Introduction To Chemistry
5th Edition
ISBN: 9781259911149
Author: BAUER, Richard C., Birk, James P., Marks, Pamela
Publisher: Mcgraw-hill Education,
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Chapter 9, Problem 8QP
Interpretation Introduction
Interpretation:
A graph is to be drawn between the inverse of the length of gas column and the difference in mercury levels.
Concept Introduction:
A graph is plotted between the two variables to describe or study how one variable changes with a change in the values of another variable. The graph between the inverse of the length of the gas column and mercury levels can describe the relationship between the pressure and the volume of a gas.
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Part I.
a)
Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone
b) Pinacol (2,3-dimethyl, 1-3-butanediol) on treatment w/ acid gives a mixture of pina colone
(3,3-dimethyl-2-butanone) and 2, 3-dimethyl - 1,3-butadiene. Give reasonable mechanism
the formation of
the products
For
3. The explosive decomposition of 2 mole of TNT (2,4,6-trinitrotoluene) is shown below:
Assume the C(s) is soot-basically atomic carbon (although it isn't actually atomic carbon in real life).
2
CH3
H
NO2
NO2
3N2 (g)+7CO (g) + 5H₂O (g) + 7C (s)
H
a. Use bond dissociation energies to calculate how much AU is for this reaction in kJ/mol.
Part I.
Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone and answer the ff:
Pinacol (2,3-dimethyl, 1-3-butanediol) on treatment w/ acid gives a mixture of pina colone
and
(3,3-dimethyl-2-butanone) 2,3-dimethyl-1,3-butadiene. Give reasonable mechanism
the formation of the products
For
Chapter 9 Solutions
Introduction To Chemistry
Ch. 9 - Prob. 1QCCh. 9 - Prob. 2QCCh. 9 - Prob. 3QCCh. 9 - Prob. 4QCCh. 9 - Prob. 5QCCh. 9 - Prob. 1PPCh. 9 - Prob. 2PPCh. 9 - What pressure is needed to compress 455 mL of...Ch. 9 - Prob. 4PPCh. 9 - Prob. 5PP
Ch. 9 - Prob. 6PPCh. 9 - Prob. 7PPCh. 9 - Prob. 8PPCh. 9 - Prob. 9PPCh. 9 - Prob. 10PPCh. 9 - Prob. 11PPCh. 9 - Prob. 12PPCh. 9 - Prob. 13PPCh. 9 - Prob. 14PPCh. 9 - Prob. 15PPCh. 9 - Prob. 16PPCh. 9 - Prob. 17PPCh. 9 - Prob. 18PPCh. 9 - Prob. 1QPCh. 9 - Prob. 2QPCh. 9 - Prob. 3QPCh. 9 - Prob. 4QPCh. 9 - A series of organic compounds called the alkanes...Ch. 9 - Prob. 6QPCh. 9 - Prob. 7QPCh. 9 - Prob. 8QPCh. 9 - Prob. 9QPCh. 9 - Prob. 10QPCh. 9 - Prob. 11QPCh. 9 - Prob. 12QPCh. 9 - Prob. 13QPCh. 9 - Prob. 14QPCh. 9 - Prob. 15QPCh. 9 - Prob. 16QPCh. 9 - Prob. 17QPCh. 9 - Prob. 18QPCh. 9 - Prob. 19QPCh. 9 - Prob. 20QPCh. 9 - Prob. 21QPCh. 9 - Prob. 22QPCh. 9 - Prob. 23QPCh. 9 - Prob. 24QPCh. 9 - Prob. 25QPCh. 9 - Prob. 26QPCh. 9 - Prob. 27QPCh. 9 - Prob. 28QPCh. 9 - Prob. 29QPCh. 9 - Prob. 30QPCh. 9 - Prob. 31QPCh. 9 - Prob. 32QPCh. 9 - Prob. 33QPCh. 9 - Prob. 34QPCh. 9 - Prob. 35QPCh. 9 - Prob. 36QPCh. 9 - Prob. 37QPCh. 9 - Prob. 38QPCh. 9 - Prob. 39QPCh. 9 - Prob. 40QPCh. 9 - Prob. 41QPCh. 9 - Prob. 42QPCh. 9 - Prob. 43QPCh. 9 - Prob. 44QPCh. 9 - Prob. 45QPCh. 9 - Prob. 46QPCh. 9 - Prob. 47QPCh. 9 - Prob. 48QPCh. 9 - Prob. 49QPCh. 9 - Prob. 50QPCh. 9 - Prob. 51QPCh. 9 - Prob. 52QPCh. 9 - Prob. 53QPCh. 9 - Prob. 54QPCh. 9 - Prob. 55QPCh. 9 - Prob. 56QPCh. 9 - Prob. 57QPCh. 9 - Prob. 58QPCh. 9 - Prob. 59QPCh. 9 - Prob. 60QPCh. 9 - Prob. 61QPCh. 9 - Prob. 62QPCh. 9 - Prob. 63QPCh. 9 - Prob. 