ORGANIC CHEM. VOL.1+2-W/WILEYPLUS
12th Edition
ISBN: 9781119304241
Author: Solomons
Publisher: WILEY C
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Chapter H, Problem 7PP
Practice Problem H.7
One of the important steps in Gates’ synthesis of morphine involved the following transformation:
Suggest how this step was accomplished.
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Students have asked these similar questions
Provide correct IUPAC names for each of the following compounds.
NOT
a.
b.
C.
2003
H,N-
CH3
NH2
CH
. Consider the reaction below to answer the following questions.
OH
1. NaH
2. CH3I, ether
O-CH3
A. Write the complete stepwise mechanism for the reaction. Show all intermediate structures and all
electron flow with arrows.
B. Mechanistically, the Williamson ether synthesis outlined above is:
ن نخنه
a. an El process
b.
an SN1 process
C.
an E2 process
d.
an SN2 process
C. Alternatively, cyclopentyl methyl ether may be synthesized from cyclopentene.
synthesis of cyclopentyl methyl ether from cyclopentene.
Outline a
Q2. A good synthesis of
(CH3)3C-
would be:
A)
B)
CSI3
0
CH3CC1
(CH3) 3CC1
Benzene
AlCl3
AlCl3
(CH3)3CC1
CH3CC1
Benzene
C)
AlCl3
0
AlCl3
CH3CC1
(CH3) 2C-CH2
Bonzone
AlCl3
HF
D) More than one of these
E) None of these
Chapter H Solutions
ORGANIC CHEM. VOL.1+2-W/WILEYPLUS
Ch. H - Prob. 1PPCh. H - Prob. 2PPCh. H - Prob. 3PPCh. H - Practice Problem H.4
In 1891 G. Merling...Ch. H - Practice Problem H.5
Many alkaloids appear to be...Ch. H - Practice Problem H.6 Papaverine has been...Ch. H - Practice Problem H.7
One of the important steps in...Ch. H - Prob. 8PPCh. H - Practice Problem H.9 Gramine has been synthesized...
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