Pearson eText Organic Chemistry -- Instant Access (Pearson+)
Pearson eText Organic Chemistry -- Instant Access (Pearson+)
9th Edition
ISBN: 9780135213728
Author: Leroy Wade, Jan Simek
Publisher: PEARSON+
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Chapter 9, Problem 9.33SP

Predict the products of reaction of pent-1-yne with the following reagents.

  1. a. 1 equivalent of HCl
  2. b. 2 equivalents of HCl
  3. c. excess H2, Ni
  4. d. H2, Pd/BaSO4, quinoline
  5. e. 1 equivalent of Br2
  6. f. 2 equivalents of Br2
  7. g. cold, dilute KMnO4
  8. h. warm, concd. KMnO4, NaOH
  9. i. Na, liquid ammonia
  10. j. NaNH2
  11. k. H2SO4/HgSO4, H2O
  12. l. Sia2BH, then H2O2, OH
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When two solutions, one of 0.1 M KCl (I) and the other of 0.1 M MCl (II), are brought into contact by a membrane. The cation M cannot cross the membrane. At equilibrium, x moles of K+ will have passed from solution (I) to (II). To maintain the neutrality of the two solutions, x moles of Cl- will also have to pass from I to II. Explain this equality: (0.1 - x)/x = (0.1 + x)/(0.1 - x)
Calculate the variation in the potential of the Pt/MnO4-, Mn2+ pair with pH, ​​indicating the value of the standard potential. Data: E0 = 1.12.
Given the cell: Pt l H2(g) l dis X:KCl (sat) l Hg2Cl2(s) l Hg l Pt. Calculate the emf of the cell as a function of pH.

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Pearson eText Organic Chemistry -- Instant Access (Pearson+)

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