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Concept explainers
Interpretation:
From the given set of statements, the true statement/s needs to be determined.
Concept introduction:
The temperature above which gas cannot be liquefied by pressure alone is called as critical temperature. The pressure which is required to liquefy the gas at its critical temperature is called as critical pressure.
Triple point is defined as the temperature at which all phases of water such as gas, liquid, and solid occur at equilibrium. The solid form of water occurs at the temperature below the triple point.
Hydrogen bonding can be defined as the weak bond between two molecules which results from attraction between proton of one molecule and electronegative atom in another molecule.
Face-centered cubic is defined as the cubic lattice of fcc is equivalent to every eight corners of the structure.
The relation between edge length and atomic radius for fcc crystal is given by the following formula-
The structure which has lattice points at every eight corners and an atom centered in the cube is called as body-centered cubic.
The relation between edge length and atomic radius for bcc crystal is given by the following formula-
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Chapter 9 Solutions
CHEMISTRY:PRIN.+REACTIONS-OWLV2 ACCESS
- Associate each of the solids BN, P4S3, Pb, and CaCl2 with one of the following sets of properties. a A bluish white, lustrous solid melting at 327C; the solid is soft and malleable. b A white solid melting at 772C; the solid is an electrical nonconductor but dissolves in water to give a conducting solution. c A yellowish green solid melting at 172C. d A very hard, colorless substance melting at about 3000C.arrow_forwardSilicon carbide, SiC, is a very hard, high-melting solid. What kind of crystal forces account for these properties?arrow_forwardRutile, TiO2, crystallizes in a structure characteristic of many other ionic compounds How many formula units of TiO2 are in the unit cell illustrated here? (The oxide ions marked by an x are wholly within the cell; the others are in the cell faces.) Unit cell for rufflearrow_forward
- Calcium oxide consists of a face-centered cubic array of O2 ions, with Ca2+ ions at the center of the unit cell and along the centers of all 12 edges. Calculate the number of each ion in the unit cell.arrow_forwardArrange the following substances in order of increasing strength of crystal forces: CO2, KCl, H2O, N2, CaO.arrow_forwardThe unit cell of silicon carbide, SiC, is illustrated below. (a) In what type of unit cell are the (dark gray) C atoms arranged? (b) If one edge of the silicon carbide unit cell is 436.0 pm, what is the calculated density of this compound? A portion of the solid-state structure of silicon carbide.arrow_forward
- The CsCl structure is a simple cubic array of chloride ions with a cesium ion at the center of each cubic array (see Exercise 69). Given that the density of cesium chloride is 3.97 g/cm3, and assuming that the chloride and cesium ions touch along the body diagonal of the cubic unit cell, calculate the distance between the centers of adjacent Cs+ and Cl ions in the solid. Compare this value with the expected distance based on the sizes of the ions. The ionic radius of Cs+ is 169 pm, and the ionic radius of Cl is 181 pm.arrow_forwardDescribe, in general, the structures of ionic solids. Compare and contrast the structure of sodium chloride and zinc sulphide. How many tetrahedral holes and octahedral holes are there per closest packed anion? In zinc sulphide, why are only one-half of the tetrahedral holes filled with cations?arrow_forwardWhat is the coordination number of Cs in CsCl? of Na in NaCl? of Zn2 in ZnS?arrow_forward
- On the basis of the description given, classify each of the following solids as molecular, metallic, ionic, or covalent network. Explain your answers. a a lustrous, yellow solid that conducts electricity b a hard, black solid melting at 2350C to give a nonconducting liquid c a nonconducting, pink solid melting at 650C to give an electrically conducting liquid d red crystals having a characteristic odor and melting at 171Carrow_forwardWhat is the coordination number in the cesium chloride cubic structure?arrow_forwardWhat is a lattice? What is a unit cell? Describe a simple cubic unit cell. How many net atoms are contained in a simple cubic unit cell? How is the radius of the atom related to the cube edge length for a simple cubic unit cell? Answer the same questions for the body-centered cubic unit cell and for the face-centered unit cell.arrow_forward
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