EBK ORGANIC AND BIOLOGICAL CHEMISTRY
7th Edition
ISBN: 9780100547742
Author: STOKER
Publisher: YUZU
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Chapter 9, Problem 9.114EP
Interpretation Introduction
Interpretation: The possible products formed when the tripeptide, Ala-Val-Ala undergo complete hydrolysis has to be stated.
Concept introduction: The complete hydrolysis of protein results into the formation of free amino acids. Theses amino acids are obtained due to the breakdown of all the peptide bonds.
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You are trying to decide if there is a single reagent you can add that will make the following synthesis possible without any other major side products:
xi
1. ☑
2. H₂O
хе
i
Draw the missing reagent X you think will make this synthesis work in the drawing area below.
If there is no reagent that will make your desired product in good yield or without complications, just check the box under the drawing area and leave it blank.
Click and drag to start drawing a
structure.
There is no reagent that will make this synthesis work without complications.
: ☐
S
☐
Predict the major products of this organic reaction:
H
OH
1. LiAlH4
2. H₂O
?
Note: be sure you use dash and wedge bonds when necessary, for example to distinguish between major products with different stereochemistry.
Click and drag to start drawing a
structure.
G
C
टे
For each reaction below, decide if the first stable organic product that forms in solution will create a new C-C bond, and check the appropriate box.
Next, for each reaction to which you answered "Yes" to in the table, draw this product in the drawing area below.
Note for advanced students: for this problem, don't worry if you think this product will continue to react under the current conditions - just focus on the first
stable product you expect to form in solution.
NH2
CI
MgCl
?
Will the first product that forms in this reaction
create a new CC bond?
Yes
No
MgBr
?
Will the first product that forms in this reaction
create a new CC bond?
Yes
No
G
टे
Chapter 9 Solutions
EBK ORGANIC AND BIOLOGICAL CHEMISTRY
Ch. 9.1 - Prob. 1QQCh. 9.1 - Proteins are naturally occurring unbranched...Ch. 9.2 - Prob. 1QQCh. 9.2 - How do the various standard amino acids differ...Ch. 9.2 - The number of carboxyl groups and amino groups...Ch. 9.2 - How many different subclassifications are there...Ch. 9.2 - Which of the following statements concerning...Ch. 9.3 - Prob. 1QQCh. 9.3 - Proteins from plant sources are a. always complete...Ch. 9.3 - Incomplete dietary proteins contain inadequate...
Ch. 9.4 - Which of the following statements concerning the...Ch. 9.4 - Prob. 2QQCh. 9.4 - Which of the following statements concerning...Ch. 9.5 - Which of the standard amino acids exist as...Ch. 9.5 - Which of the following is the zwitterion ion...Ch. 9.5 - Which of the following is the structural form for...Ch. 9.6 - Cysteine is unique among standard amino acids in...Ch. 9.6 - Prob. 2QQCh. 9.7 - The joining together of two amino acids to form a...Ch. 9.7 - Prob. 2QQCh. 9.7 - Which of the following statements concerning the...Ch. 9.7 - What functional group is present in the bond...Ch. 9.7 - How many isomeric tripeptides can be formed from...Ch. 9.8 - The two best-known peptide hormones present in the...Ch. 9.8 - Which of the following peptides