Chemistry: Structure and Properties Plus MasteringChemistry with eText -- Access Card Package
1st Edition
ISBN: 9780321729736
Author: Nivaldo J. Tro
Publisher: PEARSON
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Textbook Question
Chapter 9, Problem 53E
Provide the formula for each acid
- hydrofluoric acid
- hydrobromic acid
- sulfurous acid
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NMR spectrum of ethyl acetate has signals whose chemical shifts are indicated below. Which hydrogen or set of hydrogens corresponds to the signal at
4.1 ppm? Select the single best answer.
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ethyl acetate
H NMR: 1.3 ppm, 2.0 ppm, 4.1 ppm
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How many signals do you expect in the H NMR spectrum for this molecule?
Br Br
Write the answer below.
Also, in each of the drawing areas below is a copy of the molecule, with Hs shown. In each copy, one of the H atoms is colored red. Highlight in red all other H
atoms that would contribute to the same signal as the H already highlighted red
Note for advanced students: In this question, any multiplet is counted as one signal.
1
Number of signals in the 'H NMR spectrum.
For the molecule in the top drawing area, highlight in red any other H atoms that will contribute to
the same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at right.
Check
For the molecule in the bottom drawing area, highlight in red any other H atoms that will contribute
to the same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at right.
O
✓
No additional Hs to color in top
molecule
ง
No additional Hs to color in bottom…
in the kinetics experiment, what were the values calculated? Select all that apply.a) equilibrium constantb) pHc) order of reactiond) rate contstant
Chapter 9 Solutions
Chemistry: Structure and Properties Plus MasteringChemistry with eText -- Access Card Package
Ch. 9 - Prob. 1SAQCh. 9 - What mass (in grams) of Mg(NO3)2 is present in 145...Ch. 9 - Prob. 3SAQCh. 9 - Potassium iodide reacts with lead(ll) nitrate in...Ch. 9 - Which solution forms a precipitate when mixed with...Ch. 9 - What is the net ionic equation for the reaction...Ch. 9 - What is the net ionic equation for the reaction...Ch. 9 - What is the net ionic equation for the reaction...Ch. 9 - What is the oxidation state of carbon in CO32-? +3...Ch. 9 - Prob. 10SAQ
Ch. 9 - Prob. 11SAQCh. 9 - What is an aqueous solution? What is the...Ch. 9 - What is molarity? How is it useful?Ch. 9 - Explain how a strong electrolyte, a weak...Ch. 9 - What is an acid? Explain the difference between a...Ch. 9 - What does it mean for a compound to be soluble?...Ch. 9 - What are the solubility rules? How are they...Ch. 9 - Which cations and anions form compounds that are...Ch. 9 - What is a precipitation reaction? Give an example.Ch. 9 - How can you predict whether a precipitation...Ch. 9 - Explain how a molecular equation, a complete ionic...Ch. 9 - Prob. 11ECh. 9 - Prob. 12ECh. 9 - Prob. 13ECh. 9 - Explain the principles behind an acid-base...Ch. 9 - Prob. 15ECh. 9 - Which reactant types give rise to gas-evolution...Ch. 9 - Prob. 17ECh. 9 - What are oxidation states? How can oxidation...Ch. 9 - What happens to a substance when it becomes...Ch. 9 - In a redox reaction, which reactant is the...Ch. 9 - Prob. 21ECh. 9 - Prob. 22ECh. 9 - What is the molarity of NO3- in each solution?...Ch. 9 - What is the molarity of Cl- in each solution?...Ch. 9 - Prob. 25ECh. 9 - Prob. 26ECh. 9 - A laboratory procedure calls for making 400.0 mL...Ch. 9 - Prob. 28ECh. 9 - If 123 mL of a 1.1 M glucose solution is diluted...Ch. 9 - If 3.5 L of a 4.8 M SrCl2 solution is diluted to...Ch. 9 - To what volume should you dilute 50.0 mL of a 12 M...Ch. 9 - Prob. 32ECh. 9 - Consider the precipitation reaction:...Ch. 9 - Consider the reaction:...Ch. 9 - What is the minimum amount of 6.0 M H2SO4...Ch. 9 - What molarity of ZnCl2forms when 25.0 g of zinc...Ch. 9 - You mix a 25.0 mL sample of a 1.20 M potassium...Ch. 9 - Prob. 38ECh. 9 - For each compound (all water soluble), would you...Ch. 9 - Classify each compound as a strong electrolyte or...Ch. 9 - Determine whether each compound is soluble or...Ch. 9 - Prob. 42ECh. 9 - Prob. 43ECh. 9 - Complete and balance each equation. If no reaction...Ch. 9 - Write a molecular equation for the precipitation...Ch. 9 - Write a molecular equation for the precipitation...Ch. 9 - Write balanced complete ionic