK IDNO
CONC
NAME
18.1447
55.6339
26.2213
TOTAL
8314067 1196500
100
C-R8A CHROMATOPAC CH=1
DATA 1: @CHRM1.C00
ATTEN=10 SPEED= 10.0
0. 0
087
337.
0.841
1.150
C-R8A CHROMATOPAC CH=1 Report No. =14
DATA=1: @CHRM1.000 11/03/05 08:12:40
** CALCULATION REPORT **
CH PKNO
TIME
AREA
1
3 0.841
1099933
41.15
4039778
HEIGHT MK IDNO
170372
649997¯¯¯
CONC
NAME
21.4007
78.5993
TOTAL
5139711 820369
100
3
C-R8A CHROMATOPAC
CH=1
DATA 1: @CHRM1.C00
ATTEN=10 SPEED= 10.0
0.100
0:652
5.856
3
1.165
C-RSA CHROMATOPAC CH-1 Report No. =15
DATA=1: @CHRM1.000 11/03/05 08:15:26
** CALCULATION REPORT **
CH PKNO TIME
AREA
HEIGHT MK IDNO CONC
NAME
1 3 3 0.856
4
1.165
TOTAL
1253386
4838738
175481
708024 V
20.5739
79.4261
6092124…
Chapter H Solutions
Organic Chemistry, 12e Study Guide/Student Solutions Manual
Ch. H - Prob. 1PPCh. H - Prob. 2PPCh. H - Prob. 3PPCh. H - Practice Problem H.4
In 1891 G. Merling...Ch. H - Practice Problem H.5
Many alkaloids appear to be...Ch. H - Practice Problem H.6 Papaverine has been...Ch. H - Practice Problem H.7
One of the important steps in...Ch. H - Prob. 8PPCh. H - Practice Problem H.9 Gramine has been synthesized...
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