ORGANIC CHEMISTRY-WILEYPLUS ACCESS PKG.
ORGANIC CHEMISTRY-WILEYPLUS ACCESS PKG.
12th Edition
ISBN: 9781119766919
Author: Solomons
Publisher: WILEY
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Chapter F, Problem 4PP
Interpretation Introduction

Interpretation:

The compound British Anti – Lewisite (BAL) is to be synthesised from allyl alcohol.

Concept introduction:

The compound British Anti – Lewisite (BAL) is used as inorganic mercury, which is effective in protecting the kidney from ORGANIC CHEMISTRY-WILEYPLUS ACCESS PKG., Chapter F, Problem 4PP , additional homework tip  1. In BAL, both the thiol groups ORGANIC CHEMISTRY-WILEYPLUS ACCESS PKG., Chapter F, Problem 4PP , additional homework tip  2 lose hydrogen and binds with the ORGANIC CHEMISTRY-WILEYPLUS ACCESS PKG., Chapter F, Problem 4PP , additional homework tip  3.

Addition of bromine across the double bond is done via electrophilic addition reaction. This can be shown as follows:

ORGANIC CHEMISTRY-WILEYPLUS ACCESS PKG., Chapter F, Problem 4PP , additional homework tip  4

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3. Titanium(III) chloride can be used to catalyze the polymerization of ethylene. It is prepared by hydrogen reduction of Titanium(IV) chloride. Reaction of hydrogen gas with titanium(IV) chloride gas produces solid titanium(III) chloride and hydrogen chloride gas. (a) Write a BALANCED chemical reaction for the preparation of titanium(III) chloride (b) A 250 L reaction vessel at 325°C is filled with hydrogen gas to a pressure of 1.3 atm. Titanium(IV) chloride is then added to bring the total pressure to 3.00 atm. How many grams of titanium(III) chloride will be produced after completion of the reaction? (c) What will be the pressure of the resulting hydrogen chloride gas that is also produced?
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