Introducing Chemistry
6th Edition
ISBN: 9780134557373
Author: Tro
Publisher: PEARSON
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Textbook Question
Chapter 9, Problem 70E
How many 3d electrons are in an atom of each element?
a. Fe
b. Zn
c. K
d. As
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3. The explosive decomposition of 2 mole of TNT (2,4,6-trinitrotoluene) is shown below:
Assume the C(s) is soot-basically atomic carbon (although it isn't actually atomic carbon in real life).
2
CH3
H
NO2
NO2
3N2 (g)+7CO (g) + 5H₂O (g) + 7C (s)
H
a. Use bond dissociation energies to calculate how much AU is for this reaction in kJ/mol.
Part I.
Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone and answer the ff:
Pinacol (2,3-dimethyl, 1-3-butanediol) on treatment w/ acid gives a mixture of pina colone
and
(3,3-dimethyl-2-butanone) 2,3-dimethyl-1,3-butadiene. Give reasonable mechanism
the formation of the products
For
Show the mechanism for these reactions
Chapter 9 Solutions
Introducing Chemistry
Ch. 9 - Q1. Which set of wavelengths for light are...Ch. 9 - Which of the listed types of electromagnetic...Ch. 9 - Q3. Which electron transition in the Bohr model...Ch. 9 - What is the electron configuration of arsenic...Ch. 9 - Which orbital diagram corresponds to phosphorus...Ch. 9 - Q6. How many valence electrons does tellurium (Te)...Ch. 9 - Q7. The element sulfur forms an ion with what...Ch. 9 - Order the elements Sr, Ca, and Se in order of...Ch. 9 - Which of the listed elements has the highest...Ch. 9 - Q10. Which of the listed elements is most...
Ch. 9 - Which property decreases as you move down a column...Ch. 9 - Q12. When aluminum forms an ion, it loses...Ch. 9 - 1. When were the Bohr model the quantum-mechanical...Ch. 9 - 2. What is light? How fast does light travel?
Ch. 9 - 3. What is white light? Colored light?
Ch. 9 - Explain in terms of absorbed and reflected light,...Ch. 9 - What is the relationship between the wavelength of...Ch. 9 - 6. List some sources of gamma rays.
Ch. 9 - How are X-rays used?Ch. 9 - Why should excess exposure to gamma rays and...Ch. 9 - Why should excess exposure to ultraviolet light be...Ch. 9 - What objects emit infrared light? What technology...Ch. 9 - Why do microwave ovens heat food but tend not to...Ch. 9 - 12 .What type of electromagnetic radiation is used...Ch. 9 - Describe the Bohr model for the hydrogen atom.Ch. 9 - 14. What is an emission spectrum? Use the Bohr...Ch. 9 - 15. Explain the difference between a Bohr orbit...Ch. 9 - 16. What is the difference between the ground...Ch. 9 - 17. Explain how the motion of an electron is...Ch. 9 - 18. Why do quantum-mechanical orbital have “fuzzy”...Ch. 9 - 19. List the four possible subshells in the...Ch. 9 - 20. List the quantum-mechanical orbitals through...Ch. 9 - Prob. 21ECh. 9 - Prob. 22ECh. 9 - Within an electron configuration. What do symbols...Ch. 9 - Explain the difference between valence electrons...Ch. 9 - Identify each block in the blank periodic table....Ch. 9 - Prob. 26ECh. 9 - Prob. 27ECh. 9 - Prob. 28ECh. 9 - Prob. 29ECh. 9 - How far does light travel in each time period? a....Ch. 9 - 31. Which type of electromagnetic radiation has...Ch. 9 - 32. Which type of electromagnetic radiation has...Ch. 9 - List the types of electromagnetic radiation in...Ch. 9 - List the types of electromagnetic radiation in...Ch. 9 - List two types of electromagnetic radiation with...Ch. 9 - List two types of electromagnetic radiation with...Ch. 9 - List these three types of radiationinfrared,...Ch. 9 - List these three types of electromagnetic...Ch. 9 - Prob. 39ECh. 9 - 40. In the Bohr model, what happens when an...Ch. 9 - 41. Two of the emission wavelengths in the...Ch. 9 - 42. Two of the emission wavelengths in the...Ch. 9 - 43. Sketch the 1s and 2p orbitals. How do the 2s...Ch. 9 - Sketch the 3d orbitals. How do the 4d orbitals...Ch. 9 - Which electron is, on average closer to the...Ch. 9 - 46. Which electron is, on average, farther from...Ch. 9 - 47. According to the quantum-mechanical model for...Ch. 9 - Prob. 48ECh. 9 - 49. Write full electron configuration for each...Ch. 9 - 50. Write full electron configurations for each...Ch. 9 - 51. Write full orbital diagrams and indicate the...Ch. 9 - Write full orbital diagrams and indicate the...Ch. 9 - Write electron configurations for each element....Ch. 9 - Write electron configurations for each element....Ch. 9 - Prob. 55ECh. 9 - Prob. 56ECh. 9 - Write full electron configurations and indicate...Ch. 9 - 58. Write full electron configurations and...Ch. 9 - Write orbital diagrams for the valence electrons...Ch. 9 - 60. Write orbital diagrams for the valence...Ch. 9 - How many valence