(a) Interpretation: The products of the reaction between 1 - bromobutane and sodium methoxide are to be predicted and the curved-arrow mechanism of the reaction is to be stated. Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

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Answer 1

Question

Chapter 9, Problem 9.30P

Interpretation Introduction

(a)

Interpretation:

The products of the reaction between 1- bromobutane and sodium methoxide are to be predicted and the curved-arrow mechanism of the reaction is to be stated.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

Interpretation Introduction

(b)

Interpretation:

The products of the reaction between 2- bromobutane and potassium tert-butoxide are to be predicted and the curved-arrow mechanism of the reaction is to be stated.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

Interpretation Introduction

(c)

Interpretation:

The products of the reaction between 2-bromo-1,1-dimethylcyclopentane and ethanol are to be predicted and the curved-arrow mechanism of the reaction is to be stated.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

Interpretation Introduction

(d)

Interpretation:

The products of the reaction between bromocyclohexane and methanol are to be predicted and the curved-arrow mechanism of the reaction is to be stated.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

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MISSED THIS? Read Section 19.9 (Pages 878-881); Watch IWE 19.10 Consider the following reaction: CH3OH(g) CO(g) + 2H2(g) (Note that AG,CH3OH(g) = -162.3 kJ/mol and AG,co(g)=-137.2 kJ/mol.) Part A Calculate AG for this reaction at 25 °C under the following conditions: PCH₂OH Pco PH2 0.815 atm = 0.140 atm 0.170 atm Express your answer in kilojoules to three significant figures. Ο ΑΣΦ AG = -150 Submit Previous Answers Request Answer □? kJ × Incorrect; Try Again; 2 attempts remaining Calculate the free energy change under nonstandard conditions (AGrxn) by using the following relationship: AGrxn = AGrxn + RTInQ, AGxn+RTInQ, where AGxn is the standard free energy change, R is the ideal gas constant, T is the temperature in kelvins, a is the reaction quotient. Provide Feedback Next >

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Answer 2

Question

Chapter 9, Problem 9.30P

Interpretation Introduction

(a)

Interpretation:

The products of the reaction between 1- bromobutane and sodium methoxide are to be predicted and the curved-arrow mechanism of the reaction is to be stated.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

Interpretation Introduction

(b)

Interpretation:

The products of the reaction between 2- bromobutane and potassium tert-butoxide are to be predicted and the curved-arrow mechanism of the reaction is to be stated.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

Interpretation Introduction

(c)

Interpretation:

The products of the reaction between 2-bromo-1,1-dimethylcyclopentane and ethanol are to be predicted and the curved-arrow mechanism of the reaction is to be stated.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

Interpretation Introduction

(d)

Interpretation:

The products of the reaction between bromocyclohexane and methanol are to be predicted and the curved-arrow mechanism of the reaction is to be stated.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

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Answer 3

Question

Chapter 9, Problem 9.30P

Interpretation Introduction

(a)

Interpretation:

The products of the reaction between 1- bromobutane and sodium methoxide are to be predicted and the curved-arrow mechanism of the reaction is to be stated.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

Interpretation Introduction

(b)

Interpretation:

The products of the reaction between 2- bromobutane and potassium tert-butoxide are to be predicted and the curved-arrow mechanism of the reaction is to be stated.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

Interpretation Introduction

(c)

Interpretation:

The products of the reaction between 2-bromo-1,1-dimethylcyclopentane and ethanol are to be predicted and the curved-arrow mechanism of the reaction is to be stated.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

Interpretation Introduction

(d)

Interpretation:

The products of the reaction between bromocyclohexane and methanol are to be predicted and the curved-arrow mechanism of the reaction is to be stated.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

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Answer 4

Question

Chapter 9, Problem 9.30P

Interpretation Introduction

(a)

Interpretation:

The products of the reaction between 1- bromobutane and sodium methoxide are to be predicted and the curved-arrow mechanism of the reaction is to be stated.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

Interpretation Introduction

(b)

Interpretation:

The products of the reaction between 2- bromobutane and potassium tert-butoxide are to be predicted and the curved-arrow mechanism of the reaction is to be stated.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

Interpretation Introduction

(c)

Interpretation:

The products of the reaction between 2-bromo-1,1-dimethylcyclopentane and ethanol are to be predicted and the curved-arrow mechanism of the reaction is to be stated.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

Interpretation Introduction

(d)

Interpretation:

The products of the reaction between bromocyclohexane and methanol are to be predicted and the curved-arrow mechanism of the reaction is to be stated.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

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Answer 5

Chapter 9, Problem 9.30P

Interpretation Introduction

(a)

Interpretation:

The products of the reaction between 1- bromobutane and sodium methoxide are to be predicted and the curved-arrow mechanism of the reaction is to be stated.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

Interpretation Introduction

(b)

Interpretation:

The products of the reaction between 2- bromobutane and potassium tert-butoxide are to be predicted and the curved-arrow mechanism of the reaction is to be stated.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

Interpretation Introduction

(c)

Interpretation:

The products of the reaction between 2-bromo-1,1-dimethylcyclopentane and ethanol are to be predicted and the curved-arrow mechanism of the reaction is to be stated.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

Interpretation Introduction

(d)

Interpretation:

The products of the reaction between bromocyclohexane and methanol are to be predicted and the curved-arrow mechanism of the reaction is to be stated.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

Answer 6

Chapter 9, Problem 9.30P

Interpretation Introduction

(a)

Interpretation:

The products of the reaction between 1- bromobutane and sodium methoxide are to be predicted and the curved-arrow mechanism of the reaction is to be stated.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

Answer 7

Chapter 9, Problem 9.30P

Interpretation Introduction

(a)

Interpretation:

The products of the reaction between 1- bromobutane and sodium methoxide are to be predicted and the curved-arrow mechanism of the reaction is to be stated.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The products of the reaction between 2- bromobutane and potassium tert-butoxide are to be predicted and the curved-arrow mechanism of the reaction is to be stated.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The products of the reaction between 2- bromobutane and potassium tert-butoxide are to be predicted and the curved-arrow mechanism of the reaction is to be stated.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The products of the reaction between 2-bromo-1,1-dimethylcyclopentane and ethanol are to be predicted and the curved-arrow mechanism of the reaction is to be stated.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The products of the reaction between 2-bromo-1,1-dimethylcyclopentane and ethanol are to be predicted and the curved-arrow mechanism of the reaction is to be stated.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

Answer 12

Interpretation Introduction

(d)

Interpretation:

The products of the reaction between bromocyclohexane and methanol are to be predicted and the curved-arrow mechanism of the reaction is to be stated.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

Answer 13

Interpretation Introduction

(d)

Interpretation:

The products of the reaction between bromocyclohexane and methanol are to be predicted and the curved-arrow mechanism of the reaction is to be stated.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 9 - Prob. 9.1P Ch. 9 - Prob. 9.2P Ch. 9 - Prob. 9.3P Ch. 9 - Prob. 9.4P Ch. 9 - Prob. 9.5P Ch. 9 - Prob. 9.6P Ch. 9 - Prob. 9.7P Ch. 9 - Prob. 9.8P Ch. 9 - Prob. 9.9P Ch. 9 - Prob. 9.10P

Solution Summary: The author explains that the products of the reaction between 1- bromobutane and sodium methoxide are to be predicted.

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