(a) Interpretation: The structure from the provided IUPAC name is to be drawn. Concept introduction: If a molecule contains at least one ring entirely made up of carbon and hydrogen atoms, then such a ring could establish the root as a ‘cycloalkane’. Alternatively, the ring could serve as a substituent and called cycloalkyl groups. Whether a ring is treated as a root or a substituent depends on the relative number of carbon atoms in it. If the largest carbon ring has as many or more carbons than the longest continuous straight carbon chain, then the ring serves as the parent. If the longest continuous carbon chain has more carbon atoms than the longest continuous straight carbon chain, then the longest continuous straight chain serves as a parent and the ring serves as a substituent. When the parent is a cycloalkane, then C1 has the greatest number of attached substituents, and numbering increases clockwise or anticlockwise around the ring so that the next substituent is encountered the earliest. Prefixes are used to indicate the number of substituents attached to the ring or to the longest continuous straight chain.

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Answer 1

Question

Chapter A, Problem A.28P

Interpretation Introduction

(a)

Interpretation:

The structure from the provided IUPAC name is to be drawn.

Concept introduction:

If a molecule contains at least one ring entirely made up of carbon and hydrogen atoms, then such a ring could establish the root as a ‘cycloalkane’. Alternatively, the ring could serve as a substituent and called cycloalkyl groups. Whether a ring is treated as a root or a substituent depends on the relative number of carbon atoms in it. If the largest carbon ring has as many or more carbons than the longest continuous straight carbon chain, then the ring serves as the parent. If the longest continuous carbon chain has more carbon atoms than the longest continuous straight carbon chain, then the longest continuous straight chain serves as a parent and the ring serves as a substituent. When the parent is a cycloalkane, then C1 has the greatest number of attached substituents, and numbering increases clockwise or anticlockwise around the ring so that the next substituent is encountered the earliest. Prefixes are used to indicate the number of substituents attached to the ring or to the longest continuous straight chain.

Interpretation Introduction

(b)

Interpretation:

The structure from the given IUPAC name is to be drawn.

Concept introduction:

Interpretation Introduction

(c)

Interpretation:

The structure from the provided IUPAC name is to be drawn.

Concept introduction:

If a molecule contains at least one ring entirely made up of carbon and hydrogen atoms, then such a ring could establish the root as a ‘cycloalkane’. Alternatively, the ring could serve as a substituent and called cycloalkyl groups. Whether a ring is treated as a root or a substituent depends on the relative number of carbon atoms in it. If the largest carbon ring has as many or more carbons than the longest continuous straight carbon chain, then the ring serves as the parent. If the longest continuous carbon chain has more carbon atoms than the longest continuous straight carbon chain, then the longest continuous straight chain serves as a parent and the ring serves as a substituent. When the parent is a cycloalkane, then C1 has the greatest number of attached substituents, and numbering increases clockwise or anticlockwise around the ring so that the next substituent is encountered the earliest. Prefixes are used to indicate the number of substituents attached to the ring or to the longest continuous straight chain.

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9 7 8 C 9 8 200 190 B 5 A -197.72 9 8 7 15 4 3 0: ང་ 200 190 180 147.52 134.98 170 160 150 140 130 120 110 100 90 90 OH 10 4 3 1 2 -143.04 140. 180 170 160 150 140 130 120 110 100 90 CI 3 5 1 2 141.89 140.07 200 190 180 170 160 150 140 130 120 110 100 ៖- 90 129. 126.25 80 70 60 -60 50 40 10 125.19 -129.21 80 70 3.0 20 20 -8 60 50 10 ppm -20 40 128.31 80 80 70 60 50 40 40 -70.27 3.0 20 10 ppm 00˚0-- 77.17 30 20 20 -45.36 10 ppm -0.00 26.48 22.32 ―30.10 ―-0.00

Assign all the carbons

C 5 4 3 CI 2 the Righ B A 5 4 3 The Lich. OH 10 4 5 3 1 LOOP- -147.52 T 77.17 -45.36 200 190 180 170 160 150 140 130 120 110 100 90 80 70 60 50 40 30 20 10 ppm B -126.25 77.03 200 190 180 170 160 150 140 130 120 110 100 90 80 70 60 50 40 30 20 10 ppm 200 190 180 170 160 150 140 130 120 110 100 90 80 TO LL <-50.00 70 60 50 40 30 20 10 ppm 45.06 30.18 -26.45 22.36 --0.00 45.07 7.5 1.93 2.05 -30.24 -22.36 C A 7 8 5 ° 4 3 7.5 7.0 6.5 6.0 5.5 5.0 4.5 4.0 3.5 3.0 2.5 2.0 1.5 1.0 ppm 9 8 5 4 3 ཡི་ OH 10 2 7.5 7.0 6.5 6.0 5.5 5.0 4.5 4.0 3.5 3.0 2.5 2.0 1.5 5 4 3 2 that th 7 I 7.0 6.5 6.0 5.5 5.0 4.5 4.0 3.5 3.0 2.5 2.0 1.5 115 2.21 4.00 1.0 ppm 6.96 2.76 5.01 1.0 ppm 6.30 1.00

Answer 2

Question

Chapter A, Problem A.28P

Interpretation Introduction

(a)

Interpretation:

The structure from the provided IUPAC name is to be drawn.

Concept introduction:

If a molecule contains at least one ring entirely made up of carbon and hydrogen atoms, then such a ring could establish the root as a ‘cycloalkane’. Alternatively, the ring could serve as a substituent and called cycloalkyl groups. Whether a ring is treated as a root or a substituent depends on the relative number of carbon atoms in it. If the largest carbon ring has as many or more carbons than the longest continuous straight carbon chain, then the ring serves as the parent. If the longest continuous carbon chain has more carbon atoms than the longest continuous straight carbon chain, then the longest continuous straight chain serves as a parent and the ring serves as a substituent. When the parent is a cycloalkane, then C1 has the greatest number of attached substituents, and numbering increases clockwise or anticlockwise around the ring so that the next substituent is encountered the earliest. Prefixes are used to indicate the number of substituents attached to the ring or to the longest continuous straight chain.

Interpretation Introduction

(b)

Interpretation:

The structure from the given IUPAC name is to be drawn.

Concept introduction:

Interpretation Introduction

(c)

Interpretation:

The structure from the provided IUPAC name is to be drawn.

Concept introduction:

If a molecule contains at least one ring entirely made up of carbon and hydrogen atoms, then such a ring could establish the root as a ‘cycloalkane’. Alternatively, the ring could serve as a substituent and called cycloalkyl groups. Whether a ring is treated as a root or a substituent depends on the relative number of carbon atoms in it. If the largest carbon ring has as many or more carbons than the longest continuous straight carbon chain, then the ring serves as the parent. If the longest continuous carbon chain has more carbon atoms than the longest continuous straight carbon chain, then the longest continuous straight chain serves as a parent and the ring serves as a substituent. When the parent is a cycloalkane, then C1 has the greatest number of attached substituents, and numbering increases clockwise or anticlockwise around the ring so that the next substituent is encountered the earliest. Prefixes are used to indicate the number of substituents attached to the ring or to the longest continuous straight chain.

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Answer 3

Question

Chapter A, Problem A.28P

Interpretation Introduction

(a)

Interpretation:

The structure from the provided IUPAC name is to be drawn.

Concept introduction:

If a molecule contains at least one ring entirely made up of carbon and hydrogen atoms, then such a ring could establish the root as a ‘cycloalkane’. Alternatively, the ring could serve as a substituent and called cycloalkyl groups. Whether a ring is treated as a root or a substituent depends on the relative number of carbon atoms in it. If the largest carbon ring has as many or more carbons than the longest continuous straight carbon chain, then the ring serves as the parent. If the longest continuous carbon chain has more carbon atoms than the longest continuous straight carbon chain, then the longest continuous straight chain serves as a parent and the ring serves as a substituent. When the parent is a cycloalkane, then C1 has the greatest number of attached substituents, and numbering increases clockwise or anticlockwise around the ring so that the next substituent is encountered the earliest. Prefixes are used to indicate the number of substituents attached to the ring or to the longest continuous straight chain.

Interpretation Introduction

(b)

Interpretation:

The structure from the given IUPAC name is to be drawn.

Concept introduction:

Interpretation Introduction

(c)

Interpretation:

The structure from the provided IUPAC name is to be drawn.

Concept introduction:

If a molecule contains at least one ring entirely made up of carbon and hydrogen atoms, then such a ring could establish the root as a ‘cycloalkane’. Alternatively, the ring could serve as a substituent and called cycloalkyl groups. Whether a ring is treated as a root or a substituent depends on the relative number of carbon atoms in it. If the largest carbon ring has as many or more carbons than the longest continuous straight carbon chain, then the ring serves as the parent. If the longest continuous carbon chain has more carbon atoms than the longest continuous straight carbon chain, then the longest continuous straight chain serves as a parent and the ring serves as a substituent. When the parent is a cycloalkane, then C1 has the greatest number of attached substituents, and numbering increases clockwise or anticlockwise around the ring so that the next substituent is encountered the earliest. Prefixes are used to indicate the number of substituents attached to the ring or to the longest continuous straight chain.

