Among the following compounds the compound which reacts faster in S N 2 reaction is to be identified. Concept Introduction: Primary substitution, unless there is a steric hindrance in the alkyl halide or nucleophile, then elimination is favoured.

Question

An unknown weak acid with a concentration of 0.410 M has a pH of 5.600. What is the Ka of the weak acid?

Answer 1

Question

Chapter 9.12, Problem 39P

(a)

Interpretation Introduction

Interpretation:

Among the following compounds the compound which reacts faster in S_N2 reaction is to be identified.

Concept Introduction:

Primary substitution, unless there is a steric hindrance in the alkyl halide or nucleophile, then elimination is favoured.

(b)

Interpretation Introduction

Interpretation:

Among the following compounds the compound which reacts faster in E1 reaction is to be identified.

Concept Introduction:

For an E1/E2 reaction, when same alkyl group is present with the leaving group, the relative reactivity of alkyl halide is,

RI > RBr > RCl > RF .

(c)

Interpretation Introduction

Interpretation:

Among the following which reacts faster in S_N1 reaction is to be identified.

Concept Introduction:

Secondary alkyl halide do not undergo S_N1 reaction, tertiary can undergo both substitution and elimination product, and substitution is mostly favored.

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An unknown weak acid with a concentration of 0.410 M has a pH of 5.600. What is the Ka of the weak acid?

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R₂ R₁ R₁ a R Rg Nu R₂ Rg R₁ R R₁₂ R3 R R Nu enolate forming R₁ R B-Alkylated carbonyl species or amines Cyclic B-Ketoester R₁₁ HOB R R₁B R R₁₂ B-Hydroxy carbonyl R diester R2 R3 R₁ RB OR R₂ 0 aB-Unsaturated carbonyl NaOR Aldol HOR reaction 1) LDA 2) R-X 3) H₂O/H₂O ketone, aldehyde 1) 2°-amine 2) acid chloride 3) H₂O'/H₂O 0 O R₁ R₁ R R₁ R₁₂ Alkylated a-carbon R₁ H.C R₁ H.C Alkylated methyl ketone acetoacetic ester B-Ketoester ester R₁ HO R₂ R B-Dicarbonyl HO Alkylated carboxylic acid malonic ester Write the reagents required to bring about each reaction next to the arrows shown. Next, record any regiochemistry or stereochemistry considerations relevant to the reaction. You should also record any key aspects of the mechanism, such as forma- tion of an important intermediate, as a helpful reminder. You may want to keep track of all reactions that make carbon-carbon bonds, because these help you build large molecules from smaller fragments. This especially applies to the reactions in…

Answer 2

Question

Chapter 9.12, Problem 39P

(a)

Interpretation Introduction

Interpretation:

Among the following compounds the compound which reacts faster in S_N2 reaction is to be identified.

Concept Introduction:

Primary substitution, unless there is a steric hindrance in the alkyl halide or nucleophile, then elimination is favoured.

(b)

Interpretation Introduction

Interpretation:

Among the following compounds the compound which reacts faster in E1 reaction is to be identified.

Concept Introduction:

For an E1/E2 reaction, when same alkyl group is present with the leaving group, the relative reactivity of alkyl halide is,

RI > RBr > RCl > RF .

(c)

Interpretation Introduction

Interpretation:

Among the following which reacts faster in S_N1 reaction is to be identified.

Concept Introduction:

Secondary alkyl halide do not undergo S_N1 reaction, tertiary can undergo both substitution and elimination product, and substitution is mostly favored.

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Answer 3

Question

Chapter 9.12, Problem 39P

(a)

Interpretation Introduction

Interpretation:

Among the following compounds the compound which reacts faster in S_N2 reaction is to be identified.

Concept Introduction:

Primary substitution, unless there is a steric hindrance in the alkyl halide or nucleophile, then elimination is favoured.

(b)

Interpretation Introduction

Interpretation:

Among the following compounds the compound which reacts faster in E1 reaction is to be identified.

Concept Introduction:

For an E1/E2 reaction, when same alkyl group is present with the leaving group, the relative reactivity of alkyl halide is,

RI > RBr > RCl > RF .

(c)

Interpretation Introduction

Interpretation:

Among the following which reacts faster in S_N1 reaction is to be identified.

Concept Introduction:

Secondary alkyl halide do not undergo S_N1 reaction, tertiary can undergo both substitution and elimination product, and substitution is mostly favored.

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Answer 4

Question

Chapter 9.12, Problem 39P

(a)

Interpretation Introduction

Interpretation:

Among the following compounds the compound which reacts faster in S_N2 reaction is to be identified.

Concept Introduction:

Primary substitution, unless there is a steric hindrance in the alkyl halide or nucleophile, then elimination is favoured.

(b)

Interpretation Introduction

Interpretation:

Among the following compounds the compound which reacts faster in E1 reaction is to be identified.

Concept Introduction:

For an E1/E2 reaction, when same alkyl group is present with the leaving group, the relative reactivity of alkyl halide is,

RI > RBr > RCl > RF .

(c)

Interpretation Introduction

Interpretation:

Among the following which reacts faster in S_N1 reaction is to be identified.

Concept Introduction:

Secondary alkyl halide do not undergo S_N1 reaction, tertiary can undergo both substitution and elimination product, and substitution is mostly favored.

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Answer 5

Chapter 9.12, Problem 39P

(a)

Interpretation Introduction

Interpretation:

Among the following compounds the compound which reacts faster in S_N2 reaction is to be identified.

Concept Introduction:

Primary substitution, unless there is a steric hindrance in the alkyl halide or nucleophile, then elimination is favoured.

(b)

Interpretation Introduction

Interpretation:

Among the following compounds the compound which reacts faster in E1 reaction is to be identified.

