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OWLv2 with LabSkills for Gilbert/Martin's Experimental Organic Chemistry: A Miniscale & Microscale Approach, 6th Edition, [Instant Access], 4 terms (24 months)
6th Edition
ISBN: 9781305387676
Author: John C. Gilbert; Stephen F. Martin
Publisher: Cengage Learning US
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Chapter 9.2, Problem 22E
(a)
Interpretation Introduction
Interpretation:
Considering the NMR data for 1-chlorobutane, various resonances to the hydrogen
nuclei responsible for them are to be assigned.
Concept Introduction : Nuclear Magnetic Resonance (NMR) spectroscopy is a logical chemistry method used in quality control.
It studies for defining the material and purity of a sample and their molecular structure. It explains magnetic energy levels undergoing the resonance transition when the atomic nuclei are exposed to an external magnetic field and an
(b)
Interpretation Introduction
Interpretation:The various resonances of C nuclei needs to be assigned in the 13C NMR data.
Concept Introduction : Nuclear Magnetic Resonance (NMR) spectroscopy is a logical chemistry method used in quality control.
It studies for defining the material and purity of a sample and their molecular structure. It explains magnetic energy levels undergoing the resonance transition when the atomic nuclei are exposed to an external magnetic field and an electromagnetic radiation is applied with the specific frequency. The NMR spectrum is obtained by detecting the absorption signals.
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Nitration of furan with acetylnitrate leads to 2,5-dinitrofuran. Mononitration can be done by
A. carrying out the reaction at higher temperature.
B. using nitric acid instead of acetyl nitrate.
C. carrying out the nitration in the presence of pyridine
D. using concentrated nitric acid/sulfuric acid instead of acetyl nitrate.
1. Summarize the main characteristics of nucleophilic acyl substitution. 2. Choose one carboxylic acid that has applications in diagnostic tests, nutrition, or pharmacology. Explain how the molecular property contributes to the bulk property of the carboxylic acid.
Why are alcohols usually bad electrophiles? You must support your answer with data on the basicity/acidity of the leaving group.
Chapter 9 Solutions
OWLv2 with LabSkills for Gilbert/Martin's Experimental Organic Chemistry: A Miniscale & Microscale Approach, 6th Edition, [Instant Access], 4 terms (24 months)
Ch. 9.2 - Prob. 1ECh. 9.2 - Prob. 2ECh. 9.2 - Prob. 3ECh. 9.2 - Prob. 4ECh. 9.2 - Prob. 5ECh. 9.2 - Prob. 6ECh. 9.2 - Prob. 7ECh. 9.2 - Prob. 8ECh. 9.2 - Prob. 9ECh. 9.2 - Prob. 10E
Ch. 9.2 - Prob. 11ECh. 9.2 - Prob. 12ECh. 9.2 - Prob. 13ECh. 9.2 - Prob. 14ECh. 9.2 - Prob. 15ECh. 9.2 - Prob. 16ECh. 9.2 - Prob. 17ECh. 9.2 - Prob. 18ECh. 9.2 - Prob. 19ECh. 9.2 - Prob. 20ECh. 9.2 - Prob. 21ECh. 9.2 - Prob. 22ECh. 9.2 - Prob. 23ECh. 9.2 - Prob. 24ECh. 9.3 - Prob. 1ECh. 9.3 - Prob. 2ECh. 9.3 - Prob. 3ECh. 9.3 - Prob. 4ECh. 9.3 - Prob. 5ECh. 9.3 - Prob. 6ECh. 9.3 - Prob. 7ECh. 9.3 - Prob. 8ECh. 9.3 - Prob. 9ECh. 9.3 - Prob. 10ECh. 9.3 - Prob. 11ECh. 9.3 - Prob. 12ECh. 9.3 - Prob. 13ECh. 9.3 - Prob. 14E
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