Chemistry In Focus
6th Edition
ISBN: 9781305544727
Author: Tro
Publisher: Cengage
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Textbook Question
Chapter 9, Problem 2E
From a molecular standpoint, explain how thermal energy is transferred from a hot object to a cold one.
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Q4: Rank the relative nucleophilicity of halide ions in water solution and DMF solution,
respectively.
F CI
Br |
Q5: Determine which of the substrates will and will not react with NaSCH3 in an SN2 reaction to
have a reasonable yield of product.
NH2
Br
Br
Br
OH
Br
Q7: Rank the following groups in order of basicity, nucleophilicity, and leaving group ability.
a) H₂O, OH, CH3COOT
b) NH3, H₂O, H₂S
Q8: Rank the following compounds in order of increasing reactivity in a nucleophilic substitution
reaction with CN as the nucleophile.
Br
A
B
NH2
LL
F
C
D
OH
CI
LLI
E
Q9: Complete the missing entities for following reactions (e.g., major product(s), reactants,
and/or solvents) for the SN2 reactions to occur efficiently. Include curved-arrow mechanism for
reactions a) to d).
a)
H
"Cl
D
+
-OCH 3
Page 3 of 5
Chapter 9 Solutions
Chemistry In Focus
Ch. 9 - Conversion of Energy Units The complete combustion...Ch. 9 - Calculating Energy Use in Kilowatt-Hours What is...Ch. 9 - Prob. 9.3YTCh. 9 - Enthalpy of Reaction How much energy in...Ch. 9 - Prob. 9.5YTCh. 9 - Prob. 1SCCh. 9 - Prob. 2SCCh. 9 - Prob. 3SCCh. 9 - Prob. 4SCCh. 9 - When two solutions are mixed in a beaker, a...
Ch. 9 - Prob. 1ECh. 9 - From a molecular standpoint, explain how thermal...Ch. 9 - Prob. 3ECh. 9 - Prob. 4ECh. 9 - Prob. 5ECh. 9 - Explain the first law of thermodynamics and its...Ch. 9 - What is entropy? Why is entropy important?Ch. 9 - Explain the second law of thermodynamics and its...Ch. 9 - Prob. 9ECh. 9 - Prob. 10ECh. 9 - Define each of the following terms: a. heat b....Ch. 9 - Prob. 12ECh. 9 - What happens to the temperature of the...Ch. 9 - Prob. 14ECh. 9 - Prob. 15ECh. 9 - Prob. 16ECh. 9 - Prob. 17ECh. 9 - Prob. 18ECh. 9 - Prob. 19ECh. 9 - What are the environmental problems associated...Ch. 9 - Prob. 21ECh. 9 - Prob. 22ECh. 9 - What is the major cause of acid rain?Ch. 9 - Explain how acid rain is formed and its effects on...Ch. 9 - Prob. 25ECh. 9 - Prob. 26ECh. 9 - Prob. 27ECh. 9 - Prob. 28ECh. 9 - Prob. 29ECh. 9 - Which fossil fuel is the worst offender when it...Ch. 9 - Prob. 31ECh. 9 - Prob. 32ECh. 9 - Prob. 33ECh. 9 - Prob. 34ECh. 9 - Assume that electricity costs 15 cents per...Ch. 9 - Prob. 36ECh. 9 - Prob. 37ECh. 9 - Prob. 38ECh. 9 - The coldest temperature ever measured in the...Ch. 9 - The warmest temperature ever measured in the...Ch. 9 - Chemical Reactions and Energy Calculate the amount...Ch. 9 - Prob. 42ECh. 9 - Prob. 43ECh. 9 - Prob. 44ECh. 9 - Prob. 45ECh. 9 - Prob. 46ECh. 9 - Prob. 47ECh. 9 - Prob. 48ECh. 9 - Calculate the amount of carbon dioxide (in kg)...Ch. 9 - Prob. 50ECh. 9 - The second law of thermodynamics has been called...Ch. 9 - You are camping and contemplating placing some hot...Ch. 9 - Prob. 56ECh. 9 - Prob. 57ECh. 9 - Prob. 58E
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- Q10: (a) Propose a synthesis of C from A. (b) Propose a synthesis of C from B. Br Br ...\SCH 3 A B Carrow_forward9: Complete the missing entities for following reactions (e.g., major product(s), reactants, and/or solvents) for the SN2 reactions to occur efficiently. Include curved-arrow mechanism for reactions a) to d).arrow_forwardComplete the missing entities for following reactions (e.g., major product(s), reactants, and/or solvents) for the SN2 reactions to occur efficiently. Include curved-arrow mechanism for reactions a) to d).arrow_forward
- QUESTION 3: Provide the synthetic steps that convert the starting material into the product (no mechanism required). HO OH NH CH3 multiple steps 요요 H3Carrow_forwardQ6: Predict the effect of the changes given on the rate of the reaction below. CH3OH CH3Cl + NaOCH3 → CH3OCH3 + NaCl a) Change the substrate from CH3CI to CH31: b) Change the nucleophile from NaOCH 3 to NaSCH3: c) Change the substrate from CH3CI to (CH3)2CHCI: d) Change the solvent from CH3OH to DMSO.arrow_forwardQ3: Arrange each group of compounds from fastest SN2 reaction rate to slowest SN2 reaction rate. a) CI Cl فيكم H3C-Cl A B C D Br Br b) A B C Br H3C-Br Darrow_forward
- Q2: Group these solvents into either protic solvents or aprotic solvents. Acetonitrile (CH3CN), H₂O, Acetic acid (CH3COOH), Acetone (CH3COCH3), CH3CH2OH, DMSO (CH3SOCH3), DMF (HCON(CH3)2), CH3OHarrow_forwardSuppose the rate of evaporation in a hot, dry region is 1.76 meters per year, and the seawater there has a salinity of 35 ‰. Assuming a 93% yield, how much salt (NaCl) can be harvested each year from 1 km2 of solar evaporation ponds that use this seawater as a source?arrow_forwardhelparrow_forward
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