Chemistry & Chemical Reactivity, Hybrid Edition (with OWLv2 24-Months Printed Access Card)
9th Edition
ISBN: 9781285462530
Author: John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher: Cengage Learning
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Chapter 9, Problem 53IL
The sulfamate ion, H2NSO3–, can be thought of as having been formed from the amide ion, NH2–, and sulphur trioxide, SO3.
(a) What are the electron-pair and molecular geometries or the amide ion and or SO3? What are the hybridizations of the N and S atoms, respectively?
(b) Sketch a structure for the sulfamate ion, and estimate the bond angles.
(c) What changes in hybridization do you expect for N and S in the course of the reaction
NH2– + SO3 → H2N—SO3–?
(d) Is SO3 the donor of an electron pair or the acceptor of an electron pair in the reaction with amide ion? Does the electrostatic potential map shown below confirm your prediction?
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Chapter 9 Solutions
Chemistry & Chemical Reactivity, Hybrid Edition (with OWLv2 24-Months Printed Access Card)
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The...Ch. 9.2 - Prob. 3RCCh. 9.2 - Prob. 4RCCh. 9.3 - What is the electron configuration of the H2+ ion?...Ch. 9.3 - Could the anion Li2 exist? What is the ions bond...Ch. 9.3 - The cations O2+ and N2+ are formed when molecules...
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