64QPCh. 9 - Prob. 65QPCh. 9 - Prob. 66QPCh. 9 - Prob. 67QPCh. 9 - Prob. 68QPCh. 9 - Prob. 69QPCh. 9 - Prob. 70QPCh. 9 - Prob. 71QPCh. 9 - Prob. 72QPCh. 9 - Prob. 73QPCh. 9 - Prob. 74QPCh. 9 - Prob. 75QPCh. 9 - Prob. 76QPCh. 9 - Prob. 77QPCh. 9 - Prob. 78QPCh. 9 - Prob. 79QPCh. 9 - Prob. 80QPCh. 9 - Prob. 81QPCh. 9 - Prob. 82QPCh. 9 - Prob. 83QPCh. 9 - Prob. 84QPCh. 9 - Prob. 85QPCh. 9 - Prob. 86QPCh. 9 - Prob. 87QPCh. 9 - Prob. 88QPCh. 9 - Prob. 89QPCh. 9 - Prob. 90QPCh. 9 - Prob. 91QPCh. 9 - Prob. 92QPCh. 9 - Prob. 93QPCh. 9 - Prob. 94QPCh. 9 - Prob. 95QPCh. 9 - Prob. 96QPCh. 9 - Prob. 97QPCh. 9 - Prob. 98QPCh. 9 - Prob. 99QPCh. 9 - Prob. 100QPCh. 9 - Prob. 101QPCh. 9 - Prob. 102QPCh. 9 - Prob. 103QPCh. 9 - Prob. 104QPCh. 9 - Prob. 105QPCh. 9 - Prob. 106QPCh. 9 - Prob. 107QPCh. 9 - Prob. 108QPCh. 9 - Prob. 109QPCh. 9 - Prob. 110QPCh. 9 - Prob. 111QPCh. 9 - Prob. 112QPCh. 9 - Prob. 113QPCh. 9 - Prob. 114QPCh. 9 - Prob. 115QPCh. 9 - Prob. 116QPCh. 9 - Prob. 117QPCh. 9 - Prob. 118QPCh. 9 - Prob. 119QPCh. 9 - Prob. 120QPCh. 9 - Prob. 121QPCh. 9 - Prob. 122QPCh. 9 - Prob. 123QPCh. 9 - Prob. 124QPCh. 9 - Prob. 125QPCh. 9 - Prob. 126QPCh. 9 - Prob. 127QPCh. 9 - Prob. 128QPCh. 9 - Prob. 129QPCh. 9 - Prob. 130QPCh. 9 - Prob. 131QPCh. 9 - Prob. 132QPCh. 9 - Prob. 133QPCh. 9 - Prob. 134QPCh. 9 - Prob. 135QPCh. 9 - Prob. 136QPCh. 9 - Prob. 137QPCh. 9 - Prob. 138QPCh. 9 - Prob. 139QPCh. 9 - Prob. 140QPCh. 9 - Prob. 141QPCh. 9 - Prob. 142QPCh. 9 - Prob. 143QPCh. 9 - Prob. 144QPCh. 9 - Prob. 145QPCh. 9 - Prob. 146QPCh. 9 - Prob. 147QPCh. 9 - Prob. 148QPCh. 9 - Prob. 149QPCh. 9 - Prob. 150QPCh. 9 - Prob. 151QPCh. 9 - Prob. 152QPCh. 9 - Prob. 153QPCh. 9 - Prob. 154QPCh. 9 - Prob. 155QPCh. 9 - Prob. 156QPCh. 9 - Prob. 157QPCh. 9 - Prob. 158QPCh. 9 - Prob. 159QPCh. 9 - Prob. 160QPCh. 9 - Prob. 161QPCh. 9 - Prob. 162QPCh. 9 - Prob. 163QPCh. 9 - Prob. 164QPCh. 9 - Prob. 165QPCh. 9 - Butane burns with oxygen according to the...Ch. 9 - Prob. 167QP
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- 19.78 Write the products of the following sequences of reactions. Refer to your reaction road- maps to see how the combined reactions allow you to "navigate" between the different functional groups. Note that you will need your old Chapters 6-11 and Chapters 15-18 roadmaps along with your new Chapter 19 roadmap for these. (a) 1. BHS 2. H₂O₂ 3. H₂CrO4 4. SOCI₂ (b) 1. Cl₂/hv 2. KOLBU 3. H₂O, catalytic H₂SO4 4. H₂CrO4 Reaction Roadmap An alkene 5. EtOH 6.0.5 Equiv. NaOEt/EtOH 7. Mild H₂O An alkane 1.0 2. (CH3)₂S 3. H₂CrO (d) (c) 4. Excess EtOH, catalytic H₂SO OH 4. Mild H₂O* 5.0.5 Equiv. NaOEt/EtOH An alkene 6. Mild H₂O* A carboxylic acid 7. Mild H₂O* 1. SOC₁₂ 2. EtOH 3.0.5 Equiv. NaOEt/E:OH 5.1.0 Equiv. NaOEt 6. NH₂ (e) 1. 0.5 Equiv. NaOEt/EtOH 2. Mild H₂O* Br (f) i H An aldehyde 1. Catalytic NaOE/EtOH 2. H₂O*, heat 3. (CH,CH₂)₂Culi 4. Mild H₂O* 5.1.0 Equiv. LDA Br An ester 4. NaOH, H₂O 5. Mild H₂O* 6. Heat 7. MgBr 8. Mild H₂O* 7. Mild H₂O+arrow_forwardLi+ is a hard acid. With this in mind, which if the following compounds should be most soluble in water? Group of answer choices LiBr LiI LiF LiClarrow_forwardQ4: Write organic product(s) of the following reactions and show the curved-arrow mechanism of the reactions. Br MeOH OSO2CH3 MeOHarrow_forward
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