Chemistry [hardcover]
Chemistry [hardcover]
5th Edition
ISBN: 9780393264845
Author: Geoffery Davies
Publisher: NORTON
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Chapter 9, Problem 9.68QP
Interpretation Introduction

Interpretation: The possibility of all the nitrogen atoms present in the given structure having the same hybridization is to be validated.

Concept introduction: Hybridization is a process in which two or more atomic orbital of nearly similar energy combine together to form equal number of hybrid orbitals of similar energy.

To validate: The possibility of all the nitrogen atoms present in the given structure having the same hybridization.

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a. Determine the electrochemical potential of the following cell using E°Mg2+/Mg = -2.362 V. Mg | Mg2+ (a=104) || H* (a = 4) | H2 (p = 0.5 bar) | Pt b. A galvanic chain consists of Co²+ / Co and Ag+ / Ag half-cells with EºCo²+/Co = -0.282 V and Eº Ag+/Ag = 0.799 V. Determine which half-cell will be reduced and which one will be oxidised. Furthermore, calculate the electrochemical potential as well as the equilibrium constant of the whole cell at i. [Co²+] = 0.1 M and [Ag+] = 0.5 M ii. [Co²+] = 0.001 M and [Ag*] = 1.5 M
The equilibrium voltage of the following cell has been measured at 0.522 V at 25 °C. Pt | H2, g❘ HClaq || AgClaq | Ags State the redox reactions present in this cell. Calculate the pH value of the electrolyte solution with KL, AgCl = 1.96 · 10-10 mol² / L². Assume that the concentrations of H+ and Clare equal.
Here are the energies (in kcal/mol) for staggered and eclipsed interactions for CH, CC, and CBr bonds eclipsed (0°) staggered (60°) bonds CH/CH 1.0 0.0 CH/CC 1.3 0.0 Br: CC/CC 3.0 0.9 Br CH/CBr 1.8 0.0 CC / CBr 3.3 1.0 CBr / CBr 3.7 1.2 a) I've drawn the Newman projection for one of the staggered conformations of the molecule above, looking down the C2-C3 bond. Draw Newman projections for the other two staggered and the three eclipsed conformations (in order). CH₂ H3C. H' H Br b) Calculate the relative energies for each of the conformations and write them below each conformation.

Chapter 9 Solutions

Chemistry [hardcover]

Ch. 9.7 - Prob. 11PECh. 9.7 - Prob. 12PECh. 9.7 - Prob. 13PECh. 9 - Prob. 9.1VPCh. 9 - Prob. 9.2VPCh. 9 - Prob. 9.3VPCh. 9 - Prob. 9.4VPCh. 9 - Prob. 9.5VPCh. 9 - Prob. 9.6VPCh. 9 - Prob. 9.7VPCh. 9 - Prob. 9.8VPCh. 9 - Prob. 9.9QPCh. 9 - Prob. 9.10QPCh. 9 - Prob. 9.11QPCh. 9 - Prob. 9.12QPCh. 9 - Prob. 9.13QPCh. 9 - Prob. 9.14QPCh. 9 - Prob. 9.15QPCh. 9 - Prob. 9.16QPCh. 9 - Prob. 9.17QPCh. 9 - Prob. 9.18QPCh. 9 - Prob. 9.19QPCh. 9 - Prob. 9.20QPCh. 9 - Prob. 9.21QPCh. 9 - Prob. 9.22QPCh. 9 - Prob. 9.23QPCh. 9 - Prob. 9.24QPCh. 9 - Prob. 9.25QPCh. 9 - Prob. 9.26QPCh. 9 - Prob. 9.27QPCh. 9 - Prob. 9.28QPCh. 9 - Prob. 9.29QPCh. 9 - Prob. 9.30QPCh. 9 - Prob. 9.31QPCh. 9 - Prob. 9.32QPCh. 9 - Prob. 9.33QPCh. 9 - Prob. 9.34QPCh. 9 - Prob. 9.35QPCh. 9 - Prob. 9.36QPCh. 9 - Prob. 9.37QPCh. 9 - Prob. 9.38QPCh. 9 - Prob. 9.39QPCh. 9 - Prob. 9.40QPCh. 9 - Prob. 9.41QPCh. 9 - Prob. 9.42QPCh. 9 - Prob. 9.43QPCh. 9 - Prob. 9.44QPCh. 9 - Prob. 9.45QPCh. 9 - Prob. 9.46QPCh. 9 - Prob. 9.47QPCh. 9 - Prob. 9.48QPCh. 9 - Prob. 9.49QPCh. 9 - Prob. 9.50QPCh. 9 - Prob. 9.51QPCh. 9 - Prob. 9.52QPCh. 9 - Prob. 9.53QPCh. 9 - Prob. 9.54QPCh. 9 - Prob. 9.55QPCh. 9 - Prob. 9.56QPCh. 9 - Prob. 9.57QPCh. 9 - Prob. 9.58QPCh. 9 - Prob. 9.59QPCh. 9 - Prob. 9.60QPCh. 9 - Prob. 9.61QPCh. 9 - Prob. 9.62QPCh. 9 - Prob. 9.63QPCh. 9 - Prob. 9.64QPCh. 9 - Prob. 9.65QPCh. 9 - Prob. 9.66QPCh. 9 - Prob. 9.67QPCh. 9 - Prob. 9.68QPCh. 9 - Prob. 9.69QPCh. 9 - Prob. 9.70QPCh. 9 - Prob. 9.71QPCh. 9 - Prob. 9.72QPCh. 9 - Prob. 9.73QPCh. 9 - Prob. 9.74QPCh. 9 - Prob. 9.75QPCh. 9 - Prob. 9.76QPCh. 9 - Prob. 9.77QPCh. 9 - Prob. 9.78QPCh. 9 - Prob. 9.79QPCh. 9 - Prob. 9.80QPCh. 9 - Prob. 9.81QPCh. 9 - Prob. 9.82QPCh. 9 - Prob. 9.83QPCh. 9 - Prob. 9.84QPCh. 9 - Prob. 9.85QPCh. 9 - Prob. 9.86QPCh. 9 - Prob. 9.87QPCh. 9 - Prob. 9.88QPCh. 9 - Prob. 9.89QPCh. 9 - Prob. 9.90QPCh. 9 - Prob. 9.91QPCh. 9 - Prob. 9.92QPCh. 9 - Prob. 9.93QPCh. 9 - Prob. 9.94QPCh. 9 - Prob. 9.95QPCh. 9 - Prob. 9.96QPCh. 9 - Prob. 9.97QPCh. 9 - Prob. 9.98QPCh. 9 - Prob. 9.99QPCh. 9 - Prob. 9.100QPCh. 9 - Prob. 9.101QPCh. 9 - Prob. 9.102QPCh. 9 - Prob. 9.103QPCh. 9 - Prob. 9.104QPCh. 9 - Prob. 9.105QPCh. 9 - Prob. 9.106QPCh. 9 - Prob. 9.107QPCh. 9 - Prob. 9.108QPCh. 9 - Prob. 9.109QPCh. 9 - Prob. 9.110QPCh. 9 - Prob. 9.111QPCh. 9 - Prob. 9.112QPCh. 9 - Prob. 9.113QPCh. 9 - Prob. 9.114QPCh. 9 - Prob. 9.115APCh. 9 - Prob. 9.116APCh. 9 - Prob. 9.117APCh. 9 - Prob. 9.118APCh. 9 - Prob. 9.119APCh. 9 - Prob. 9.120APCh. 9 - Prob. 9.121APCh. 9 - Prob. 9.122APCh. 9 - Prob. 9.123APCh. 9 - Prob. 9.124APCh. 9 - Prob. 9.125APCh. 9 - Prob. 9.126APCh. 9 - Prob. 9.127APCh. 9 - Prob. 9.128APCh. 9 - Prob. 9.129APCh. 9 - Prob. 9.130APCh. 9 - Prob. 9.131APCh. 9 - Prob. 9.132APCh. 9 - Prob. 9.133APCh. 9 - Prob. 9.134APCh. 9 - Prob. 9.135APCh. 9 - Prob. 9.136APCh. 9 - Prob. 9.137APCh. 9 - Prob. 9.138APCh. 9 - Prob. 9.139APCh. 9 - Prob. 9.140APCh. 9 - Prob. 9.141APCh. 9 - Prob. 9.142APCh. 9 - Prob. 9.143AP
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