electrons are in each element? a....Ch. 9 - 62. How many valence electrons are in each...Ch. 9 - 63. List the outer electron configuration for each...Ch. 9 - Prob. 64ECh. 9 - Prob. 65ECh. 9 - Use the periodic table to write electron...Ch. 9 - Use the periodic table to write electron...Ch. 9 - 68. Use the periodic table to write electron...Ch. 9 - Prob. 69ECh. 9 - How many 3d electrons are in an atom of each...Ch. 9 - Prob. 71ECh. 9 - Prob. 72ECh. 9 - Name the element in the third period (row) of the...Ch. 9 - 74. Name the element in the fourth period of the...Ch. 9 - 75. Use the periodic table to identify the element...Ch. 9 - 76. Use the periodic table to identify the element...Ch. 9 - 77. Choose the element with the higher ionization...Ch. 9 - Choose the element with the higher ionization...Ch. 9 - Arrange the elements in order of increasing...Ch. 9 - 80. Arrange the elements in order of increasing...Ch. 9 - 81. Choose the element with the larger atoms from...Ch. 9 - Choose the element with the larger atoms from each...Ch. 9 - Prob. 83ECh. 9 - Prob. 84ECh. 9 - 85. Choose the more metallic element from each...Ch. 9 - Choose the more metallic element from each pair....Ch. 9 - 87. Arrange these elements in order of increasing...Ch. 9 - Arrange these elements in order of increasing...Ch. 9 - What is the maximum number of electrons that can...Ch. 9 - 90. What is the maximum number of electrons that...Ch. 9 - Use the electron configurations of the alkaline...Ch. 9 - Prob. 92ECh. 9 - Write the electron configuration for each ion....Ch. 9 - Write the electron configuration for each ion....Ch. 9 - Prob. 95ECh. 9 - 96. Examine Figure 4.14, which shows the elements...Ch. 9 - Prob. 97ECh. 9 - Identify what is wrong with each electron...Ch. 9 - Prob. 99ECh. 9 - Prob. 100ECh. 9 - Prob. 101ECh. 9 - Based on periodic trends, which one of these...Ch. 9 - When an electron makes a transition from n=3 to...Ch. 9 - Prob. 104ECh. 9 - The distance from the sun to Earth is 1.496108 km....Ch. 9 - Prob. 106ECh. 9 - 107. The wave nature of matter was first proposed...Ch. 9 - 108. The particle nature of light was first...Ch. 9 - Prob. 109ECh. 9 - When atoms lose more than one electron, the...Ch. 9 - 111. Excessive exposure to sunlight increases the...Ch. 9 - 112. The quantum-mechanical model, besides...Ch. 9 - Prob. 113QGWCh. 9 - 116. Using grammatically correct sentences,...Ch. 9 - 117. The first graph shown here is of the first...
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- Draw the stepwise mechanismarrow_forwardDraw a structural formula of the principal product formed when benzonitrile is treated with each reagent. (a) H₂O (one equivalent), H₂SO₄, heat (b) H₂O (excess), H₂SO₄, heat (c) NaOH, H₂O, heat (d) LiAlH4, then H₂Oarrow_forwardDraw the stepwise mechanism for the reactionsarrow_forward
- Draw stepwise mechanismarrow_forwardPart I. Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone and answer the ff: a) Give the major reason for the exposure of benzophenone al isopropyl alcohol (w/acid) to direct sunlight of pina colone Mechanism For b) Pinacol (2,3-dimethy 1, 1-3-butanediol) on treatment w/ acid gives a mixture (3,3-dimethyl-2-butanone) and 2, 3-dimethyl-1,3-butadiene. Give reasonable the formation of the productsarrow_forwardwhat are the Iupac names for each structurearrow_forward
- What are the IUPAC Names of all the compounds in the picture?arrow_forward1) a) Give the dominant Intermolecular Force (IMF) in a sample of each of the following compounds. Please show your work. (8) SF2, CH,OH, C₂H₂ b) Based on your answers given above, list the compounds in order of their Boiling Point from low to high. (8)arrow_forward19.78 Write the products of the following sequences of reactions. Refer to your reaction road- maps to see how the combined reactions allow you to "navigate" between the different functional groups. Note that you will need your old Chapters 6-11 and Chapters 15-18 roadmaps along with your new Chapter 19 roadmap for these. (a) 1. BHS 2. H₂O₂ 3. H₂CrO4 4. SOCI₂ (b) 1. Cl₂/hv 2. KOLBU 3. H₂O, catalytic H₂SO4 4. H₂CrO4 Reaction Roadmap An alkene 5. EtOH 6.0.5 Equiv. NaOEt/EtOH 7. Mild H₂O An alkane 1.0 2. (CH3)₂S 3. H₂CrO (d) (c) 4. Excess EtOH, catalytic H₂SO OH 4. Mild H₂O* 5.0.5 Equiv. NaOEt/EtOH An alkene 6. Mild H₂O* A carboxylic acid 7. Mild H₂O* 1. SOC₁₂ 2. EtOH 3.0.5 Equiv. NaOEt/E:OH 5.1.0 Equiv. NaOEt 6. NH₂ (e) 1. 0.5 Equiv. NaOEt/EtOH 2. Mild H₂O* Br (f) i H An aldehyde 1. Catalytic NaOE/EtOH 2. H₂O*, heat 3. (CH,CH₂)₂Culi 4. Mild H₂O* 5.1.0 Equiv. LDA Br An ester 4. NaOH, H₂O 5. Mild H₂O* 6. Heat 7. MgBr 8. Mild H₂O* 7. Mild H₂O+arrow_forward
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