EP ORGANIC CHEMISTRY -MOD.MASTERING 18W
EP ORGANIC CHEMISTRY -MOD.MASTERING 18W
9th Edition
ISBN: 9780136781776
Author: Wade
Publisher: PEARSON CO
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Chapter 9, Problem 9.29SP

(a)

Interpretation Introduction

To determine: The synthesis of 1,2dibromohexane, using hex1ene as starting material.

Interpretation: The synthesis of 1,2dibromohexane, using hex1ene as starting material is to be shown.

Concept introduction: The synthesis of compound relies upon the type of reactants and reagents that are used during the reactions. The mechanism in alkene and alkynes proceed through the breaking of double or triple bonds because pi bonds are less stable.

Stability of product should be high for the formation of a high yield product. The reagents perform numerous functions in reactions like proton abstraction, oxidation, reduction, catalysis, and dehydrogenation.

(b)

Interpretation Introduction

To determine: The synthesis of hex1yne, using 1,2dibromohexane as starting material, which is obtained from hex1ene.

Interpretation: The synthesis of hex1yne, using 1,2dibromohexane as starting material is to be shown.

Concept introduction: The synthesis of compound relies upon the type of reactants and reagents that are used during the reactions. The mechanism in alkene and alkynes proceed through the breaking of double or triple bonds because pi bonds are less stable.

Stability of product should be high for the formation of a high yield product. The reagents perform numerous functions in reactions like proton abstraction, oxidation, reduction, catalysis, and dehydrogenation.

(c)

Interpretation Introduction

To determine: The synthesis of 2,2dibromohexane, using hex1yne as starting material, which is the product of part (b).

Interpretation: The synthesis of 2,2dibromohexane, using hex1yne as starting material is to be shown.

Concept introduction: The synthesis of compound relies upon the type of reactants and reagents that are used during the reactions. The mechanism in alkene and alkynes proceed through the breaking of double or triple bonds because pi bonds are less stable.

Stability of product should be high for the formation of a high yield product. The reagents perform numerous functions in reactions like proton abstraction, oxidation, reduction, catalysis, and dehydrogenation.

(d)

Interpretation Introduction

To determine: The synthesis of hex2yne, using 2,2dibromohexane as starting material which is a product of part (c).

Interpretation: The synthesis of hex2yne, using 2,2dibromohexane as starting material is to be shown.

Concept introduction: The synthesis of compound relies upon the type of reactants and reagents that are used during the reactions. The mechanism in alkene and alkynes proceed through the breaking of double or triple bonds because pi bonds are less stable.

Stability of product should be high for the formation of a high yield product. The reagents perform numerous functions in reactions like proton abstraction, oxidation, reduction, catalysis, and dehydrogenation.

(e)

Interpretation Introduction

To determine: The synthesis of hex2one, using hex1yne as starting material which is a product of part (b).

Interpretation: The synthesis of hex2one, using hex1yne as starting material which is a product of part (b) is to be shown.

Concept introduction: The synthesis of compound relies upon the type of reactants and reagents that are used during the reactions. The mechanism in alkene and alkynes proceed through the breaking of double or triple bonds because pi bonds are less stable.

Stability of product should be high for the formation of a high yield product. The reagents perform numerous functions in reactions like proton abstraction, oxidation, reduction, catalysis, and dehydrogenation.

(f)

Interpretation Introduction

To determine: The synthesis of hexanal, using hex1yne as starting material which is a product of part (b).

Interpretation: The synthesis of hexanal, using hex1yne as starting material which is a product of part (b) is to be shown.

Concept introduction: The synthesis of compound relies upon the type of reactants and reagents that are used during the reactions. The mechanism in alkene and alkynes proceed through the breaking of double or triple bonds because pi bonds are less stable.

Stability of product should be high for the formation of a high yield product. The reagents perform numerous functions in reactions like proton abstraction, oxidation, reduction, catalysis, and dehydrogenation.

(g)

Interpretation Introduction

To determine: The synthesis of pentanoic acid, using hex1yne as starting material which is a product of part (b).

Interpretation: The synthesis of pentanoic acid, using hex1yne as starting material which is a product of part (b) is to be shown.

Concept introduction: The synthesis of compound relies upon the type of reactants and reagents that are used during the reactions. The mechanism in alkene and alkynes proceed through the breaking of double or triple bonds because pi bonds are less stable.

Stability of product should be high for the formation of a high yield product. The reagents perform numerous functions in reactions like proton abstraction, oxidation, reduction, catalysis, and dehydrogenation.

(h)

Interpretation Introduction

To determine: The synthesis of pentanal, using hex1ene as starting material.

Interpretation: The synthesis of pentanal, using hex1ene as starting material is to be shown.

Concept introduction: The synthesis of compound relies upon the type of reactants and reagents that are used during the reactions. The mechanism in alkene and alkynes proceed through the breaking of double or triple bonds because pi bonds are less stable.

Stability of product should be high for the formation of a high yield product. The reagents perform numerous functions in reactions like proton abstraction, oxidation, reduction, catalysis, and dehydrogenation.

(i)

Interpretation Introduction

To determine: The synthesis of undec6yn5ol , using hex1yne as starting material, which is a product of part (b).

Interpretation: The synthesis of undec6yn5ol , using hex1yne as starting material, which is a product of part (b) is to be shown.

Concept introduction: The synthesis of compound relies upon the type of reactants and reagents that are used during the reactions. The mechanism in alkene and alkynes proceed through the breaking of double or triple bonds because pi bonds are less stable.

Stability of product should be high for the formation of a high yield product. The reagents perform numerous functions in reactions like proton abstraction, oxidation, reduction, catalysis, and dehydrogenation.

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3. Propose a synthesis for the following transformation. Do not draw an arrow-pushing mechanism below, but make sure to draw the product of each proposed step (3 points). CN + En CN
3) Propagation of uncertainty. Every measurement has uncertainty. In this problem, we'll evaluate the uncertainty in every step of a titration of potassium hydrogen phthalate (a common acid used in titrations, abbreviated KHP, formula CsH5KO4) with NaOH of an unknown concentration. The calculation that ultimately needs to be carried out is: concentration NaOH 1000 x mass KHP × purity KHP molar mass KHP x volume NaOH Measurements: a) You use a balance to weigh 0.3992 g of KHP. The uncertainty is ±0.15 mg (0.00015 g). b) You use a buret to slowly add NaOH to the KHP until it reaches the endpoint. It takes 18.73 mL of NaOH. The uncertainty of the burst is 0.03 mL.. c) The manufacturer states the purity of KHP is 100%±0.05%. d) Even though we don't think much about them, molar masses have uncertainty as well. The uncertainty comes from the distribution of isotopes, rather than random measurement error. The uncertainty in the elements composing KHP are: a. Carbon: b. Hydrogen: ±0.0008…
Don't used hand raiting and don't used Ai solution

Chapter 9 Solutions

EP ORGANIC CHEMISTRY -MOD.MASTERING 18W

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