ORG CHEM W/ EBOOK & SW5 + STUDY GUIDE
ORG CHEM W/ EBOOK & SW5 + STUDY GUIDE
2nd Edition
ISBN: 9780393666144
Author: KARTY
Publisher: NORTON
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Chapter E, Problem E.3P
Interpretation Introduction

(a)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

To write the IUPAC name, first, it is important to determine the highest-priority functional group present that requires a suffix referring to Table E-1. For a molecule that contains a NH2 as the highest priority group, the amine suffix is added to the IUPAC name of the root chain. The next step is to number the main chain or ring such that carbon atoms involving the highest-priority functional group receive the lowest possible numbers. The locator number for the highest-priority functional group is written immediately before the suffix, except when redundant. All other functional groups in the molecule are treated as substituents and appear in the name as a prefix. Prefixes such as ‘di’, ‘tri’, ‘tetra’… etc. are used to indicate the number of identical substituents attached. The substituents are named in the alphabetical order.

Interpretation Introduction

(b)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

To write the IUPAC name, first it is important to determine the highest-priority functional group present that requires a suffix referring to Table E-1. For a molecule that contains a NH2 as the highest priority group, the amine suffix is added to the IUPAC name of the root chain. The next step is to number the main chain or ring such that carbon atoms involving the highest-priority functional group receives the lowest possible numbers. The locator number for the highest-priority functional group is written immediately before the suffix, except when redundant. All other functional groups in the molecule are treated as substituents and appear in the name as a prefix. Prefixes such as ‘di’, ‘tri’, ‘tetra’… etc. are used to indicate the number of identical substituents attached. The substituents are named in the alphabetical order.

Interpretation Introduction

(c)

Interpretation:

The IUPAC name of the given molecule is to be written.

Concept introduction:

To write the IUPAC name, first it is important to determine the highest-priority functional group present that requires a suffix referring to Table E-1. For a molecule that contains a NH2 as the highest priority group, the amine suffix is added to the IUPAC name of the root chain. The next step is to number the main chain or ring such that carbon atoms involving the highest-priority functional group receives the lowest possible numbers. The locator number for the highest-priority functional group is written immediately before the suffix, except when redundant. All other functional groups in the molecule are treated as substituents and appear in the name as a prefix. Prefixes such as ‘di’, ‘tri’, ‘tetra’… etc. are used to indicate the number of identical substituents attached. The substituents are named in the alphabetical order.

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2. 200 LOD For an unknown compound with a molecular ion of 101 m/z: a. Use the molecular ion to propose at least two molecular formulas. (show your work) b. What is the DU for each of your possible formulas? (show your work) C. Solve the structure and assign each of the following spectra. 8 6 4 2 (ppm) 150 100 50 ō (ppm) 4000 3000 2000 1500 1000 500 HAVENUMBERI-11
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