Introductory Chemistry, Books a la Carte Plus MasteringChemistry with eText -- Access Card Package (5th Edition)
5th Edition
ISBN: 9780321934604
Author: Nivaldo J. Tro
Publisher: PEARSON
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Textbook Question
Chapter 9, Problem 43E
Sketch the 1s and 2p orbitals. How do the 2s and 3p orbitals differ from the 1s and 2p orbitals?
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Students have asked these similar questions
Part VII. The H-NMR of a compound with molecular formula C5 H 10 O2 is given below.
Find the following:
(a) The no. of protons corresponding to each signal in the spectra
(6) Give the structure of the compound and assign the signals to each
proton in the compound.
a
70.2
Integration Values
C5H10O2
b
47.7
C
46.5
d
69.5
3.6 3.5
3.4 3.3 3.2 3.1 3.0
2.9 2.8
2.7
2.6 2.5
2.4 2.3 2.2 2.1 2.0
Chemical Shift (ppm)
1.9
1.8
1.7 1.6
1.5
1.4 1.3 1.2
1.1 1.0
0.9 0.8
Part 111. 1 H-NMR spectrum of a compound with integration values in red is given below.
Answer the following:
(a) write the signals in the 'H-NMR spectrum to the corresponding protons on the structure
of the molecule below.
(b) Identify the theoretical multiplicities for each proton in the compound. Also give the possible.
complex splitting patterns assuming J values are not similar.
там
Br
22
2
3
6
4 7.2 7.0 6.8 6.6 6.4 6.2 6.0 5.8 5.6 5.4 5.2 5.0 4.8 4.6 4.4 4.2 4.0 3.8 3.6 3.4 3.2 3.0 2.8 2.6 2.4 2.2 2.0 1.8 1.6 1.4 1.2 1.0 0.8 0
Chemical Shift (ppm)
ra.
Br
2
3
6
6
2.5
2.4
2.3
2.2
2.1
2.0
1.9
1.8
1.7
1.6
1.5
1.4
1.3
1.2
1.1
1.0
0.9
0.8
Chemical Shift (ppm)
2
2
Br
7.3
7.2
7.1
7.0 6.9
6.7 6.6 6.5
6.4
6.3
6.2
6.1
6.0
Chemical Shift (ppm)
5.9
5.8 5.7
5.5 5.4 5.3 5.2
5.0 4.9
1600°
1538°C
1493°C
In the diagram, the letter L indicates
that it is a liquid. Indicate its
components in the upper region
where only L is indicated.
The
iron-iron carbide phase
diagram.
Temperature (°C)
1400
8
1394°C
y+L
1200
2.14
y, Austenite
10000
912°C
800a
0.76
0.022
600
400
(Fe)
a, Ferrite
Composition (at% C)
15
1147°C
a + Fe3C
2
3
Composition (wt% C)
L
2500
4.30
2000
y + Fe3C
727°C
1500
Cementite (Fe3C)
1000
4
5
6
6.70
Temperature (°F)
Chapter 9 Solutions
Introductory Chemistry, Books a la Carte Plus MasteringChemistry with eText -- Access Card Package (5th Edition)
Ch. 9 - Q1. Which set of wavelengths for light are...Ch. 9 - Which of the listed types of electromagnetic...Ch. 9 - Q3. Which electron transition in the Bohr model...Ch. 9 - What is the electron configuration of arsenic...Ch. 9 - Which orbital diagram corresponds to phosphorus...Ch. 9 - Q6. How many valence electrons does tellurium (Te)...Ch. 9 - Q7. The element sulfur forms an ion with what...Ch. 9 - Order the elements Sr, Ca, and Se in order of...Ch. 9 - Which of the listed elements has the highest...Ch. 9 - Q10. Which of the listed elements is most...
Ch. 9 - Which property decreases as you move down a column...Ch. 9 - Q12. When aluminum forms an ion, it loses...Ch. 9 - 1. When were the Bohr model the quantum-mechanical...Ch. 9 - 2. What is light? How fast does light travel?
Ch. 9 - 3. What is white light? Colored light?