Concept Introduction:

For an E1/E2 reaction, when same alkyl group is present with the leaving group, the relative reactivity of alkyl halide is,

RI > RBr > RCl > RF .

(c)

Interpretation Introduction

Interpretation:

Among the following which reacts faster in S_N1 reaction is to be identified.

Concept Introduction:

Secondary alkyl halide do not undergo S_N1 reaction, tertiary can undergo both substitution and elimination product, and substitution is mostly favored.

Answer 6

Chapter 9.12, Problem 39P

(a)

Interpretation Introduction

Interpretation:

Among the following compounds the compound which reacts faster in S_N2 reaction is to be identified.

Concept Introduction:

Primary substitution, unless there is a steric hindrance in the alkyl halide or nucleophile, then elimination is favoured.

Answer 7

Chapter 9.12, Problem 39P

(a)

Interpretation Introduction

Interpretation:

Among the following compounds the compound which reacts faster in S_N2 reaction is to be identified.

Concept Introduction:

Primary substitution, unless there is a steric hindrance in the alkyl halide or nucleophile, then elimination is favoured.

Answer 8

(b)

Interpretation Introduction

Interpretation:

Among the following compounds the compound which reacts faster in E1 reaction is to be identified.

Concept Introduction:

For an E1/E2 reaction, when same alkyl group is present with the leaving group, the relative reactivity of alkyl halide is,

RI > RBr > RCl > RF .

Answer 9

(b)

Interpretation Introduction

Interpretation:

Among the following compounds the compound which reacts faster in E1 reaction is to be identified.

Concept Introduction:

For an E1/E2 reaction, when same alkyl group is present with the leaving group, the relative reactivity of alkyl halide is,

RI > RBr > RCl > RF .

Answer 10

(c)

Interpretation Introduction

Interpretation:

Among the following which reacts faster in S_N1 reaction is to be identified.

Concept Introduction:

Secondary alkyl halide do not undergo S_N1 reaction, tertiary can undergo both substitution and elimination product, and substitution is mostly favored.

Answer 11

(c)

Interpretation Introduction

Interpretation:

Among the following which reacts faster in S_N1 reaction is to be identified.

Concept Introduction:

Secondary alkyl halide do not undergo S_N1 reaction, tertiary can undergo both substitution and elimination product, and substitution is mostly favored.

Answer 12

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Answer 23

Ch. 9.1 - Prob. 3P Ch. 9.1 - Does increasing the energy barrier for an SN2...Ch. 9.1 - Rank the following alkyl bromides from most...Ch. 9.1 - Prob. 8P Ch. 9.2 - Prob. 9P Ch. 9.2 - Prob. 10P Ch. 9.2 - Prob. 11P Ch. 9.2 - Prob. 12P Ch. 9.2 - Which substitution reaction lakes place more...Ch. 9.2 - Prob. 15P

Among the following compounds the compound which reacts faster in S N 2 reaction is to be identified. Concept Introduction: Primary substitution, unless there is a steric hindrance in the alkyl halide or nucleophile, then elimination is favoured.

Solution Summary: The author explains that the compound that reacts faster in S N 2 reaction is to be identified.

Concept explainers

Interpretation:

Among the following compounds the compound which reacts faster in S_N2 reaction is to be identified.

Concept Introduction:

Primary substitution, unless there is a steric hindrance in the alkyl halide or nucleophile, then elimination is favoured.

Interpretation:

Among the following compounds the compound which reacts faster in E1 reaction is to be identified.

Concept Introduction:

For an E1/E2 reaction, when same alkyl group is present with the leaving group, the relative reactivity of alkyl halide is,

RI > RBr > RCl > RF .

Interpretation:

Among the following which reacts faster in S_N1 reaction is to be identified.

Concept Introduction:

Secondary alkyl halide do not undergo S_N1 reaction, tertiary can undergo both substitution and elimination product, and substitution is mostly favored.

Chapter 9 Solutions

Among the following compounds the compound which reacts faster in S N 2 reaction is to be identified. Concept Introduction: Primary substitution, unless there is a steric hindrance in the alkyl halide or nucleophile, then elimination is favoured.

Solution Summary: The author explains that the compound that reacts faster in S N 2 reaction is to be identified.

Concept explainers

Interpretation: Among the following compounds the compound which reacts faster in SN2 reaction is to be identified. Concept Introduction: Primary substitution, unless there is a steric hindrance in the alkyl halide or nucleophile, then elimination is favoured.

Interpretation: Among the following compounds the compound which reacts faster in E1 reaction is to be identified. Concept Introduction: For an E1/E2 reaction, when same alkyl group is present with the leaving group, the relative reactivity of alkyl halide is, RI > RBr > RCl > RF .

Interpretation: Among the following which reacts faster in SN1 reaction is to be identified. Concept Introduction: Secondary alkyl halide do not undergo SN1 reaction, tertiary can undergo both substitution and elimination product, and substitution is mostly favored.

Chapter 9 Solutions

Interpretation:

Among the following compounds the compound which reacts faster in S_N2 reaction is to be identified.

Concept Introduction:

Primary substitution, unless there is a steric hindrance in the alkyl halide or nucleophile, then elimination is favoured.

Interpretation:

Among the following compounds the compound which reacts faster in E1 reaction is to be identified.

Concept Introduction:

For an E1/E2 reaction, when same alkyl group is present with the leaving group, the relative reactivity of alkyl halide is,

RI > RBr > RCl > RF .

Interpretation:

Among the following which reacts faster in S_N1 reaction is to be identified.

Concept Introduction:

Secondary alkyl halide do not undergo S_N1 reaction, tertiary can undergo both substitution and elimination product, and substitution is mostly favored.