Chemistry: Structure and Properties (2nd Edition)
2nd Edition
ISBN: 9780134293936
Author: Nivaldo J. Tro
Publisher: PEARSON
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Chapter E, Problem 108E
Interpretation Introduction
To determine:
Most dense substance, without calculations
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13. (11pts total) Consider the arrows pointing at three different carbon-carbon bonds in the
molecule depicted below.
Bond B
Bond A
Bond C
a. (2pts) Which bond between A-C is weakest? Which is strongest? Place answers in
appropriate boxes.
Weakest
Bond
Strongest
Bond
b. (4pts) Consider the relative stability of all cleavage products that form when bonds A,
B, AND C are homolytically cleaved/broken. Hint: cleavage products of bonds A, B,
and C are all carbon radicals.
i. Which ONE cleavage product is the most stable? A condensed or bond line
representation is fine.
ii. Which ONE cleavage product is the least stable? A condensed or bond line
representation is fine.
c. (5pts) Use principles discussed in lecture, supported by relevant structures, to
succinctly explain the why your part b (i) radical is more stable than your part b(ii)
radical. Written explanation can be no more than one-two succinct sentence(s)!
Google
Print Last Name, First Name Initial
Statifically more chances to abstract one of these 6H
11. (10pts total) Consider the radical chlorination of 1,3-diethylcyclohexane depicted below. 4
4th total
• 6H total
래
• 4H total
21 total
ZH
2H
Statistical
H < 3° C-H weakest
-
product
abstraction here
bund
leads to thermo favored
a) (6pts) How many unique mono-chlorinated products can be formed and what are the
structures for the thermodynamically and statistically favored products?
Product
6
Number of Unique
Mono-Chlorinated Products
Thermodynamically
Favored Product
Statistically
Favored Product
b) (4pts) Draw the arrow pushing mechanism for the FIRST propagation step (p-1) for the
formation of the thermodynamically favored product. Only draw the p-1 step. You do
not need to include lone pairs of electrons. No enthalpy calculation necessary
H
H-Cl
Waterfox
10. (5pts) Provide the complete arrow pushing mechanism for the chemical transformation →
depicted below
Use proper curved arrow notation that explicitly illustrates all bonds being broken, and
all bonds formed in the transformation.
Also, be sure to include all lone pairs and formal charges on all atoms involved in the
flow of electrons.
CH3O
II
HA
H
CH3O-H
H
①
Chapter E Solutions
Chemistry: Structure and Properties (2nd Edition)
Ch. E - What are the standard SI base units of length,...Ch. E - What are the three common temperature scales? Does...Ch. E - What are prefix multipliers? List some examples.Ch. E - What is a derived unit? List an example.Ch. E - Explain the relationship between the reliability...Ch. E - What is the significance of the number of digits...Ch. E - Explain the difference between precision and...Ch. E - Prob. 8ECh. E - When multiplying or dividing measured quantities,...Ch. E - When adding or subtracting measured quantities,...
Ch. E - Explain the difference between density and mass.Ch. E - Explain the difference between intensive and...Ch. E - Prob. 13ECh. E - Prob. 14ECh. E - Prob. 15ECh. E - Prob. 16ECh. E - What is dimensional analysis?Ch. E - How should units be treated in calculations?Ch. E - Convert each temperature. a. 32 °F to °C...Ch. E - Convert each temperature. a. 212 °F to °C...Ch. E - The coldest temperature ever measured in the...Ch. E - Prob. 22ECh. E - Use the prefix multipliers to express each...Ch. E - Use prefix multipliers to express each measurement...Ch. E - Use scientific notation to express each quantity...Ch. E - Use scientific notation to express each quantity...Ch. E - Complete the table.Ch. E - Complete the table.Ch. E - Express the quantity 254,998 m in each unit. a. km...Ch. E - Express the quantity 556.2 × 10-12 s in each unit....Ch. E - How many 1-cm squares does it take to construct a...Ch. E - How many 1-cm cubes does it take to construct a...Ch. E - Convert 15.0 L to each unit. a.mL b. cm3 c. gal d....Ch. E - Convert 4.58 x 103 cm3 to each unit. a. L b. mL c....Ch. E - A ruler used to measure a penny has markings every...Ch. E - A scale used to weigh produce at a market has...Ch. E - Read each measurement to the correct number of...Ch. E - Read each measurement to the correct number of...Ch. E - For each number, underline the zeroes that are...Ch. E - For each number, underline the zeroes that are...Ch. E - How many significant figures are in each number?...Ch. E - How many significant figures are in each number?...Ch. E - Which numbers are exact (and therefore have an...Ch. E - Indicate the number of significant figures in each...Ch. E - Round each number to four significant figures. a....Ch. E - Round each number to three significant figures. a....Ch. E - Calculate to the correct number of significant...Ch. E - Calculate to the correct number of significant...Ch. E - Calculate to the correct number of significant...Ch. E - Calculate to the correct number of significant...Ch. E - Calculate to the correct number of significant...Ch. E - Calculate to the correct number of significant...Ch. E - A new penny has a mass of 2.49 g and a volume of...Ch. E - A titanium bicycle frame displaces 0.314 L of...Ch. E - Glycerol is a syrupy liquid used in cosmetics and...Ch. E - An allegedly gold nugget is tested to determine...Ch. E - Ethylene glycol (antifreeze) has a density of 1.11...Ch. E - Prob. 58ECh. E - A small airplane takes on 245 L of fuel, If the...Ch. E - Human fat has a density of 0.918 g/cm3. How much...Ch. E - Perform each unit conversion. a. 27.8 L to cm3 b....Ch. E - Prob. 62ECh. E - Prob. 63ECh. E - Prob. 64ECh. E - A runner wants to run 10.0 km. She knows that her...Ch. E - Prob. 66ECh. E - A European automobile has a gas mileage of 17...Ch. E - A gas can holds 5.0 gallons of gasoline. Express...Ch. E - A house has an area of 195 m2. What is its area...Ch. E - Prob. 70ECh. E - The average U.S. farm occupies 435 acres. (1 acre...Ch. E - Total U.S. farmland occupies 954 million acres....Ch. E - An acetaminophen suspension for infants contains...Ch. E - An ibuprofen suspension for infants contains 100...Ch. E - Convert between energy units. a. 534 kWh to J b....Ch. E - Prob. 76ECh. E - Suppose that a person eats 2387 Calories per day....Ch. E - A particular frost-free refrigerator uses about...Ch. E - Prob. 79ECh. E - Prob. 80ECh. E - A solid gold cylinder sits on a weight-sensitive...Ch. E - The proton has a radius of approximately 1.0 ×...Ch. E - The density of titanium is 4.51 g/cm3. What is the...Ch. E - The density of iron is 7.86 g/cm3. What is its...Ch. E - A steel cylinder has a length of 2.16 in, a radius...Ch. E - A solid aluminum sphere has a mass of 85 g. Use...Ch. E - Prob. 87ECh. E - Prob. 88ECh. E - The Toyota Prius, a hybrid electric vehicle, has a...Ch. E - The Honda Insight, a hybrid electric vehicle, has...Ch. E - The single proton that forms the nucleus of the...Ch. E - A sample of gaseous neon atoms at atmospheric...Ch. E - Prob. 93ECh. E - The world’s record in the 100-m dash is 9.58 s,...Ch. E - Table salt contains 39.33 g of sodium per 100 g of...Ch. E - Prob. 96ECh. E - A length of #8 copper wire (radius = 1.63 mm) has...Ch. E - Rolls of aluminum foil are 304 mm wide and 0.016...Ch. E - Liquid nitrogen has a density of 0.808 g/L and...Ch. E - Mercury is often used in thermometers. The mercury...Ch. E - Prob. 101ECh. E - In 1999, scientists discovered a new class of...Ch. E - Prob. 103ECh. E - Nanotechnology, the field of building ultrasmall...Ch. E - Prob. 105ECh. E - A box contains a mixture of small copper spheres...Ch. E - A cube has an edge length of 7 cm. If it is...Ch. E - Prob. 108ECh. E - For each box, examine the blocks attached to the...Ch. E - Look up the measurement of the approximate...Ch. E - Prob. 111ECh. E - One inch is equal to 2.54 cm. Draw a line that is...Ch. E - Convert the height of each member in your group...Ch. E - Prob. 114ECh. E - Convert 85.0 °F to k. 358 k 181.1 k 302.6 k 29.4 kCh. E - Express the quantity 33.2 × 10-4 m in mm. 0.332 mm...Ch. E - How many significant figures are there in the...Ch. E - Perform the calculation to the correct number of...Ch. E - Perform the calculation to the correct number of...Ch. E - What is the mass of a 1 .75-L sample of a liquid...Ch. E - Convert 1,285 cm2to m2. 12.85 m2 0.1285 m2 1.285 ×...Ch. E - Prob. 8SAQCh. E - A solid metal sphere has a radius of 3.53 cm and a...Ch. E - A German automobile’s gas mileage is 22km/L....Ch. E - A wooden block has a volume of 18.5 in3. Express...
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