and net ionic...Ch. 9 - Write balanced complete ionic and net ionic...Ch. 9 - Mercury ions (Hg22+) can be removed from solution...Ch. 9 - Lead ions can be removed from solution by...Ch. 9 - Name each acid. Hl(aq) HNO3(aq) H2CO3(aq)Ch. 9 - Name each acid HCI(aq) HClO2(aq) H2SO4(aq)Ch. 9 - Provide the formula for each acid hydrofluoric...Ch. 9 - Provide the formula for each acid phosphoric acid...Ch. 9 - Write balanced molecular and net ionic equations...Ch. 9 - Write balanced molecular and net ionic equations...Ch. 9 - Complete and balance each acid-base equation...Ch. 9 - Complete and balance each acid-base equation...Ch. 9 - A 25.00-mL sample of an unknown HClO4solution...Ch. 9 - A 30.00-mL sample of an unknown H3PO4 solution is...Ch. 9 - Complete and balance each gas-evolution equation:...Ch. 9 - Prob. 62ECh. 9 - Write a balanced equation for the reaction between...Ch. 9 - Prob. 64ECh. 9 - Assign oxidation states to each atom in each...Ch. 9 - Prob. 66ECh. 9 - Prob. 67ECh. 9 - Prob. 68ECh. 9 - Determine whether or not each reaction is a redox...Ch. 9 - Determine whether or not each reaction is a redox...Ch. 9 - Prob. 71ECh. 9 - Prob. 72ECh. 9 - People often use sodium bicarbonate as an antacid...Ch. 9 - Toilet bowl cleaners often contain hydrochloric...Ch. 9 - Prob. 75ECh. 9 - Prob. 76ECh. 9 - Predict the products and write a balanced...Ch. 9 - Predict the products and write a balanced...Ch. 9 - Prob. 79ECh. 9 - Prob. 80ECh. 9 - Prob. 81ECh. 9 - A solution contains Cr3+ ion and Mg2+ ion. The...Ch. 9 - Find the volume of 0.110 M hydrochloric acid...Ch. 9 - Find the volume of 0.150 M sulfuric acid necessary...Ch. 9 - Treatment of gold metal with BrF3 and KF produces...Ch. 9 - We prepare a solution by mixing 0.10 L of 0.12 M...Ch. 9 - A solution contains Ag +and Hg2+ions. The addition...Ch. 9 - The water in lakes that have been acidified by...Ch. 9 - Recall from Section 8.5 that sodium carbonate is...Ch. 9 - A solution contains one or more of the following...Ch. 9 - A solution contains one or more of the following...Ch. 9 - Prob. 92ECh. 9 - Prob. 93ECh. 9 - Prob. 94ECh. 9 - Prob. 95E
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- true or false, given that a 20.00 mL sample of NaOH took 24.15 mL of 0.141 M HCI to reach the endpoint in a titration, the concentration of the NaOH is 1.17 M.arrow_forwardin the bromothymol blue experiment, pKa was measured. A closely related compound has a Ka of 2.10 x 10-5. What is the pKa?a) 7.1b) 4.7c) 2.0arrow_forwardcalculate the equilibrium concentration of H2 given that K= 0.017 at a constant temperature for this reaction. The inital concentration of HBr is 0.050 M.2HBr(g) ↔ H2(g) + Br2(g)a) 4.48 x 10-2 M b) 5.17 x 10-3 Mc) 1.03 x 10-2 Md) 1.70 x 10-2 Marrow_forward
- true or falsegiven these two equilibria with their equilibrium constants:H2(g) + CI2(l) ↔ 2HCI(g) K= 0.006 CI2(l) ↔ CI2(g) K= 0.30The equilibrium contstant for the following reaction is 1.8H2(g) + CI2 ↔ 2HCI(g)arrow_forwardI2(g) + CI2(g) ↔ 2ICIK for this reaction is 81.9. Find the equilibrium concentration of I2 if the inital concentration of I2 and CI2 are 0.010 Marrow_forwardtrue or false,the equilibrium constant for this reaction is 0.50.PCI5(g) ↔ PCI3(g) + CI2(g)Based on the above, the equilibrium constant for the following reaction is 0.25.2PCI5(g) ↔. 2PCI3(g) + 2CI2(g)arrow_forward
- true or false, using the following equilibrium, if carbon dioxide is added the equilibrium will shift toward the productsC(s) + CO2(g) ↔ 2CO(g)arrow_forward2S2O2/3- (aq) + I2 (aq) ---> S4O2/6- (aq) +2I- (aq) Experiment I2 (M) S2O3- (M) Initital Rate (M/s) 1 0.01 0.01 0.0004 2 0.01 0.02 0.0004 3 0.02 0.01 0.0008 Calculate the overall order for this reaction using the table data a) 3b) 0c) 2d) 1arrow_forwardthe decomposition of N2O5 is the first order with a half-life of 1.98 minutes. If the inital concentration of N2O5 is 0.200 M, what is the concentration after 6 minutes?a) 0.612 Mb) 0.035 Mc) 0.024 Md) 0.100 Marrow_forward
- 20.00 mL of 0.150 M HCI is titrated with 0.075 M NaOH. What volume of NaOH is needed?a) 50 mLb) 20 mLc) 40 mLd) 26.66 mLarrow_forward20.00 mL of 0.150 M NaOH is titrated with 37.75 mL of HCI. What is the molarity of the HCI?a) 0.150 Mb) 0.079 Mc) 0.025 Md) 0.050 Marrow_forwardin the following reaction, the OH- acts as which of these?NO2- (aq) + H2O (l) ⇌ OH- (aq) + HNO2 (aq)a) not a weak acidb) basec) acidarrow_forward
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