EBK GET READY FOR ORGANIC CHEMISTRY
2nd Edition
ISBN: 8220100576379
Author: KARTY
Publisher: PEARSON
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Chapter A, Problem A.22P
Interpretation Introduction
(a)
Interpretation:
The structure for the given IUPAC name, is to be drawn.
Concept introduction:
An
Interpretation Introduction
(b)
Interpretation:
The structure for the given IUPAC name, is to be drawn.
Concept introduction:
An alkane is said to be substituted if a hydrogen atom of the alkane is replaced by another atom or group of atoms. In the IUPAC name of a molecule, the root defines the number of carbon atoms in the longest chain. The names of the substituents and their respective locant numbers show the carbon atoms of the root to which those substituents are attached.
Interpretation Introduction
(c)
Interpretation:
The structure for the given IUPAC name, is to be drawn.
Concept introduction:
An alkane is said to be substituted if a hydrogen atom of the alkane is replaced by another atom or group of atoms. In the IUPAC name of a molecule, the root defines the number of carbon atoms in the longest chain. The names of the substituents and their respective locant numbers show the carbon atoms of the root to which those substituents are attached.
Interpretation Introduction
(d)
Interpretation:
The structure for the given IUPAC name, is to be drawn.
Concept introduction:
An alkane is said to be substituted if a hydrogen atom of the alkane is replaced by another atom or group of atoms. In the IUPAC name of a molecule, the root defines the number of carbon atoms in the longest chain. The names of the substituents and their respective locant numbers show the carbon atoms of the root to which those substituents are attached.
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8. Draw all the resonance forms for each of the fling molecules or ions, and indicate the major
contributor in each case, or if they are equivalent (45)
(2)
-PH2
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J
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+0
Also calculate the amount of starting materials chlorobenzaldehyde and p-chloroacetophenone
required to prepare 400 mg of the given chalcone product 1, 3-bis(4-chlorophenyl)prop-2-en-1-one
molar mass ok 1,3-bis(4-Chlorophenyl) prop-2-en-1-one = 277.1591m01
number of moles= 0.400/277.15 = 0.00144 moles
2 x 0.00 144=0.00288 moves
arams of acetophenone = 0.00144 X 120.16 = 0.1739
0.1739x2=0.3469
grams of benzaldehyde = 0.00144X106.12=0.1539
0.1539x2 = 0.3069
Starting materials:
0.3469 Ox acetophenone,
0.3069 of benzaldehyde
3
1.
Answer the questions about the following reaction:
(a) Draw in the arrows that can be used make this reaction occur and draw in the product of substitution in this
reaction. Be sure to include any relevant stereochemistry in the product structure.
+
SK
F
Br
+
(b) In which solvent would this reaction proceed the fastest (Circle one)
Methanol
Acetone
(c) Imagine that you are working for a chemical company and it was your job to perform a similar reaction to the
one above, with the exception of the S atom in this reaction being replaced by an O atom. During the reaction, you
observe the formation of three separate molecules instead of the single molecule obtained above. What is the likeliest
other products that are formed? Draw them in the box provided.
Chapter A Solutions
EBK GET READY FOR ORGANIC CHEMISTRY
Ch. A - Prob. A.1PCh. A - Prob. A.2PCh. A - Prob. A.3PCh. A - Prob. A.4PCh. A - Prob. A.5PCh. A - Prob. A.6PCh. A - Prob. A.7PCh. A - Prob. A.8PCh. A - Prob. A.9PCh. A - Prob. A.10P
Ch. A - Prob. A.11PCh. A - Prob. A.12PCh. A - Prob. A.13PCh. A - Prob. A.14PCh. A - Prob. A.15PCh. A - Prob. A.16PCh. A - Prob. A.17PCh. A - Prob. A.18PCh. A - Prob. A.19PCh. A - Prob. A.20PCh. A - Prob. A.21PCh. A - Prob. A.22PCh. A - Prob. A.23PCh. A - Prob. A.24PCh. A - Prob. A.25PCh. A - Prob. A.26PCh. A - Prob. A.27PCh. A - Prob. A.28PCh. A - Prob. A.29PCh. A - Prob. A.30PCh. A - Prob. A.31PCh. A - Prob. A.32PCh. A - Prob. A.33PCh. A - Prob. A.34PCh. A - Prob. A.35PCh. A - Prob. A.36PCh. A - Prob. A.37PCh. A - Prob. A.38PCh. A - Prob. A.39PCh. A - Prob. A.40PCh. A - Prob. A.41PCh. A - Prob. A.42PCh. A - Prob. A.43PCh. A - Prob. A.44PCh. A - Prob. A.45PCh. A - Prob. A.46P
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