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Answer 4

Question

Chapter A, Problem A.28P

Interpretation Introduction

(a)

Interpretation:

The structure from the provided IUPAC name is to be drawn.

Concept introduction:

If a molecule contains at least one ring entirely made up of carbon and hydrogen atoms, then such a ring could establish the root as a ‘cycloalkane’. Alternatively, the ring could serve as a substituent and called cycloalkyl groups. Whether a ring is treated as a root or a substituent depends on the relative number of carbon atoms in it. If the largest carbon ring has as many or more carbons than the longest continuous straight carbon chain, then the ring serves as the parent. If the longest continuous carbon chain has more carbon atoms than the longest continuous straight carbon chain, then the longest continuous straight chain serves as a parent and the ring serves as a substituent. When the parent is a cycloalkane, then C1 has the greatest number of attached substituents, and numbering increases clockwise or anticlockwise around the ring so that the next substituent is encountered the earliest. Prefixes are used to indicate the number of substituents attached to the ring or to the longest continuous straight chain.

Interpretation Introduction

(b)

Interpretation:

The structure from the given IUPAC name is to be drawn.

Concept introduction:

Interpretation Introduction

(c)

Interpretation:

The structure from the provided IUPAC name is to be drawn.

Concept introduction:

If a molecule contains at least one ring entirely made up of carbon and hydrogen atoms, then such a ring could establish the root as a ‘cycloalkane’. Alternatively, the ring could serve as a substituent and called cycloalkyl groups. Whether a ring is treated as a root or a substituent depends on the relative number of carbon atoms in it. If the largest carbon ring has as many or more carbons than the longest continuous straight carbon chain, then the ring serves as the parent. If the longest continuous carbon chain has more carbon atoms than the longest continuous straight carbon chain, then the longest continuous straight chain serves as a parent and the ring serves as a substituent. When the parent is a cycloalkane, then C1 has the greatest number of attached substituents, and numbering increases clockwise or anticlockwise around the ring so that the next substituent is encountered the earliest. Prefixes are used to indicate the number of substituents attached to the ring or to the longest continuous straight chain.

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Answer 5

Chapter A, Problem A.28P

Interpretation Introduction

(a)

Interpretation:

The structure from the provided IUPAC name is to be drawn.

Concept introduction:

If a molecule contains at least one ring entirely made up of carbon and hydrogen atoms, then such a ring could establish the root as a ‘cycloalkane’. Alternatively, the ring could serve as a substituent and called cycloalkyl groups. Whether a ring is treated as a root or a substituent depends on the relative number of carbon atoms in it. If the largest carbon ring has as many or more carbons than the longest continuous straight carbon chain, then the ring serves as the parent. If the longest continuous carbon chain has more carbon atoms than the longest continuous straight carbon chain, then the longest continuous straight chain serves as a parent and the ring serves as a substituent. When the parent is a cycloalkane, then C1 has the greatest number of attached substituents, and numbering increases clockwise or anticlockwise around the ring so that the next substituent is encountered the earliest. Prefixes are used to indicate the number of substituents attached to the ring or to the longest continuous straight chain.

Interpretation Introduction

(b)

Interpretation:

The structure from the given IUPAC name is to be drawn.

Concept introduction:

Interpretation Introduction

(c)

Interpretation:

The structure from the provided IUPAC name is to be drawn.

Concept introduction:

If a molecule contains at least one ring entirely made up of carbon and hydrogen atoms, then such a ring could establish the root as a ‘cycloalkane’. Alternatively, the ring could serve as a substituent and called cycloalkyl groups. Whether a ring is treated as a root or a substituent depends on the relative number of carbon atoms in it. If the largest carbon ring has as many or more carbons than the longest continuous straight carbon chain, then the ring serves as the parent. If the longest continuous carbon chain has more carbon atoms than the longest continuous straight carbon chain, then the longest continuous straight chain serves as a parent and the ring serves as a substituent. When the parent is a cycloalkane, then C1 has the greatest number of attached substituents, and numbering increases clockwise or anticlockwise around the ring so that the next substituent is encountered the earliest. Prefixes are used to indicate the number of substituents attached to the ring or to the longest continuous straight chain.

Answer 6

Chapter A, Problem A.28P

Interpretation Introduction

(a)

Interpretation:

The structure from the provided IUPAC name is to be drawn.

