CHEMICAL PRINCIPLES PKG W/SAPLING
7th Edition
ISBN: 9781319086411
Author: ATKINS
Publisher: MAC HIGHER
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Chapter F, Problem M.1E
Interpretation Introduction
Interpretation:
Percentage yield of hydrazine has to be calculated.
Concept Introduction:
The yield that can be obtained to the maximum from the given quantity of the reactant is known as theoretical yield. This does not consider the side reactions or impurities in the product formation. Percentage yield is the yield of the product that is formed expressed in terms of percentage. This can be given by the equation given below;
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Consider the following nucleophilic substitution reaction. The compound listed above the arrow is the solvent for the reaction. If nothing is listed over the arrow,
then the nucleophile is also the solvent for the reaction.
Part 1 of 2
Br
CH,CN
+ I¯
What is the correct mechanism for the reaction? Select the single best answer.
@SN2
○ SN 1
Part: 1/2
Part 2 of 2
Draw the products for the reaction. Include both the major organic product and the inorganic product. If more than one stereoisomer is possible, draw
only one stereoisomer. Include stereochemistry where relevant.
Click and drag to start drawing a
structure.
X
હૈ
20.33 Think-Pair-Share
(a) Rank the following dienes and dienophiles in order of increasing reactivity in the
Diels-Alder reaction.
(i)
CO₂Et
(ii)
COEt
||
CO₂Et
MeO
MeO
(b) Draw the product that results from the most reactive diene and most reactive
dienophile shown in part (a).
(c) Draw a depiction of the orbital overlap involved in the pericyclic reaction that oc-
curs between the diene and dienophile in part (b).
(d) Is the major product formed in part (b) the endo or exo configuration? Explain
your reasoning.
20.40 The following compound undergoes an intramolecular Diels-Alder reaction to give a
tricyclic product. Propose a structural formula for the product.
CN
heat
An intramolecular
Diels-Alder adduct
Chapter F Solutions
CHEMICAL PRINCIPLES PKG W/SAPLING
Ch. F - Prob. A.1ASTCh. F - Prob. A.1BSTCh. F - Prob. A.2ASTCh. F - Prob. A.2BSTCh. F - Prob. A.3ASTCh. F - Prob. A.3BSTCh. F - Prob. A.4ASTCh. F - Prob. A.4BSTCh. F - Prob. A.5ASTCh. F - Prob. A.5BST
Ch. F - Prob. A.1ECh. F - Prob. A.2ECh. F - Prob. A.3ECh. F - Prob. A.4ECh. F - Prob. A.5ECh. F - Prob. A.6ECh. F - Prob. A.7ECh. F - Prob. A.8ECh. F - Prob. A.9ECh. F - Prob. A.10ECh. F - Prob. A.11ECh. F - Prob. A.12ECh. F - Prob. A.13ECh. F - Prob. A.14ECh. F - Prob. A.15ECh. F - Prob. A.16ECh. F - Prob. A.17ECh. F - Prob. A.18ECh. F - Prob. A.19ECh. F - Prob. A.20ECh. F - Prob. A.21ECh. F - Prob. A.22ECh. F - Prob. A.23ECh. F - Prob. A.24ECh. F - Prob. A.25ECh. F - Prob. A.26ECh. F - Prob. A.27ECh. F - Prob. A.28ECh. F - Prob. A.29ECh. F - Prob. A.30ECh. F - Prob. A.31ECh. F - Prob. A.32ECh. F - Prob. A.33ECh. F - Prob. A.34ECh. F - Prob. A.35ECh. F - Prob. A.36ECh. F - Prob. A.37ECh. F - Prob. A.38ECh. F - Prob. A.39ECh. F - Prob. A.40ECh. F - Prob. A.41ECh. F - Prob. A.42ECh. F - Prob. B.1ASTCh. F - Prob. B.1BSTCh. F - Prob. B.2ASTCh. F - Prob. B.2BSTCh. F - Prob. B.3ASTCh. F - Prob. B.3BSTCh. F - Prob. B.1ECh. F - Prob. B.2ECh. F - Prob. B.3ECh. F - Prob. B.4ECh. F - Prob. B.5ECh. F - Prob. B.6ECh. F - Prob. B.7ECh. F - Prob. B.8ECh. F - Prob. B.9ECh. F - Prob. B.10ECh. F - Prob. B.11ECh. F - Prob. B.12ECh. F - Prob. B.13ECh. F - Prob. B.14ECh. F - Prob. B.15ECh. F - Prob. B.16ECh. F - Prob. B.17ECh. F - Prob. B.18ECh. F - Prob. B.19ECh. F - Prob. B.20ECh. F - Prob. B.21ECh. F - Prob. B.22ECh. F - Prob. C.1ASTCh. F - Prob. C.1BSTCh. F - Prob. C.2ASTCh. F - Prob. C.2BSTCh. F - Prob. C.1ECh. F - Prob. C.2ECh. F - Prob. C.3ECh. F - Prob. C.4ECh. F - Prob. C.5ECh. F - Prob. C.6ECh. F - Prob. C.7ECh. F - Prob. C.8ECh. F - Prob. C.9ECh. F - Prob. C.10ECh. F - Prob. C.11ECh. F - Prob. C.12ECh. F - Prob. C.13ECh. F - Prob. C.14ECh. F - Prob. C.15ECh. F - Prob. C.16ECh. F - Prob. C.17ECh. F - Prob. C.18ECh. F - Prob. C.19ECh. F - Prob. C.20ECh. F - Prob. C.21ECh. F - Prob. C.22ECh. F - Prob. D.1ASTCh. F - Prob. D.1BSTCh. F - Prob. D.2ASTCh. F - Prob. D.2BSTCh. F - Prob. D.3ASTCh. F - Prob. D.3BSTCh. F - Prob. D.4ASTCh. F - Prob. D.4BSTCh. F - Prob. D.5ASTCh. F - Prob. D.5BSTCh. F - Prob. D.1ECh. F - Prob. D.2ECh. F - Prob. D.3ECh. F - Prob. D.4ECh. F - Prob. D.5ECh. F - Prob. D.6ECh. F - Prob. D.7ECh. F - Prob. D.8ECh. F - Prob. D.9ECh. F - Prob. D.10ECh. F - Prob. D.11ECh. F - Prob. D.12ECh. F - Prob. D.13ECh. F - Prob. D.14ECh. F - Prob. D.15ECh. F - Prob. D.16ECh. F - Prob. D.17ECh. F - Prob. D.18ECh. F - Prob. D.19ECh. F - Prob. D.20ECh. F - Prob. D.21ECh. F - Prob. D.22ECh. F - Prob. D.23ECh. F - Prob. D.24ECh. F - Prob. D.25ECh. F - Prob. D.26ECh. F - Prob. D.27ECh. F - Prob. D.28ECh. F - Prob. D.29ECh. F - Prob. D.30ECh. F - Prob. D.31ECh. F - Prob. D.32ECh. F - Prob. D.33ECh. F - Prob. D.34ECh. F - Prob. D.35ECh. F - Prob. D.36ECh. F - Prob. E.1ASTCh. F - Prob. E.1BSTCh. F - Prob. E.2ASTCh. F - Prob. E.2BSTCh. F - Prob. E.3ASTCh. F - Prob. E.3BSTCh. F - Prob. E.4ASTCh. F - Prob. E.4BSTCh. F - Prob. E.5ASTCh. F - Prob. E.5BSTCh. F - Prob. E.6ASTCh. F - Prob. E.6BSTCh. F - Prob. E.1ECh. F - Prob. E.2ECh. F - Prob. E.3ECh. F - Prob. E.4ECh. F - Prob. E.5ECh. F - Prob. E.6ECh. F - Prob. E.7ECh. F - Prob. E.8ECh. F - Prob. E.9ECh. F - Prob. E.10ECh. F - Prob. E.11ECh. F - Prob. E.12ECh. F - Prob. E.13ECh. F - Prob. E.14ECh. F - Prob. E.15ECh. F - Prob. E.16ECh. F - Prob. E.17ECh. F - Prob. E.18ECh. F - Prob. E.19ECh. F - Prob. E.20ECh. F - Prob. E.21ECh. F - Prob. E.22ECh. F - Prob. E.23ECh. F - Prob. E.24ECh. F - Prob. E.25ECh. F - Prob. E.26ECh. F - Prob. E.27ECh. F - Prob. E.28ECh. F - Prob. E.29ECh. F - Prob. E.30ECh. F - Prob. E.31ECh. F - Prob. E.32ECh. F - Prob. E.33ECh. F - Prob. E.34ECh. F - Prob. F.1ASTCh. F - Prob. F.1BSTCh. F - Prob. F.2ASTCh. F - Prob. F.2BSTCh. F - Prob. F.3ASTCh. F - Prob. F.3BSTCh. F - Prob. F.4ASTCh. F - Prob. F.4BSTCh. F - Prob. F.1ECh. F - Prob. F.2ECh. F - Prob. F.3ECh. F - Prob. F.4ECh. F - Prob. F.5ECh. F - Prob. F.6ECh. F - Prob. F.7ECh. F - Prob. F.8ECh. F - Prob. F.9ECh. F - Prob. F.10ECh. F - Prob. F.11ECh. F - Prob. F.12ECh. F - Prob. F.13ECh. F - Prob. F.14ECh. F - Prob. F.15ECh. F - Prob. F.16ECh. F - Prob. F.17ECh. F - Prob. F.18ECh. F - Prob. F.19ECh. F - Prob. F.20ECh. F - Prob. F.21ECh. F - Prob. F.22ECh. F - Prob. F.23ECh. F - Prob. F.24ECh. F - Prob. F.25ECh. F - Prob. F.26ECh. F - Prob. F.27ECh. F - Prob. F.28ECh. F - Prob. G.1ASTCh. F - Prob. G.1BSTCh. F - Prob. G.2ASTCh. F - Prob. G.2BSTCh. F - Prob. G.3ASTCh. F - Prob. G.3BSTCh. F - Prob. G.4ASTCh. F - Prob. G.4BSTCh. F - Prob. G.1ECh. F - Prob. G.2ECh. F - Prob. G.3ECh. F - Prob. G.4ECh. F - Prob. G.5ECh. F - Prob. G.6ECh. F - Prob. G.7ECh. F - Prob. G.8ECh. F - Prob. G.9ECh. F - Prob. G.10ECh. F - Prob. G.11ECh. F - Prob. G.12ECh. F - Prob. G.13ECh. F - Prob. G.14ECh. F - Prob. G.15ECh. F - Prob. G.16ECh. F - Prob. G.17ECh. F - Prob. G.18ECh. F - Prob. G.19ECh. F - Prob. G.20ECh. F - Prob. G.21ECh. F - Prob. G.22ECh. F - Prob. G.23ECh. F - Prob. G.24ECh. F - Prob. G.25ECh. F - Prob. G.27ECh. F - Prob. G.28ECh. F - Prob. G.30ECh. F - Prob. H.1ASTCh. F - Prob. H.1BSTCh. F - Prob. H.1ECh. F - Prob. H.2ECh. F - Prob. H.3ECh. F - Prob. H.4ECh. F - Prob. H.5ECh. F - Prob. H.6ECh. F - Prob. H.7ECh. F - Prob. H.8ECh. F - Prob. H.9ECh. F - Prob. H.10ECh. F - Prob. H.11ECh. F - Prob. H.12ECh. F - Prob. H.13ECh. F - Prob. H.14ECh. F - Prob. H.15ECh. F - Prob. H.16ECh. F - Prob. H.17ECh. F - Prob. H.18ECh. F - Prob. H.19ECh. F - Prob. H.20ECh. F - Prob. H.21ECh. F - Prob. H.22ECh. F - Prob. H.23ECh. F - Prob. H.24ECh. F - Prob. H.25ECh. F - Prob. H.26ECh. F - Prob. I.1ASTCh. F - Prob. I.1BSTCh. F - Prob. I.2ASTCh. F - Prob. I.2BSTCh. F - Prob. I.3ASTCh. F - Prob. I.3BSTCh. F - Prob. I.1ECh. F - Prob. I.2ECh. F - Prob. I.3ECh. F - Prob. I.4ECh. F - Prob. I.5ECh. F - Prob. I.6ECh. F - Prob. I.7ECh. F - Prob. I.8ECh. F - Prob. I.9ECh. F - Prob. I.10ECh. F - Prob. I.11ECh. F - Prob. I.12ECh. F - Prob. I.13ECh. F - Prob. I.14ECh. F - Prob. I.15ECh. F - Prob. I.16ECh. F - Prob. I.17ECh. F - Prob. I.18ECh. F - Prob. I.19ECh. F - Prob. I.20ECh. F - Prob. I.21ECh. F - Prob. I.22ECh. F - Prob. I.23ECh. F - Prob. I.24ECh. F - Prob. I.25ECh. F - Prob. I.26ECh. F - Prob. J.1ASTCh. F - Prob. J.1BSTCh. F - Prob. J.2ASTCh. F - Prob. J.2BSTCh. F - Prob. J.1ECh. F - Prob. J.2ECh. F - Prob. J.3ECh. F - Prob. J.4ECh. F - Prob. J.5ECh. F - Prob. J.6ECh. F - Prob. J.7ECh. F - Prob. J.8ECh. F - Prob. J.9ECh. F - Prob. J.10ECh. F - Prob. J.11ECh. F - Prob. J.12ECh. F - Prob. J.13ECh. F - Prob. J.14ECh. F - Prob. J.15ECh. F - Prob. J.16ECh. F - Prob. J.17ECh. F - Prob. J.18ECh. F - Prob. J.19ECh. F - Prob. J.20ECh. F - Prob. J.21ECh. F - Prob. J.22ECh. F - Prob. J.23ECh. F - Prob. J.24ECh. F - Prob. K.1ASTCh. F - Prob. K.1BSTCh. F - Prob. K.2ASTCh. F - Prob. K.2BSTCh. F - Prob. K.3ASTCh. F - Prob. K.3BSTCh. F - Prob. K.4ASTCh. F - Prob. K.4BSTCh. F - Prob. K.5ASTCh. F - Prob. K.5BSTCh. F - Prob. K.1ECh. F - Prob. K.2ECh. F - Prob. K.3ECh. F - Prob. K.4ECh. F - Prob. K.5ECh. F - Prob. K.6ECh. F - Prob. K.7ECh. F - Prob. K.8ECh. F - Prob. K.9ECh. F - Prob. K.10ECh. F - Prob. K.11ECh. F - Prob. K.12ECh. F - Prob. K.13ECh. F - Prob. K.14ECh. F - Prob. K.15ECh. F - Prob. K.16ECh. F - Prob. K.17ECh. F - Prob. K.18ECh. F - Prob. K.19ECh. F - Prob. K.20ECh. F - Prob. K.21ECh. F - Prob. K.22ECh. F - Prob. K.23ECh. F - Prob. K.24ECh. F - Prob. K.25ECh. F - Prob. K.26ECh. F - Prob. L.1ASTCh. F - Prob. L.1BSTCh. F - Prob. L.2ASTCh. F - Prob. L.2BSTCh. F - Prob. L.3ASTCh. F - Prob. L.3BSTCh. F - Prob. L.1ECh. F - Prob. L.2ECh. F - Prob. L.3ECh. F - Prob. L.4ECh. F - Prob. L.5ECh. F - Prob. L.6ECh. F - Prob. L.7ECh. F - Prob. L.8ECh. F - Prob. L.9ECh. F - Prob. L.10ECh. F - Prob. L.11ECh. F - Prob. L.12ECh. F - Prob. L.13ECh. F - Prob. L.14ECh. F - Prob. L.15ECh. F - Prob. L.16ECh. F - Prob. L.17ECh. F - Prob. L.18ECh. F - Prob. L.19ECh. F - Prob. L.20ECh. F - Prob. L.21ECh. F - Prob. L.22ECh. F - Prob. L.23ECh. F - Prob. L.24ECh. F - Prob. L.25ECh. F - Prob. L.29ECh. F - Prob. L.30ECh. F - Prob. L.31ECh. F - Prob. L.32ECh. F - Prob. L.33ECh. F - Prob. L.34ECh. F - Prob. L.35ECh. F - Prob. L.37ECh. F - Prob. L.38ECh. F - Prob. L.39ECh. F - Prob. L.40ECh. F - Prob. L.41ECh. F - Prob. L.42ECh. F - Prob. M.1ASTCh. F - Prob. M.1BSTCh. F - Prob. M.2ASTCh. F - Prob. M.2BSTCh. F - Prob. M.3ASTCh. F - Prob. M.3BSTCh. F - Prob. M.4ASTCh. F - Prob. M.4BSTCh. F - Prob. M.1ECh. F - Prob. M.2ECh. F - Prob. M.3ECh. F - Prob. M.4ECh. F - Prob. M.5ECh. F - Prob. M.6ECh. F - Prob. M.7ECh. F - Prob. M.8ECh. F - Prob. M.9ECh. F - Prob. M.10ECh. F - Prob. M.11ECh. F - Prob. M.12ECh. F - Prob. M.13ECh. F - Prob. M.14ECh. F - Prob. M.15ECh. F - Prob. M.16ECh. F - Prob. M.17ECh. F - Prob. M.18ECh. F - Prob. M.19ECh. F - Prob. M.20ECh. F - Prob. M.21ECh. F - Prob. M.22ECh. F - Prob. M.23ECh. F - Prob. M.25ECh. F - Prob. M.26ECh. F - Prob. M.27ECh. F - Prob. M.28E
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