The major product expected when given alkyne reacts with aqueous acid has to be drawn. Concept Introduction: Addition Reaction: It is defined as chemical reaction in which two given molecules combines and forms product. The types of addition reactions are electrophilic addition, nucleophilic addition, free radical additions and cycloadditions. Generally, compounds with carbon-hetero atom bonds favours addition reaction. Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the more substitution position of carbon-carbon double bond which provides alkyl halides. Anti-Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

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Answer 1

Question

Chapter 9.7, Problem 18CC

(a)

Interpretation Introduction

Interpretation:

The major product expected when given alkyne reacts with aqueous acid has to be drawn.

Concept Introduction:

Addition Reaction: It is defined as chemical reaction in which two given molecules combines and forms product. The types of addition reactions are electrophilic addition, nucleophilic addition, free radical additions and cycloadditions. Generally, compounds with carbon-hetero atom bonds favours addition reaction.

Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the more substitution position of carbon-carbon double bond which provides alkyl halides.

Anti-Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

(b)

Interpretation Introduction

Interpretation:

The major product expected when given alkyne reacts with aqueous acid has to be drawn.

Concept Introduction:

Addition Reaction: It is defined as chemical reaction in which two given molecules combines and forms product. The types of addition reactions are electrophilic addition, nucleophilic addition, free radical additions and cycloadditions. Generally, compounds with carbon-hetero atom bonds favours addition reaction.

Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the more substitution position of carbon-carbon double bond which provides alkyl halides.

Anti-Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

(c)

Interpretation Introduction

Interpretation:

The major product expected when given alkyne reacts with aqueous acid has to be drawn.

Concept Introduction:

Addition Reaction: It is defined as chemical reaction in which two given molecules combines and forms product. The types of addition reactions are electrophilic addition, nucleophilic addition, free radical additions and cycloadditions. Generally, compounds with carbon-hetero atom bonds favours addition reaction.

Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the more substitution position of carbon-carbon double bond which provides alkyl halides.

Anti-Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

(d)

Interpretation Introduction

Interpretation:

The major product expected when given alkyne reacts with aqueous acid has to be drawn.

Concept Introduction:

Addition Reaction: It is defined as chemical reaction in which two given molecules combines and forms product. The types of addition reactions are electrophilic addition, nucleophilic addition, free radical additions and cycloadditions. Generally, compounds with carbon-hetero atom bonds favours addition reaction.

Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the more substitution position of carbon-carbon double bond which provides alkyl halides.

Anti-Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

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Answer 2

Question

Chapter 9.7, Problem 18CC

(a)

Interpretation Introduction

Interpretation:

The major product expected when given alkyne reacts with aqueous acid has to be drawn.

Concept Introduction:

Addition Reaction: It is defined as chemical reaction in which two given molecules combines and forms product. The types of addition reactions are electrophilic addition, nucleophilic addition, free radical additions and cycloadditions. Generally, compounds with carbon-hetero atom bonds favours addition reaction.

Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the more substitution position of carbon-carbon double bond which provides alkyl halides.

Anti-Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

(b)

Interpretation Introduction

Interpretation:

The major product expected when given alkyne reacts with aqueous acid has to be drawn.

Concept Introduction:

Addition Reaction: It is defined as chemical reaction in which two given molecules combines and forms product. The types of addition reactions are electrophilic addition, nucleophilic addition, free radical additions and cycloadditions. Generally, compounds with carbon-hetero atom bonds favours addition reaction.

Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the more substitution position of carbon-carbon double bond which provides alkyl halides.

Anti-Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

(c)

Interpretation Introduction

Interpretation:

The major product expected when given alkyne reacts with aqueous acid has to be drawn.

Concept Introduction:

Addition Reaction: It is defined as chemical reaction in which two given molecules combines and forms product. The types of addition reactions are electrophilic addition, nucleophilic addition, free radical additions and cycloadditions. Generally, compounds with carbon-hetero atom bonds favours addition reaction.

Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the more substitution position of carbon-carbon double bond which provides alkyl halides.

Anti-Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

(d)

Interpretation Introduction

Interpretation:

The major product expected when given alkyne reacts with aqueous acid has to be drawn.

Concept Introduction:

Addition Reaction: It is defined as chemical reaction in which two given molecules combines and forms product. The types of addition reactions are electrophilic addition, nucleophilic addition, free radical additions and cycloadditions. Generally, compounds with carbon-hetero atom bonds favours addition reaction.

Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the more substitution position of carbon-carbon double bond which provides alkyl halides.

Anti-Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

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Answer 3

Question

Chapter 9.7, Problem 18CC

(a)

Interpretation Introduction

Interpretation:

The major product expected when given alkyne reacts with aqueous acid has to be drawn.

Concept Introduction:

Addition Reaction: It is defined as chemical reaction in which two given molecules combines and forms product. The types of addition reactions are electrophilic addition, nucleophilic addition, free radical additions and cycloadditions. Generally, compounds with carbon-hetero atom bonds favours addition reaction.

Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the more substitution position of carbon-carbon double bond which provides alkyl halides.

Anti-Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

(b)

Interpretation Introduction

Interpretation:

The major product expected when given alkyne reacts with aqueous acid has to be drawn.

Concept Introduction:

Addition Reaction: It is defined as chemical reaction in which two given molecules combines and forms product. The types of addition reactions are electrophilic addition, nucleophilic addition, free radical additions and cycloadditions. Generally, compounds with carbon-hetero atom bonds favours addition reaction.

Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the more substitution position of carbon-carbon double bond which provides alkyl halides.

Anti-Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

(c)

Interpretation Introduction

Interpretation:

The major product expected when given alkyne reacts with aqueous acid has to be drawn.

Concept Introduction:

Addition Reaction: It is defined as chemical reaction in which two given molecules combines and forms product. The types of addition reactions are electrophilic addition, nucleophilic addition, free radical additions and cycloadditions. Generally, compounds with carbon-hetero atom bonds favours addition reaction.

Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the more substitution position of carbon-carbon double bond which provides alkyl halides.

Anti-Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

(d)

Interpretation Introduction

Interpretation:

The major product expected when given alkyne reacts with aqueous acid has to be drawn.

Concept Introduction:

Addition Reaction: It is defined as chemical reaction in which two given molecules combines and forms product. The types of addition reactions are electrophilic addition, nucleophilic addition, free radical additions and cycloadditions. Generally, compounds with carbon-hetero atom bonds favours addition reaction.

Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the more substitution position of carbon-carbon double bond which provides alkyl halides.

Anti-Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

Expert Solution & Answer

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See solution

Answer 4

Question

Chapter 9.7, Problem 18CC

(a)

Interpretation Introduction

Interpretation:

The major product expected when given alkyne reacts with aqueous acid has to be drawn.

Concept Introduction:

Addition Reaction: It is defined as chemical reaction in which two given molecules combines and forms product. The types of addition reactions are electrophilic addition, nucleophilic addition, free radical additions and cycloadditions. Generally, compounds with carbon-hetero atom bonds favours addition reaction.

Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the more substitution position of carbon-carbon double bond which provides alkyl halides.

Anti-Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

(b)

Interpretation Introduction

Interpretation:

The major product expected when given alkyne reacts with aqueous acid has to be drawn.

Concept Introduction:

Addition Reaction: It is defined as chemical reaction in which two given molecules combines and forms product. The types of addition reactions are electrophilic addition, nucleophilic addition, free radical additions and cycloadditions. Generally, compounds with carbon-hetero atom bonds favours addition reaction.

Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the more substitution position of carbon-carbon double bond which provides alkyl halides.

Anti-Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

(c)

Interpretation Introduction

Interpretation:

The major product expected when given alkyne reacts with aqueous acid has to be drawn.

Concept Introduction:

Addition Reaction: It is defined as chemical reaction in which two given molecules combines and forms product. The types of addition reactions are electrophilic addition, nucleophilic addition, free radical additions and cycloadditions. Generally, compounds with carbon-hetero atom bonds favours addition reaction.

Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the more substitution position of carbon-carbon double bond which provides alkyl halides.

Anti-Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

(d)

Interpretation Introduction

Interpretation:

The major product expected when given alkyne reacts with aqueous acid has to be drawn.

Concept Introduction:

Addition Reaction: It is defined as chemical reaction in which two given molecules combines and forms product. The types of addition reactions are electrophilic addition, nucleophilic addition, free radical additions and cycloadditions. Generally, compounds with carbon-hetero atom bonds favours addition reaction.

Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the more substitution position of carbon-carbon double bond which provides alkyl halides.

Anti-Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

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Answer 5

Chapter 9.7, Problem 18CC

(a)

Interpretation Introduction

Interpretation:

The major product expected when given alkyne reacts with aqueous acid has to be drawn.

Concept Introduction:

Addition Reaction: It is defined as chemical reaction in which two given molecules combines and forms product. The types of addition reactions are electrophilic addition, nucleophilic addition, free radical additions and cycloadditions. Generally, compounds with carbon-hetero atom bonds favours addition reaction.

Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the more substitution position of carbon-carbon double bond which provides alkyl halides.

Anti-Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

(b)

Interpretation Introduction

Interpretation:

The major product expected when given alkyne reacts with aqueous acid has to be drawn.

Concept Introduction:

Addition Reaction: It is defined as chemical reaction in which two given molecules combines and forms product. The types of addition reactions are electrophilic addition, nucleophilic addition, free radical additions and cycloadditions. Generally, compounds with carbon-hetero atom bonds favours addition reaction.

Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the more substitution position of carbon-carbon double bond which provides alkyl halides.

Anti-Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

(c)

Interpretation Introduction

Interpretation:

The major product expected when given alkyne reacts with aqueous acid has to be drawn.

Concept Introduction:

Addition Reaction: It is defined as chemical reaction in which two given molecules combines and forms product. The types of addition reactions are electrophilic addition, nucleophilic addition, free radical additions and cycloadditions. Generally, compounds with carbon-hetero atom bonds favours addition reaction.

Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the more substitution position of carbon-carbon double bond which provides alkyl halides.

Anti-Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

(d)

Interpretation Introduction

Interpretation:

The major product expected when given alkyne reacts with aqueous acid has to be drawn.

Concept Introduction:

Addition Reaction: It is defined as chemical reaction in which two given molecules combines and forms product. The types of addition reactions are electrophilic addition, nucleophilic addition, free radical additions and cycloadditions. Generally, compounds with carbon-hetero atom bonds favours addition reaction.

Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the more substitution position of carbon-carbon double bond which provides alkyl halides.

Anti-Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

Answer 6

Chapter 9.7, Problem 18CC

(a)

Interpretation Introduction

Interpretation:

The major product expected when given alkyne reacts with aqueous acid has to be drawn.

Concept Introduction:

Addition Reaction: It is defined as chemical reaction in which two given molecules combines and forms product. The types of addition reactions are electrophilic addition, nucleophilic addition, free radical additions and cycloadditions. Generally, compounds with carbon-hetero atom bonds favours addition reaction.

Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the more substitution position of carbon-carbon double bond which provides alkyl halides.

Anti-Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

Answer 7

Chapter 9.7, Problem 18CC

(a)

Interpretation Introduction

Interpretation:

The major product expected when given alkyne reacts with aqueous acid has to be drawn.

Concept Introduction:

Addition Reaction: It is defined as chemical reaction in which two given molecules combines and forms product. The types of addition reactions are electrophilic addition, nucleophilic addition, free radical additions and cycloadditions. Generally, compounds with carbon-hetero atom bonds favours addition reaction.

Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the more substitution position of carbon-carbon double bond which provides alkyl halides.

Anti-Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The major product expected when given alkyne reacts with aqueous acid has to be drawn.

Concept Introduction:

Addition Reaction: It is defined as chemical reaction in which two given molecules combines and forms product. The types of addition reactions are electrophilic addition, nucleophilic addition, free radical additions and cycloadditions. Generally, compounds with carbon-hetero atom bonds favours addition reaction.

Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the more substitution position of carbon-carbon double bond which provides alkyl halides.

Anti-Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The major product expected when given alkyne reacts with aqueous acid has to be drawn.

Concept Introduction:

Addition Reaction: It is defined as chemical reaction in which two given molecules combines and forms product. The types of addition reactions are electrophilic addition, nucleophilic addition, free radical additions and cycloadditions. Generally, compounds with carbon-hetero atom bonds favours addition reaction.

Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the more substitution position of carbon-carbon double bond which provides alkyl halides.

Anti-Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The major product expected when given alkyne reacts with aqueous acid has to be drawn.

Concept Introduction:

Addition Reaction: It is defined as chemical reaction in which two given molecules combines and forms product. The types of addition reactions are electrophilic addition, nucleophilic addition, free radical additions and cycloadditions. Generally, compounds with carbon-hetero atom bonds favours addition reaction.

Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the more substitution position of carbon-carbon double bond which provides alkyl halides.

Anti-Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The major product expected when given alkyne reacts with aqueous acid has to be drawn.

Concept Introduction:

Addition Reaction: It is defined as chemical reaction in which two given molecules combines and forms product. The types of addition reactions are electrophilic addition, nucleophilic addition, free radical additions and cycloadditions. Generally, compounds with carbon-hetero atom bonds favours addition reaction.

Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the more substitution position of carbon-carbon double bond which provides alkyl halides.

Anti-Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

Answer 12

(d)

Interpretation Introduction

Interpretation:

The major product expected when given alkyne reacts with aqueous acid has to be drawn.

Concept Introduction:

Addition Reaction: It is defined as chemical reaction in which two given molecules combines and forms product. The types of addition reactions are electrophilic addition, nucleophilic addition, free radical additions and cycloadditions. Generally, compounds with carbon-hetero atom bonds favours addition reaction.

Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the more substitution position of carbon-carbon double bond which provides alkyl halides.

Anti-Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

Answer 13

(d)

Interpretation Introduction

Interpretation:

The major product expected when given alkyne reacts with aqueous acid has to be drawn.

Concept Introduction:

Addition Reaction: It is defined as chemical reaction in which two given molecules combines and forms product. The types of addition reactions are electrophilic addition, nucleophilic addition, free radical additions and cycloadditions. Generally, compounds with carbon-hetero atom bonds favours addition reaction.

Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the more substitution position of carbon-carbon double bond which provides alkyl halides.

Anti-Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

Answer 14

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Answer 15

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Answer 17

Ch. 9.2 - Prob. 1LTS Ch. 9.2 - Prob. 1PTS Ch. 9.2 - Prob. 2PTS Ch. 9.2 - Prob. 3PTS Ch. 9.2 - (+)-Citronella is the main compound responsible...Ch. 9.3 - Prob. 2LTS Ch. 9.3 - Prob. 5PTS Ch. 9.3 - Prob. 6ATS Ch. 9.4 - Prob. 7CC Ch. 9.4 - Prob. 8CC

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