Concept introduction:

If a molecule contains at least one ring entirely made up of carbon and hydrogen atoms, then such a ring could establish the root as a ‘cycloalkane’. Alternatively, the ring could serve as a substituent and called cycloalkyl groups. Whether a ring is treated as a root or a substituent depends on the relative number of carbon atoms in it. If the largest carbon ring has as many or more carbons than the longest continuous straight carbon chain, then the ring serves as the parent. If the longest continuous carbon chain has more carbon atoms than the longest continuous straight carbon chain, then the longest continuous straight chain serves as a parent and the ring serves as a substituent. When the parent is a cycloalkane, then C1 has the greatest number of attached substituents, and numbering increases clockwise or anticlockwise around the ring so that the next substituent is encountered the earliest. Prefixes are used to indicate the number of substituents attached to the ring or to the longest continuous straight chain.

Answer 7

Chapter A, Problem A.28P

Interpretation Introduction

(a)

Interpretation:

The structure from the provided IUPAC name is to be drawn.

Concept introduction:

If a molecule contains at least one ring entirely made up of carbon and hydrogen atoms, then such a ring could establish the root as a ‘cycloalkane’. Alternatively, the ring could serve as a substituent and called cycloalkyl groups. Whether a ring is treated as a root or a substituent depends on the relative number of carbon atoms in it. If the largest carbon ring has as many or more carbons than the longest continuous straight carbon chain, then the ring serves as the parent. If the longest continuous carbon chain has more carbon atoms than the longest continuous straight carbon chain, then the longest continuous straight chain serves as a parent and the ring serves as a substituent. When the parent is a cycloalkane, then C1 has the greatest number of attached substituents, and numbering increases clockwise or anticlockwise around the ring so that the next substituent is encountered the earliest. Prefixes are used to indicate the number of substituents attached to the ring or to the longest continuous straight chain.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The structure from the given IUPAC name is to be drawn.

Concept introduction:

Answer 9

Interpretation Introduction

(b)

Interpretation:

The structure from the given IUPAC name is to be drawn.

Concept introduction:

Answer 10

Interpretation Introduction

(c)

Interpretation:

The structure from the provided IUPAC name is to be drawn.

Concept introduction:

If a molecule contains at least one ring entirely made up of carbon and hydrogen atoms, then such a ring could establish the root as a ‘cycloalkane’. Alternatively, the ring could serve as a substituent and called cycloalkyl groups. Whether a ring is treated as a root or a substituent depends on the relative number of carbon atoms in it. If the largest carbon ring has as many or more carbons than the longest continuous straight carbon chain, then the ring serves as the parent. If the longest continuous carbon chain has more carbon atoms than the longest continuous straight carbon chain, then the longest continuous straight chain serves as a parent and the ring serves as a substituent. When the parent is a cycloalkane, then C1 has the greatest number of attached substituents, and numbering increases clockwise or anticlockwise around the ring so that the next substituent is encountered the earliest. Prefixes are used to indicate the number of substituents attached to the ring or to the longest continuous straight chain.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The structure from the provided IUPAC name is to be drawn.

Concept introduction:

If a molecule contains at least one ring entirely made up of carbon and hydrogen atoms, then such a ring could establish the root as a ‘cycloalkane’. Alternatively, the ring could serve as a substituent and called cycloalkyl groups. Whether a ring is treated as a root or a substituent depends on the relative number of carbon atoms in it. If the largest carbon ring has as many or more carbons than the longest continuous straight carbon chain, then the ring serves as the parent. If the longest continuous carbon chain has more carbon atoms than the longest continuous straight carbon chain, then the longest continuous straight chain serves as a parent and the ring serves as a substituent. When the parent is a cycloalkane, then C1 has the greatest number of attached substituents, and numbering increases clockwise or anticlockwise around the ring so that the next substituent is encountered the earliest. Prefixes are used to indicate the number of substituents attached to the ring or to the longest continuous straight chain.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. A - Prob. A.1P Ch. A - Prob. A.2P Ch. A - Prob. A.3P Ch. A - Prob. A.4P Ch. A - Prob. A.5P Ch. A - Prob. A.6P Ch. A - Prob. A.7P Ch. A - Prob. A.8P Ch. A - Prob. A.9P Ch. A - Prob. A.10P

Solution Summary: The structure for the given IUPAC name is as shown in Figure 1 above.

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(b)

Interpretation:

The structure from the given IUPAC name is to be drawn.

Concept introduction:

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Chapter A Solutions

Solution Summary: The structure for the given IUPAC name is as shown in Figure 1 above.

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(b) Interpretation: The structure from the given IUPAC name is to be drawn. Concept introduction:

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Chapter A Solutions

(b)

Interpretation:

The structure from the given IUPAC name is to be drawn.

Concept introduction: