PREPARING F/YOUR ACS EXAM IN GEN CHEM
18th Edition
ISBN: 9781732776401
Author: EUBANKS
Publisher: American Chemical Society
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Chapter EQ, Problem 25PQ
Interpretation Introduction
Interpretation:
The addition of solid
Concept introduction:
Le Chatelier's principle:
It states that if a system in equilibrium gets disturbed due to modification of concentration, temperature, volume, and pressure, then it reset to counteract the effect of disturbance.
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Balance the following equations
Synthesis
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302
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+
+
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N2
↑
6.
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+
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+
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10.
11.
AR
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+
Cl₂
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↑
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12.
Al
+
Br₂
13.
Fe
+
F2
↑
14.
Sn
+
15.
Sb
+
16.
Ca
+
17.
Ba
+
02
↑
↑
↑
P4010 Com
BiCl, Syn
NH3 Syn
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Agl Syn
Pbo Com
AlBr, yn
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Considering the important roles of biothiols in lysosomes of live organisms, and unique photophysical / photochemical properties of ruthenium(II) complexes, a novel ruthenium(II) complex, Ru-2, has been developed as a molecular probe for phosphorescence and time-gated luminescence assay of biothiols in human sera, live cells, and in vivo. Ru-2 is weakly luminescent due to the effective photoinduced electron transfer (PET) from Ru(II) luminophore to electron acceptor, 2,4-dinitrobenzene-sulfonyl (DNBS). In the presence of biothiols, such as glutathione (GSH), cysteine (Cys), and homocysteine (Hcy), the emission of Ru-2 solution was switched ON, as a result of the cleavage of quencher to form the product, Ru-1. Ru-2 showed high selectivity and sensitivity for the detection of biothiols under physiological conditions, with detection limits of 62 nM, 146 nM, and 115 nM for GSH, Cys, and Hcy, respectively. The emission lifetimes of Ru-1 and Ru-2 were measured to be 405 and 474 ns,…
Chapter EQ Solutions
PREPARING F/YOUR ACS EXAM IN GEN CHEM
Ch. EQ - Prob. 1PQCh. EQ - Prob. 2PQCh. EQ - Prob. 3PQCh. EQ - Prob. 4PQCh. EQ - Prob. 5PQCh. EQ - Prob. 6PQCh. EQ - Prob. 7PQCh. EQ - Prob. 8PQCh. EQ - Prob. 9PQCh. EQ - Prob. 10PQ
Ch. EQ - Prob. 11PQCh. EQ - Prob. 12PQCh. EQ - Prob. 13PQCh. EQ - Prob. 14PQCh. EQ - Prob. 15PQCh. EQ - Prob. 16PQCh. EQ - Prob. 17PQCh. EQ - Prob. 18PQCh. EQ - Prob. 19PQCh. EQ - Prob. 20PQCh. EQ - Prob. 21PQCh. EQ - Prob. 22PQCh. EQ - Prob. 23PQCh. EQ - Prob. 24PQCh. EQ - Prob. 25PQCh. EQ - Prob. 26PQCh. EQ - Prob. 27PQCh. EQ - Prob. 28PQCh. EQ - Prob. 29PQCh. EQ - Prob. 30PQ
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