The possible isomers for square planar isomer [ Pt ( Br ) ( Cl ) ( NH 3 ) 2 ] have to be given. Concept Introduction: Isomers: The compounds with same molecular formula but differ in the arrangement of the atom are said to be isomers. Linkage isomers: Linkage isomerism occurs with ambidentate ligands that are capable of coordinating in more than one way. Example: SCN - /NCS - . The only difference is the atoms bind to the central ion . The ligand must have more than one donor atom but bind to ion in only one place. Hydrate Isomers: Hydrate isomers results from replacement of a coordinated group by a solvent molecule in this case it is a water molecule. Coordination Isomers: Coordination isomerism arises in compounds containing complex anionic and cationic parts. Hence, there are two complex compounds bound together, one with a negative charge and the other with a positive charge. In coordination isomers, the anion and cation complexes of a coordination compound exchange one or more ligands. Ionization Isomers: Ionization isomers occur when a ligand is bound to the metal center exchanges places with an anion or neutral molecule that was previously outside the coordination complex. Geometrical isomers: If there is restricted rotation in a molecule there arises geometric isomerism. Geometric isomers are also known as Cis- trans isomerism. If the two atoms locked in same side of the molecule then it is called as cis isomers. If the two atoms locked in opposite side of the molecule then it is called as trans isomers.

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Answer 1

Question

Chapter 9, Problem 9.3E

(a)

Interpretation Introduction

Interpretation:

The possible isomers for square planar isomer $[Pt(Br)(Cl)(NH3)2]$ have to be given.

Concept Introduction:

Isomers:

The compounds with same molecular formula but differ in the arrangement of the atom are said to be isomers.

Linkage isomers:

Linkage isomerism occurs with ambidentate ligands that are capable of coordinating in more than one way.

Example:

$SCN-/NCS-$ . The only difference is the atoms bind to the central ion. The ligand must have more than one donor atom but bind to ion in only one place.

Hydrate Isomers:

Hydrate isomers results from replacement of a coordinated group by a solvent molecule in this case it is a water molecule.

Coordination Isomers:

Coordination isomerism arises in compounds containing complex anionic and cationic parts. Hence, there are two complex compounds bound together, one with a negative charge and the other with a positive charge. In coordination isomers, the anion and cation complexes of a coordination compound exchange one or more ligands.

Ionization Isomers:

Ionization isomers occur when a ligand is bound to the metal center exchanges places with an anion or neutral molecule that was previously outside the coordination complex.

Geometrical isomers:

If there is restricted rotation in a molecule there arises geometric isomerism. Geometric isomers are also known as Cis- trans isomerism.

If the two atoms locked in same side of the molecule then it is called as cis isomers.

If the two atoms locked in opposite side of the molecule then it is called as trans isomers.

(b)

Interpretation Introduction

Interpretation:

The complex $[Pt(Br)(Cl)(NH3)2]$ is square planar not tetrahedral this has to be explained based on the existence of these isomers.

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Answer 2

Question

Chapter 9, Problem 9.3E

(a)

Interpretation Introduction

Interpretation:

The possible isomers for square planar isomer $[Pt(Br)(Cl)(NH3)2]$ have to be given.

Concept Introduction:

Isomers:

The compounds with same molecular formula but differ in the arrangement of the atom are said to be isomers.

Linkage isomers:

Linkage isomerism occurs with ambidentate ligands that are capable of coordinating in more than one way.

Example:

$SCN-/NCS-$ . The only difference is the atoms bind to the central ion. The ligand must have more than one donor atom but bind to ion in only one place.

Hydrate Isomers:

Hydrate isomers results from replacement of a coordinated group by a solvent molecule in this case it is a water molecule.

Coordination Isomers:

Coordination isomerism arises in compounds containing complex anionic and cationic parts. Hence, there are two complex compounds bound together, one with a negative charge and the other with a positive charge. In coordination isomers, the anion and cation complexes of a coordination compound exchange one or more ligands.

Ionization Isomers:

Ionization isomers occur when a ligand is bound to the metal center exchanges places with an anion or neutral molecule that was previously outside the coordination complex.

Geometrical isomers:

If there is restricted rotation in a molecule there arises geometric isomerism. Geometric isomers are also known as Cis- trans isomerism.

If the two atoms locked in same side of the molecule then it is called as cis isomers.

If the two atoms locked in opposite side of the molecule then it is called as trans isomers.

(b)

Interpretation Introduction

Interpretation:

The complex $[Pt(Br)(Cl)(NH3)2]$ is square planar not tetrahedral this has to be explained based on the existence of these isomers.

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Answer 3

Question

Chapter 9, Problem 9.3E

(a)

Interpretation Introduction

Interpretation:

The possible isomers for square planar isomer $[Pt(Br)(Cl)(NH3)2]$ have to be given.

Concept Introduction:

Isomers:

The compounds with same molecular formula but differ in the arrangement of the atom are said to be isomers.

Linkage isomers:

Linkage isomerism occurs with ambidentate ligands that are capable of coordinating in more than one way.

Example:

$SCN-/NCS-$ . The only difference is the atoms bind to the central ion. The ligand must have more than one donor atom but bind to ion in only one place.

Hydrate Isomers:

Hydrate isomers results from replacement of a coordinated group by a solvent molecule in this case it is a water molecule.

Coordination Isomers:

Coordination isomerism arises in compounds containing complex anionic and cationic parts. Hence, there are two complex compounds bound together, one with a negative charge and the other with a positive charge. In coordination isomers, the anion and cation complexes of a coordination compound exchange one or more ligands.

Ionization Isomers:

Ionization isomers occur when a ligand is bound to the metal center exchanges places with an anion or neutral molecule that was previously outside the coordination complex.

Geometrical isomers:

If there is restricted rotation in a molecule there arises geometric isomerism. Geometric isomers are also known as Cis- trans isomerism.

If the two atoms locked in same side of the molecule then it is called as cis isomers.

If the two atoms locked in opposite side of the molecule then it is called as trans isomers.

(b)

Interpretation Introduction

Interpretation:

The complex $[Pt(Br)(Cl)(NH3)2]$ is square planar not tetrahedral this has to be explained based on the existence of these isomers.

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Answer 4

Question

Chapter 9, Problem 9.3E

(a)

Interpretation Introduction

Interpretation:

The possible isomers for square planar isomer $[Pt(Br)(Cl)(NH3)2]$ have to be given.

Concept Introduction:

Isomers:

The compounds with same molecular formula but differ in the arrangement of the atom are said to be isomers.

Linkage isomers:

Linkage isomerism occurs with ambidentate ligands that are capable of coordinating in more than one way.

Example:

$SCN-/NCS-$ . The only difference is the atoms bind to the central ion. The ligand must have more than one donor atom but bind to ion in only one place.

Hydrate Isomers:

Hydrate isomers results from replacement of a coordinated group by a solvent molecule in this case it is a water molecule.

Coordination Isomers:

Coordination isomerism arises in compounds containing complex anionic and cationic parts. Hence, there are two complex compounds bound together, one with a negative charge and the other with a positive charge. In coordination isomers, the anion and cation complexes of a coordination compound exchange one or more ligands.

Ionization Isomers:

Ionization isomers occur when a ligand is bound to the metal center exchanges places with an anion or neutral molecule that was previously outside the coordination complex.

Geometrical isomers:

If there is restricted rotation in a molecule there arises geometric isomerism. Geometric isomers are also known as Cis- trans isomerism.

If the two atoms locked in same side of the molecule then it is called as cis isomers.

If the two atoms locked in opposite side of the molecule then it is called as trans isomers.

(b)

Interpretation Introduction

Interpretation:

The complex $[Pt(Br)(Cl)(NH3)2]$ is square planar not tetrahedral this has to be explained based on the existence of these isomers.

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Answer 5

Chapter 9, Problem 9.3E

(a)

Interpretation Introduction

Interpretation:

The possible isomers for square planar isomer $[Pt(Br)(Cl)(NH3)2]$ have to be given.

Concept Introduction:

Isomers:

The compounds with same molecular formula but differ in the arrangement of the atom are said to be isomers.

Linkage isomers:

Linkage isomerism occurs with ambidentate ligands that are capable of coordinating in more than one way.

Example:

$SCN-/NCS-$ . The only difference is the atoms bind to the central ion. The ligand must have more than one donor atom but bind to ion in only one place.

Hydrate Isomers:

Hydrate isomers results from replacement of a coordinated group by a solvent molecule in this case it is a water molecule.

Coordination Isomers:

Coordination isomerism arises in compounds containing complex anionic and cationic parts. Hence, there are two complex compounds bound together, one with a negative charge and the other with a positive charge. In coordination isomers, the anion and cation complexes of a coordination compound exchange one or more ligands.

Ionization Isomers:

Ionization isomers occur when a ligand is bound to the metal center exchanges places with an anion or neutral molecule that was previously outside the coordination complex.

Geometrical isomers:

If there is restricted rotation in a molecule there arises geometric isomerism. Geometric isomers are also known as Cis- trans isomerism.

If the two atoms locked in same side of the molecule then it is called as cis isomers.

If the two atoms locked in opposite side of the molecule then it is called as trans isomers.

(b)

Interpretation Introduction

Interpretation:

The complex $[Pt(Br)(Cl)(NH3)2]$ is square planar not tetrahedral this has to be explained based on the existence of these isomers.

Answer 6

Chapter 9, Problem 9.3E

(a)

Interpretation Introduction

Interpretation:

The possible isomers for square planar isomer $[Pt(Br)(Cl)(NH3)2]$ have to be given.

Concept Introduction:

Isomers:

The compounds with same molecular formula but differ in the arrangement of the atom are said to be isomers.

Linkage isomers:

Linkage isomerism occurs with ambidentate ligands that are capable of coordinating in more than one way.

Example:

$SCN-/NCS-$ . The only difference is the atoms bind to the central ion. The ligand must have more than one donor atom but bind to ion in only one place.

Hydrate Isomers:

Hydrate isomers results from replacement of a coordinated group by a solvent molecule in this case it is a water molecule.

Coordination Isomers:

Coordination isomerism arises in compounds containing complex anionic and cationic parts. Hence, there are two complex compounds bound together, one with a negative charge and the other with a positive charge. In coordination isomers, the anion and cation complexes of a coordination compound exchange one or more ligands.

Ionization Isomers:

Ionization isomers occur when a ligand is bound to the metal center exchanges places with an anion or neutral molecule that was previously outside the coordination complex.

Geometrical isomers:

If there is restricted rotation in a molecule there arises geometric isomerism. Geometric isomers are also known as Cis- trans isomerism.

If the two atoms locked in same side of the molecule then it is called as cis isomers.

If the two atoms locked in opposite side of the molecule then it is called as trans isomers.

Answer 7

Chapter 9, Problem 9.3E

(a)

Interpretation Introduction

Interpretation:

The possible isomers for square planar isomer $[Pt(Br)(Cl)(NH3)2]$ have to be given.

Concept Introduction:

Isomers:

The compounds with same molecular formula but differ in the arrangement of the atom are said to be isomers.

Linkage isomers:

Linkage isomerism occurs with ambidentate ligands that are capable of coordinating in more than one way.

Example:

$SCN-/NCS-$ . The only difference is the atoms bind to the central ion. The ligand must have more than one donor atom but bind to ion in only one place.

Hydrate Isomers:

Hydrate isomers results from replacement of a coordinated group by a solvent molecule in this case it is a water molecule.

Coordination Isomers:

Coordination isomerism arises in compounds containing complex anionic and cationic parts. Hence, there are two complex compounds bound together, one with a negative charge and the other with a positive charge. In coordination isomers, the anion and cation complexes of a coordination compound exchange one or more ligands.

Ionization Isomers:

Ionization isomers occur when a ligand is bound to the metal center exchanges places with an anion or neutral molecule that was previously outside the coordination complex.

Geometrical isomers:

If there is restricted rotation in a molecule there arises geometric isomerism. Geometric isomers are also known as Cis- trans isomerism.

If the two atoms locked in same side of the molecule then it is called as cis isomers.

If the two atoms locked in opposite side of the molecule then it is called as trans isomers.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The complex $[Pt(Br)(Cl)(NH3)2]$ is square planar not tetrahedral this has to be explained based on the existence of these isomers.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The complex $[Pt(Br)(Cl)(NH3)2]$ is square planar not tetrahedral this has to be explained based on the existence of these isomers.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 9 - Prob. 9A.1AST Ch. 9 - Prob. 9A.1BST Ch. 9 - Prob. 9A.1E Ch. 9 - Prob. 9A.2E Ch. 9 - Prob. 9A.3E Ch. 9 - Prob. 9A.4E Ch. 9 - Prob. 9A.5E Ch. 9 - Prob. 9A.6E Ch. 9 - Prob. 9A.7E Ch. 9 - Prob. 9A.8E

Solution Summary: The author explains the possible isomers for square planar and ambidentate ligands that are capable of coordinating in more than one way.

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Interpretation:

The complex $[Pt(Br)(Cl)(NH3)2]$ is square planar not tetrahedral this has to be explained based on the existence of these isomers.

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