Excessive exposure to sunlight increases the risk of skin cancer because some of the photons have enough energy to break chemical bonds in biological molecules. These bonds require approximately 250−800 kj/mol of energy to break. The energy of a single photon is given by E = h c / λ where E is the energy of the photon in j, h is Planck’s constant ( 6.626 × 10 − 31 J .s ) , and c is the speed of light ( 3.00 × 10 8 m / s ) . Determine which kinds of light contain enough energy to break chemical bonds in biological molecules by calculating the total energy in 1 mol of photons for light of each wavelength a. infrared light (1500nm) b. visible light (500 nm) c. ultraviolet light (150 nm)
Excessive exposure to sunlight increases the risk of skin cancer because some of the photons have enough energy to break chemical bonds in biological molecules. These bonds require approximately 250−800 kj/mol of energy to break. The energy of a single photon is given by E = h c / λ where E is the energy of the photon in j, h is Planck’s constant ( 6.626 × 10 − 31 J .s ) , and c is the speed of light ( 3.00 × 10 8 m / s ) . Determine which kinds of light contain enough energy to break chemical bonds in biological molecules by calculating the total energy in 1 mol of photons for light of each wavelength a. infrared light (1500nm) b. visible light (500 nm) c. ultraviolet light (150 nm)
Solution Summary: The author explains that the wavelength of electromagnetic radiation is used to determine the amount of energy carried by one of its photons.
Excessive exposure to sunlight increases the risk of skin cancer because some of the photons have enough energy to break chemical bonds in biological molecules. These bonds require approximately 250−800 kj/mol of energy to break. The energy of a single photon is given by
E
=
h
c
/
λ
where E is the energy of the photon in j, h is Planck’s constant
(
6.626
×
10
−
31
J
.s
)
, and c is the speed of light
(
3.00
×
10
8
m
/
s
)
.
Determine which kinds of light contain enough energy to break chemical bonds in biological molecules by calculating the total energy in 1 mol of photons for light of each wavelength
Predict the major organic product(s) of the following reactions. Indicate which of the following mechanisms is in operation: SN1, SN2, E1, or E2.
(c)
(4pts)
Mechanism:
heat
(E1)
CH3OH
+
1.5pts each
_E1 _ (1pt)
Br
CH3OH
(d)
(4pts)
Mechanism:
SN1
(1pt)
(e)
(3pts)
1111 I
H
10
Ill!!
H
LDA
THF (solvent)
Mechanism: E2
(1pt)
NC
(f)
Bri!!!!!
CH3
NaCN
(3pts)
acetone
Mechanism: SN2
(1pt)
(SN1)
-OCH3
OCH3
1.5pts each
2pts for either product
1pt if incorrect
stereochemistry
H
Br
(g)
“,、
(3pts)
H
CH3OH
+21
Mechanism:
SN2
(1pt)
H
CH3
2pts
1pt if incorrect
stereochemistry
H
2pts
1pt if incorrect
stereochemistry
A mixture of butyl acrylate and 4'-chloropropiophenone has been taken for proton NMR analysis. Based on this proton NMR, determine the relative percentage of each compound in the mixture
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Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell