Student Solutions Manual for Ball's Physical Chemistry, 2nd
Student Solutions Manual for Ball's Physical Chemistry, 2nd
2nd Edition
ISBN: 9798214169019
Author: David W. Ball
Publisher: Cengage Learning US
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Chapter 9, Problem 9.35E

Determine the speed of an electron being emitted by rubidium ( ϕ = 2 .16 eV ) when light of the following wavelengths is shined on the metal in vacuum: (a) 550 nm, (b) 450 nm, (c) 350 nm .

(a)

Expert Solution
Check Mark
Interpretation Introduction

Interpretation:

The speed of an electron that is being emitted by rubidium, when light of different wavelength is shined on the metal in vacuum is to be stated.

Concept introduction:

The emission of electrons when the light is shone upon a material is called the photoelectric effect. The electrons emitted by such a method are also known as photo-electrons. The process basically involves shining light of frequency υ, on a metal surface to remove the electrons with a kinetic energy of 12mv2.

Answer to Problem 9.35E

The speed of an electron that is being emitted by rubidium, when light of different wavelength is shined on the metal in vacuum is 1.8×105msec1.

Explanation of Solution

The given value of work function ϕ is 2.16 eV and λ is 550nm.

The formula to calculate the velocity of an electron is given below.

hcλ=ϕ+12mv2(1)

Where,

 h is the Planck’s Constant (6.6×1034 J sec)

 c is the speed of light (3.8×108 m sec1)

λ is the wavelength

 m is the mass of an electron

 v is the velocity of the emitted electron

 ϕ is the work function

It is known that, 1eV=1.6×1031J

Therefore,

2.16eV×1.6×1031J1eV=3.456×1019J

It is known that,

1nm =109m

Therefore,

550nm×1091nm=550×109nm

Rearrange equation (1) to calculate the value of velocity.

v=2m(hcλϕ)

Substitute the values of work function ϕ, Planck’s constant h, speed of light c, wavelength λ and mass of electron m in the above equation.

v=2(6.6×1034Jsec × 3×108msec1550×109m3.456×1019J)9.1×1031kgv=2(0.036×1017J0.03456×1017J)9.1×1031kgv=3.1536×1010m2sec2v=1.7758×105msec11.8×105

Therefore, the value of speed is 1.8×105 m sec1.

Conclusion

The speed of an electron that is being emitted by rubidium, when light of different wavelength is shined on the metal in vacuum is 1.8×105 m sec1.

(b)

Expert Solution
Check Mark
Interpretation Introduction

Interpretation:

The speed of an electron that is being emitted by rubidium, when light of different wavelength is shined on the metal in vacuum is to be stated.

Concept introduction:

The emission of electrons or other free electrons when the light is shone upon a material is called the photoelectric effect. The electrons emitted by such a method are also known as photo-electrons. The process basically, involves shining light of frequency υ, on a metal surface to remove the electrons with a kinetic energy of 12mv2.

Answer to Problem 9.35E

The speed of an electron that is being emitted by rubidium, when light of different wavelength is shined on the metal in vacuum is 4.537×105 m sec1.

Explanation of Solution

The given value of work function ϕ is 2.16 eV and λ is 450nm.

The formula to calculate the velocity of an electron is given below.

hcλ=ϕ+12mv2(2)

Where,

 h is the Planck’s Constant (6.6×1034 J sec)

 c is the speed of light (3.8×108 m sec1)

 λ is the wavelength

 m is the mass of an electron

 v is the velocity of the emitted electron

 ϕ is the work function

It is known that,

1eV =1.6×1031 J

Therefore,

2.16 eV×1.6×1031 J1 eV=3.456×1019 J

It is known that,

1nm =109 m

Therefore,

450 nm ×1091 nm=450 ×109 nm

Rearrange equation (2) to calculate the value of velocity.

v=2m(hcλϕ)

Substitute the values of work function ϕ, Planck’s constant h, speed of light c, wavelength λ and mass of electron m in the above equation, we get-

v=2(6.6×1034 J sec × 3×108 m sec1450×109 m3.456×1019 J)9.1×1031kgv=2(0.044×1017 J0.03456×1017 J)9.1×1031 kgv=20.586×1010 m2 sec2v=4.537 × 105 m sec1

Therefore, the value of speed is 4.537×105 m sec1.

Conclusion

The speed of an electron that is being emitted by rubidium, when light of different wavelength is shined on the metal in vacuum is 4.537×105 m sec1

(c)

Expert Solution
Check Mark
Interpretation Introduction

Interpretation:

The speed of an electron that is being emitted by rubidium, when light of different wavelength is shined on the metal in vacuum is to be stated.

Concept introduction:

The emission of electrons when the light is shone upon a material is called the photoelectric effect. The electrons emitted by such a method are also known as photo-electrons. The process basically involves shining light of frequency υ, on a metal surface to remove the electrons with a kinetic energy of 12mv2.

Answer to Problem 9.35E

The speed of an electron that is being emitted by rubidium, when light of different wavelength is shined on the metal in vacuum is 6.86×105 m sec1

Explanation of Solution

The given value of work function ϕ is 2.16 eV and λ is 350nm.

The formula to calculate the velocity of an electron is given below.

hcλ=ϕ+12mv2(3)

Where,

 h is the Planck’s Constant (6.6×1034 J sec)

 c is the speed of light (3.8×108 m sec1)

 λ is the wavelength

 m is the mass of an electron v is the velocity of the emitted electron

 ϕ is the work function

It is known that,

1eV =1.6×1031 J

Therefore,

2.16eV×1.6×1031 J1 eV=3.456×1019 J

It is known that,

1nm =109m

Therefore,

350 nm×1091 nm=350×109 nm

Rearrange equation (3) to calculate the value of velocity.

v=2m(hcλϕ)

Substitute the values of work function ϕ, Planck’s constant h, speed of light c, wavelength λ and mass of electron m in the above equation.

v=2(6.6×1034 J sec × 3×108 m sec1350×109 m3.456×1019 J)9.1×1031 kgv=2(0.05657×1017 J0.03456×1017 J)9.1×1031 kgv=48.37×1010 m2 sec2v=6.95×105 m sec17×105 m sec1

Therefore, the value of speed is 7×105msec1.

Conclusion

The speed of an electron that is being emitted by rubidium, when light of different wavelength is shined on the metal in vacuum is 7×105 m sec1

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Chapter 9 Solutions

Student Solutions Manual for Ball's Physical Chemistry, 2nd

Ch. 9 - Explain why no lines in the Balmer series of the...Ch. 9 - What are the series limits see the previous...Ch. 9 - The following are the numbers n2 for some of the...Ch. 9 - The Balmer series is isolated from the other...Ch. 9 - Given that the wavelengths of the first three...Ch. 9 - Some scientists study Rydberg atoms, atoms whose...Ch. 9 - Prob. 9.17ECh. 9 - Prob. 9.18ECh. 9 - a How much radiant energy is given off, in...Ch. 9 - Stefans law, equation 9.18, suggests that any body...Ch. 9 - Prob. 9.21ECh. 9 - Betelgeuse pronounced beetle juice is a reddish...Ch. 9 - An average human body has a surface area of...Ch. 9 - Prob. 9.24ECh. 9 - The slope of the plot of energy versus wavelength...Ch. 9 - a Use Wien displacement law to determine the max...Ch. 9 - Prob. 9.27ECh. 9 - Sunburn is caused by ultraviolet UV radiation. Why...Ch. 9 - Calculate the energy of photon having: a a...Ch. 9 - Prob. 9.30ECh. 9 - Integrate Plancks law equation 9.23 from the...Ch. 9 - Calculate the power of light in the wavelength...Ch. 9 - Prob. 9.33ECh. 9 - Work functions are typically given in units of...Ch. 9 - Determine the speed of an electron being emitted...Ch. 9 - Lithium has a work function of 2.90eV. Light...Ch. 9 - Prob. 9.37ECh. 9 - Assume that an electron can absorb more than one...Ch. 9 - The photoelectric effect is used today to make...Ch. 9 - Prob. 9.40ECh. 9 - Prob. 9.41ECh. 9 - Prob. 9.42ECh. 9 - Prob. 9.43ECh. 9 - Prob. 9.44ECh. 9 - Use equation 9.34 to determine the radii, in...Ch. 9 - Prob. 9.46ECh. 9 - Calculate the energies of an electron in the...Ch. 9 - Prob. 9.48ECh. 9 - Show that the collection of constants given in...Ch. 9 - Prob. 9.50ECh. 9 - Equations 9.33 and 9.34 can be combined and...Ch. 9 - a Compare equations 9.31, 9.34, and 9.41 and...Ch. 9 - Label each of the properties of an electron as a...Ch. 9 - The de Broglie equation for a particle can be...Ch. 9 - What is the wavelength of a baseball having mass...Ch. 9 - Electron microscopes operate on the fact that...Ch. 9 - Prob. 9.57ECh. 9 - Prob. 9.58ECh. 9 - Determine under what conditions of temperature and...Ch. 9 - Prob. 9.60ECh. 9 - Prob. 9.61E
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