PREPARING F/YOUR ACS EXAM IN GEN CHEM
PREPARING F/YOUR ACS EXAM IN GEN CHEM
18th Edition
ISBN: 9781732776401
Author: EUBANKS
Publisher: American Chemical Society
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Chapter EN, Problem 28PQ
Interpretation Introduction

Interpretation:

The signs of ΔH and ΔS for process of dissolution of NH4NO3 in water at 25°C that result into decrease in temperature of solution have to be determined.

Concept Introduction:

The formula that determine spontaneity of the reaction is as follows:

  ΔG=ΔHTΔS

Here,

  ΔG is change in the Gibbs free energy.

  ΔH is change in the enthalpy.

  ΔS is change in entropy.

The table that represents the three state functions is as follows:

ΔHΔSΔGNature of reaction+SpontaneousSpontaneous at low temperature++Spontaneousat high temperature++Non-spontaneous

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Using the conditions of spontaneity to deduce the signs of AH and AS Use the observations about each chemical reaction in the table below to decide the sign (positive or negative) of the reaction enthalpy AH and reaction entropy AS. Note: if you have not been given enough information to decide a sign, select the "unknown" option. reaction observations conclusions A This reaction is always spontaneous, but proceeds slower at temperatures above 120. °C. ΔΗ is (pick one) AS is (pick one) ΔΗ is (pick one) B This reaction is spontaneous except above 117. °C. AS is (pick one) ΔΗ is (pick one) This reaction is slower below 20. °C than C above. AS is |(pick one) ? 18 Ar 1
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