Ch. 9 - Explain in terms of absorbed and reflected light,...Ch. 9 - What is the relationship between the wavelength of...Ch. 9 - Prob. 6ECh. 9 - How are X-rays used?Ch. 9 - Why should excess exposure to gamma rays and...Ch. 9 - Why should excess exposure to ultraviolet light be...Ch. 9 - What objects emit infrared light? What technology...Ch. 9 - Why do microwave ovens heat food but tend not to...Ch. 9 - 12 .What type of electromagnetic radiation is used...Ch. 9 - Describe the Bohr model for the hydrogen atom.Ch. 9 - 14. What is an emission spectrum? Use the Bohr...Ch. 9 - 15. Explain the difference between a Bohr orbit...Ch. 9 - 16. What is the difference between the ground...Ch. 9 - 17. Explain how the motion of an electron is...Ch. 9 - 18. Why do quantum-mechanical orbital have “fuzzy”...Ch. 9 - Prob. 19ECh. 9 - 20. List the quantum-mechanical orbitals through...Ch. 9 - Prob. 21ECh. 9 - Prob. 22ECh. 9 - Within an electron configuration. What do symbols...Ch. 9 - Explain the difference between valence electrons...Ch. 9 - Identify each block in the blank periodic table....Ch. 9 - Prob. 26ECh. 9 - Prob. 27ECh. 9 - Prob. 28ECh. 9 - Prob. 29ECh. 9 - How far does light travel in each time period? a....Ch. 9 - 31. Which type of electromagnetic radiation has...Ch. 9 - 32. Which type of electromagnetic radiation has...Ch. 9 - List the types of electromagnetic radiation in...Ch. 9 - List the types of electromagnetic radiation in...Ch. 9 - List two types of electromagnetic radiation with...Ch. 9 - List two types of electromagnetic radiation with...Ch. 9 - List these three types of radiationinfrared,...Ch. 9 - List these three types of electromagnetic...Ch. 9 - Prob. 39ECh. 9 - 40. In the Bohr model, what happens when an...Ch. 9 - 41. Two of the emission wavelengths in the...Ch. 9 - 42. Two of the emission wavelengths in the...Ch. 9 - 43. Sketch the 1s and 2p orbitals. How do the 2s...Ch. 9 - Sketch the 3d orbitals. How do the 4d orbitals...Ch. 9 - Which electron is, on average closer to the...Ch. 9 - 46. Which electron is, on average, farther from...Ch. 9 - 47. According to the quantum-mechanical model for...Ch. 9 - Prob. 48ECh. 9 - 49. Write full electron configuration for each...Ch. 9 - Prob. 50ECh. 9 - 51. Write full orbital diagrams and indicate the...Ch. 9 - Write full orbital diagrams and indicate the...Ch. 9 - Write electron configurations for each element....Ch. 9 - Write electron configurations for each element....Ch. 9 - Prob. 55ECh. 9 - Prob. 56ECh. 9 - Prob. 57ECh. 9 - 58. Write full electron configurations and...Ch. 9 - Write orbital diagrams for the valence electrons...Ch. 9 - 60. Write orbital diagrams for the valence...Ch. 9 - How many valence electrons are in each element? a....Ch. 9 - Prob. 62ECh. 9 - Prob. 63ECh. 9 - Prob. 64ECh. 9 - Prob. 65ECh. 9 - Use the periodic table to write electron...Ch. 9 - Use the periodic table to write electron...Ch. 9 - Prob. 68ECh. 9 - Prob. 69ECh. 9 - Prob. 70ECh. 9 - Prob. 71ECh. 9 - Prob. 72ECh. 9 - Name the element in the third period (row) of the...Ch. 9 - 74. Name the element in the fourth period of the...Ch. 9 - 75. Use the periodic table to identify the element...Ch. 9 - Prob. 76ECh. 9 - 77. Choose the element with the higher ionization...Ch. 9 - Choose the element with the higher ionization...Ch. 9 - Arrange the elements in order of increasing...Ch. 9 - Prob. 80ECh. 9 - 81. Choose the element with the larger atoms from...Ch. 9 - Choose the element with the larger atoms from each...Ch. 9 - Prob. 83ECh. 9 - Prob. 84ECh. 9 - 85. Choose the more metallic element from each...Ch. 9 - Choose the more metallic element from each pair....Ch. 9 - 87. Arrange these elements in order of increasing...Ch. 9 - Arrange these elements in order of decreasing...Ch. 9 - What is the maximum number of electrons that can...Ch. 9 - Prob. 90ECh. 9 - Use the electron configurations of the alkaline...Ch. 9 - Prob. 92ECh. 9 - Write the electron configuration for each ion....Ch. 9 - Write the electron configuration for each ion....Ch. 9 - Prob. 95ECh. 9 - 96. Examine Figure 4.14, which shows the elements...Ch. 9 - Prob. 97ECh. 9 - Identify what is wrong with each electron...Ch. 9 - Prob. 99ECh. 9 - Prob. 100ECh. 9 - Prob. 101ECh. 9 - Based on periodic trends, which one of these...Ch. 9 - When an electron makes a transition from n=3 to...Ch. 9 - Prob. 104ECh. 9 - The distance from the sun to Earth is 1.496108 km....Ch. 9 - Prob. 106ECh. 9 - In the beginning of this chapter, you learned that...Ch. 9 - 108. Niels Bohr said, “Anyone who is not shocked...Ch. 9 - 107. The wave nature of matter was first proposed...Ch. 9 - 108. The particle nature of light was first...Ch. 9 - Prob. 111ECh. 9 - When atoms lose more than one electron, the...Ch. 9 - 111. Excessive exposure to sunlight increases the...Ch. 9 - 112. The quantum-mechanical model, besides...Ch. 9 - Prob. 115ECh. 9 - 116. Using grammatically correct sentences,...
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- Nonearrow_forwardPart II. Given below are the 'H-NMR spectrum at 300 MHz in CDC13 and mass spectrum using electron ionization of compound Brian. The FTIR of the said compound showed a strong peak at 1710 cm"). Determine the following: (a) molecular Formula and Degree of unsaturation of compound Brian (b) Basing on the given H-NMR spectrum tabulate the following (i) chemical shifts (ii) integration, ciii) multiplicity and (iv) interferences made for each signal (c) Draw the structure of compound Brian. ) ΕΙ 43 41 27 71 114 (M+) Hmmm 20 30 40 50 60 70 80 90 100 110 120 1H NMR spectrum 300 MHz in CDCl3 2.0 alle 1.0arrow_forwardThe iron-iron carbide phase diagram. In the diagram, the letter L indicates that it is a liquid. Indicate what its components are. Temperature (°C) 1600 10 Composition (at% C) 15 25 1538°C -1493°C 8 1400 1200 1394°C y+L L 2500 1147°C y. Austenite 2.14 4.30 2000 1000 912°C y + Fe3C 800ㅏ 0.76 0.022 600 a, Ferrite a + Fe3C 400 0 (Fe) Composition (wt% C) 727°C 1500 Cementite (Fe3C) 1000 6 6.70 Temperature (°F)arrow_forward
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