is an important...Ch. 9.9 - The term protein is generally reserved for...Ch. 9.9 - The presence of which of the following is a...Ch. 9.9 - Which of the following is not a distinguishing...Ch. 9.10 - Prob. 1QQCh. 9.10 - Prob. 2QQCh. 9.10 - Two different proteins that contain the same...Ch. 9.11 - Prob. 1QQCh. 9.11 - Prob. 2QQCh. 9.11 - Which of the following statements concerning the ...Ch. 9.12 - Interactions between amino acid R groups are...Ch. 9.12 - Prob. 2QQCh. 9.12 - R group interactions between which of the...Ch. 9.13 - Prob. 1QQCh. 9.13 - Prob. 2QQCh. 9.14 - The complete hydrolysis of a protein produces a...Ch. 9.14 - Which of the following statements concerning...Ch. 9.15 - Which of the following levels of protein structure...Ch. 9.15 - Which of the following does not involve protein...Ch. 9.15 - Which of the following is not a denaturing agent...Ch. 9.16 - Which of the following statements concerning...Ch. 9.16 - Prob. 2QQCh. 9.16 - Prob. 3QQCh. 9.16 - In which of the following pairs of proteins are...Ch. 9.17 - Insulin and human growth hormone are examples of...Ch. 9.17 - Myoglobin and transferrin are examples of a....Ch. 9.17 - Prob. 3QQCh. 9.18 - Prob. 1QQCh. 9.18 - Which of the following statements concerning basic...Ch. 9.18 - Which of the following statements about antibodies...Ch. 9.19 - Prob. 1QQCh. 9.19 - Prob. 2QQCh. 9.19 - In which of the following pairs of plasma...Ch. 9 - Prob. 9.1EPCh. 9 - What element is always present in proteins that is...Ch. 9 - What percent of a cells overall mass is accounted...Ch. 9 - Prob. 9.4EPCh. 9 - What is signified when an amino acid is designated...Ch. 9 - Prob. 9.6EPCh. 9 - Prob. 9.7EPCh. 9 - Indicate whether or not each of the following...Ch. 9 - Prob. 9.9EPCh. 9 - How many carbon atoms are present in the R group...Ch. 9 - Prob. 9.11EPCh. 9 - Prob. 9.12EPCh. 9 - Prob. 9.13EPCh. 9 - Prob. 9.14EPCh. 9 - Prob. 9.15EPCh. 9 - Prob. 9.16EPCh. 9 - Prob. 9.17EPCh. 9 - Prob. 9.18EPCh. 9 - Prob. 9.19EPCh. 9 - Prob. 9.20EPCh. 9 - Prob. 9.21EPCh. 9 - Prob. 9.22EPCh. 9 - In what way is the structure of the amino acid...Ch. 9 - Which two of the standard amino acids are...Ch. 9 - Prob. 9.25EPCh. 9 - Prob. 9.26EPCh. 9 - Indicate whether or not each of the following...Ch. 9 - Prob. 9.28EPCh. 9 - Prob. 9.29EPCh. 9 - Prob. 9.30EPCh. 9 - Prob. 9.31EPCh. 9 - Prob. 9.32EPCh. 9 - Prob. 9.33EPCh. 9 - Prob. 9.34EPCh. 9 - To which family of mirror-image isomers do nearly...Ch. 9 - In what way is the structure of glycine different...Ch. 9 - Draw Fischer projection formulas for the following...Ch. 9 - Draw Fischer projection formulas for the following...Ch. 9 - Prob. 9.39EPCh. 9 - Prob. 9.40EPCh. 9 - At room temperature, amino acids are solids with...Ch. 9 - At room temperature, most amino acids are not very...Ch. 9 - Draw the zwitterion structure for each of the...Ch. 9 - Draw the zwitterion structure for each of the...Ch. 9 - Draw the structure of serine at each of the...Ch. 9 - Prob. 9.46EPCh. 9 - Prob. 9.47EPCh. 9 - Most amino acids have isoelectric points between...Ch. 9 - Glutamic acid exists in two low-pH forms instead...Ch. 9 - Arginine exists in two high-pH forms instead of...Ch. 9 - Prob. 9.51EPCh. 9 - In a high-pH aqueous solution, indicate whether...Ch. 9 - When two cysteine molecules dimerize, what happens...Ch. 9 - What chemical reaction involving the cysteine...Ch. 9 - What two functional groups are involved in the...Ch. 9 - Prob. 9.56EPCh. 9 - Prob. 9.57EPCh. 9 - Prob. 9.58EPCh. 9 - Prob. 9.59EPCh. 9 - What are the two alternating structure units...Ch. 9 - Draw a complete condensed structural...Ch. 9 - Draw a complete condensed structural...Ch. 9 - With the help of Table 20-1, identify the amino...Ch. 9 - Prob. 9.64EPCh. 9 - Prob. 9.65EPCh. 9 - With the help of Table 20-1, assign an IUPAC name...Ch. 9 - Prob. 9.67EPCh. 9 - Draw condensed structural formulas for the...Ch. 9 - Prob. 9.69EPCh. 9 - For the tripeptide SerArgIle which amino acid...Ch. 9 - Prob. 9.71EPCh. 9 - Consider the tripeptide leucylvalyltryptophan. a....Ch. 9 - Explain why the notations SerCys and CysSer...Ch. 9 - Explain why the notations AlaGlyValAla and...Ch. 9 - Prob. 9.75EPCh. 9 - There are a total of six different amino acid...Ch. 9 - Compare the structures of the protein hormones...Ch. 9 - Compare the protein hormones oxytocin and...Ch. 9 - Prob. 9.79EPCh. 9 - Compare the structures of the peptide...Ch. 9 - Prob. 9.81EPCh. 9 - Prob. 9.82EPCh. 9 - Prob. 9.83EPCh. 9 - Prob. 9.84EPCh. 9 - Indicate whether each of the following statements...Ch. 9 - Indicate whether each of the following statements...Ch. 9 - Prob. 9.87EPCh. 9 - Two proteins with the same amino acid composition...Ch. 9 - Prob. 9.89EPCh. 9 - Prob. 9.90EPCh. 9 - Prob. 9.91EPCh. 9 - Prob. 9.92EPCh. 9 - Prob. 9.93EPCh. 9 - Prob. 9.94EPCh. 9 - Prob. 9.95EPCh. 9 - Prob. 9.96EPCh. 9 - Prob. 9.97EPCh. 9 - Prob. 9.98EPCh. 9 - Prob. 9.99EPCh. 9 - Why is the phrase unstructured segment of a...Ch. 9 - State the four types of attractive forces that...Ch. 9 - Prob. 9.102EPCh. 9 - Prob. 9.103EPCh. 9 - Prob. 9.104EPCh. 9 - Prob. 9.105EPCh. 9 - Prob. 9.106EPCh. 9 - Indicate whether each of the following statements...Ch. 9 - Prob. 9.108EPCh. 9 - Prob. 9.109EPCh. 9 - Prob. 9.110EPCh. 9 - Prob. 9.111EPCh. 9 - Quaternary protein structure is more easily...Ch. 9 - Prob. 9.113EPCh. 9 - Prob. 9.114EPCh. 9 - Prob. 9.115EPCh. 9 - Prob. 9.116EPCh. 9 - Prob. 9.117EPCh. 9 - How many different di- and tripeptides could be...Ch. 9 - Identify the primary structure of a hexapeptide...Ch. 9 - Identify the primary structure of a hexapeptide...Ch. 9 - Draw structural formulas for the products obtained...Ch. 9 - Prob. 9.122EPCh. 9 - Prob. 9.123EPCh. 9 - Why is complete hydrolysis of a protein not also...Ch. 9 - In what way is the protein in a cooked egg the...Ch. 9 - Why is cooked protein more easily digested than...Ch. 9 - Prob. 9.127EPCh. 9 - Indicate whether or not each of the following...Ch. 9 - Prob. 9.129EPCh. 9 - Prob. 9.130EPCh. 9 - Prob. 9.131EPCh. 9 - What is the major biochemical function of each of...Ch. 9 - Using the list in Section 20-17, characterize each...Ch. 9 - Prob. 9.134EPCh. 9 - Prob. 9.135EPCh. 9 - Prob. 9.136EPCh. 9 - What two nonstandard amino acids are present in...Ch. 9 - Prob. 9.138EPCh. 9 - Prob. 9.139EPCh. 9 - Prob. 9.140EPCh. 9 - Prob. 9.141EPCh. 9 - Prob. 9.142EPCh. 9 - Prob. 9.143EPCh. 9 - Describe the process by which blood...Ch. 9 - Prob. 9.145EPCh. 9 - Prob. 9.146EPCh. 9 - Prob. 9.147EPCh. 9 - Prob. 9.148EPCh. 9 - Prob. 9.149EPCh. 9 - As the lipid content of a plasma lipoprotein...Ch. 9 - Prob. 9.151EPCh. 9 - Prob. 9.152EP
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